Chloro­(p-tolyl­imido-κN)[N,N′-(trimethyl­silyl)­ferrocene-1,1′-diaminato-κ²N,N′]vanadium(V)

The title compound, [VCl(C₇H₇N){Fe(C₈H₁₃NSi)₂}] or [FeV(C₇H₇N)(C₈H₁₃NSi)₂Cl], crystallizes with the aromatic ring in the p-tolyl­imido unit parallel to the two cyclo­penta­dienyl rings of the ferrocene moiety; the vanadium-bound chloride ion also lies in the plane occupied by the imido ligand. A mirror plane bisects the molecule through the V atom, the imido ligand and the Fe atom.

Key indicators

• Single-crystal X-ray study
• T = 147 K
• Mean [sigma](C-C) = 0.004 Å
• R factor = 0.027
• wR factor = 0.034
• Data-to-parameter ratio = 11.2

checkCIF/PLATON results

No syntax errors found



Alert level A
PLAT027_ALERT_3_A _diffrn_reflns_theta_full (too) Low ............      24.72 Deg.

Author Response: Due to the detector configuration employed, data beyond 0.85 \%A was not collected.

Alert level C
THETM01_ALERT_3_C  The value of sine(theta_max)/wavelength is less than 0.590
            Calculated sin(theta_max)/wavelength =    0.5884
PLAT023_ALERT_3_C Resolution (too) Low [sin(th)/Lambda < 0.6].....      24.72 Deg.
PLAT220_ALERT_2_C Large Non-Solvent    C     Ueq(max)/Ueq(min) ...       3.08 Ratio
PLAT242_ALERT_2_C Check Low       Ueq as Compared to Neighbors for        Si1
PLAT380_ALERT_4_C Check Incorrectly? Oriented X(sp2)-Methyl Moiety        C15

   1 ALERT level A = In general: serious problem
   0 ALERT level B = Potentially serious problem
   5 ALERT level C = Check and explain
   0 ALERT level G = General alerts; check

   0 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
   2 ALERT type 2 Indicator that the structure model may be wrong or deficient
   3 ALERT type 3 Indicator that the structure quality may be low
   1 ALERT type 4 Improvement, methodology, query or suggestion
   0 ALERT type 5 Informative message, check

---

Computing details

Data collection: SMART (Bruker, 1999); cell refinement: SAINT (Bruker, 2002); data reduction: SAINT; program(s) used to solve structure: SIR92 (Altomare et al., 1993); program(s) used to refine structure: TEXSAN (Molecular Structure Corporation & Rigaku Corporation, 1998); molecular graphics: ORTEP-3 (Farrugia, 1997); software used to prepare material for publication: TEXSAN.

Chloro(p-tolylimido-κN)[N,N'-(trimethylsilyl)ferrocene-1,1'- diaminato-κ²N,N']vanadium(V)

Crystal data

[FeV(C7H7N)(C8H13NSi)2Cl]	F(000) = 1144.00
Mr = 549.95	Dx = 1.388 Mg m^−3
Orthorhombic, Pnma	Mo Kα radiation, λ = 0.7107 Å
Hall symbol: -P 2ac 2n	Cell parameters from 3806 reflections
a = 14.981 (1) Å	θ = 3.3–24.6°
b = 15.423 (1) Å	µ = 1.11 mm^−1
c = 11.3884 (8) Å	T = 147 K
V = 2631.4 (3) Å^3	Prism, red
Z = 4	0.27 × 0.21 × 0.17 mm

Data collection

Bruker SMART 1000 CCD diffractometer	1752 reflections with I > 3σ(I)
ω scans	Rint = 0.024
Absorption correction: multi-scan (Blessing, 1995)	θmax = 24.7°
Tmin = 0.728, Tmax = 0.828	h = 0→17
11979 measured reflections	k = 0→18
2332 independent reflections	l = 0→13

Refinement

Refinement on F	H-atom parameters constrained
R[F^2 > 2σ(F^2)] = 0.027	w = 1/[σ^2(Fo) + 0.00022|Fo|^2]
wR(F^2) = 0.035	(Δ/σ)max = 0.0004
S = 1.55	Δρmax = 0.39 e Å^−3
1752 reflections	Δρmin = −0.34 e Å^−3
157 parameters

Special details

Refinement. Refinement using reflections with F² > 3.0 σ(F²). The weighted R-factor (wR), goodness of fit (S) and R-factor (gt) are based on F, with F set to zero for negative F. The threshold expression of F² > 3.0 σ(F²) is used only for calculating R-factor (gt).

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq
Fe1	0.58299 (3)	0.2500	0.04443 (5)	0.0243 (2)
V1	0.79806 (4)	0.2500	0.02787 (5)	0.0205 (2)
Cl1	0.82425 (6)	0.2500	0.22308 (8)	0.0312 (3)
Si1	0.80551 (5)	0.04670 (5)	−0.05816 (7)	0.0288 (2)
N1	0.7514 (1)	0.1429 (1)	−0.0155 (2)	0.0229 (6)
N2	0.9020 (2)	0.2500	−0.0222 (2)	0.0239 (8)
C1	0.6597 (2)	0.1427 (2)	0.0163 (2)	0.0229 (7)
C2	0.5861 (2)	0.1443 (2)	−0.0634 (2)	0.0271 (7)
C3	0.5068 (2)	0.1439 (2)	0.0044 (3)	0.0343 (8)
C4	0.5294 (2)	0.1422 (2)	0.1236 (3)	0.0357 (8)
C5	0.6238 (2)	0.1411 (2)	0.1326 (2)	0.0274 (7)
C6	0.7184 (2)	−0.0363 (2)	−0.0836 (3)	0.052 (1)
C7	0.8799 (2)	0.0118 (2)	0.0627 (3)	0.068 (1)
C8	0.8704 (2)	0.0670 (2)	−0.1930 (3)	0.054 (1)
C9	0.9946 (2)	0.2500	−0.0348 (3)	0.0220 (10)
C10	1.0348 (2)	0.2500	−0.1446 (3)	0.026 (1)
C11	1.1278 (2)	0.2500	−0.1522 (3)	0.028 (1)
C12	1.1812 (2)	0.2500	−0.0535 (3)	0.026 (1)
C13	1.1396 (2)	0.2500	0.0554 (3)	0.030 (1)
C14	1.0472 (2)	0.2500	0.0653 (3)	0.0250 (10)
C15	1.2809 (3)	0.2500	−0.0640 (4)	0.038 (1)
H1	0.5897	0.1454	−0.1466	0.0325*
H2	0.4478	0.1446	−0.0261	0.0412*
H3	0.4886	0.1418	0.1875	0.0429*
H4	0.6573	0.1396	0.2034	0.0329*
H5	1.1751	0.2500	0.1245	0.0354*
H6	1.0201	0.2500	0.1407	0.0300*
H7	0.9994	0.2500	−0.2138	0.0308*
H8	1.1551	0.2500	−0.2275	0.0332*
H9	1.2962	0.2500	−0.1455	0.0455*
H10	1.3041	0.1997	−0.0280	0.0455*
H11	0.6856	−0.0452	−0.0132	0.0618*
H12	0.6793	−0.0171	−0.1438	0.0618*
H13	0.7458	−0.0892	−0.1067	0.0618*
H14	0.8454	0.0017	0.1314	0.0812*
H15	0.9097	−0.0401	0.0409	0.0812*
H16	0.9226	0.0559	0.0779	0.0812*
H17	0.8991	0.0150	−0.2168	0.0649*
H18	0.8315	0.0863	−0.2534	0.0649*
H19	0.9141	0.1103	−0.1780	0.0649*

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Fe1	0.0168 (3)	0.0220 (3)	0.0342 (3)	0.0000	0.0028 (2)	0.0000
V1	0.0159 (3)	0.0202 (3)	0.0254 (3)	0.0000	0.0013 (3)	0.0000
Cl1	0.0244 (5)	0.0432 (6)	0.0260 (5)	0.0000	−0.0015 (4)	0.0000
Si1	0.0271 (4)	0.0223 (4)	0.0371 (5)	0.0033 (3)	0.0044 (3)	−0.0023 (3)
N1	0.019 (1)	0.020 (1)	0.029 (1)	0.0007 (9)	0.0024 (9)	0.0002 (9)
N2	0.019 (2)	0.025 (2)	0.027 (2)	0.0000	−0.001 (1)	0.0000
C1	0.021 (1)	0.016 (1)	0.032 (2)	−0.000 (1)	0.001 (1)	0.000 (1)
C2	0.025 (1)	0.024 (1)	0.033 (2)	−0.004 (1)	−0.003 (1)	−0.002 (1)
C3	0.019 (1)	0.029 (2)	0.055 (2)	−0.005 (1)	−0.003 (1)	−0.001 (1)
C4	0.028 (2)	0.028 (2)	0.051 (2)	−0.004 (1)	0.016 (1)	0.003 (1)
C5	0.029 (1)	0.024 (1)	0.029 (2)	−0.000 (1)	0.000 (1)	0.005 (1)
C6	0.050 (2)	0.026 (2)	0.079 (2)	−0.003 (1)	0.014 (2)	−0.012 (2)
C7	0.069 (2)	0.055 (2)	0.079 (3)	0.034 (2)	−0.021 (2)	−0.005 (2)
C8	0.066 (2)	0.037 (2)	0.059 (2)	−0.007 (2)	0.028 (2)	−0.015 (2)
C9	0.016 (2)	0.019 (2)	0.031 (2)	0.0000	0.004 (2)	0.0000
C10	0.021 (2)	0.031 (2)	0.025 (2)	0.0000	−0.004 (2)	0.0000
C11	0.024 (2)	0.030 (2)	0.029 (2)	0.0000	0.009 (2)	0.0000
C12	0.018 (2)	0.023 (2)	0.036 (2)	0.0000	0.000 (2)	0.0000
C13	0.025 (2)	0.034 (2)	0.030 (2)	0.0000	−0.006 (2)	0.0000
C14	0.021 (2)	0.031 (2)	0.023 (2)	0.0000	0.003 (2)	0.0000
C15	0.025 (2)	0.042 (3)	0.048 (3)	0.0000	0.002 (2)	0.0000

Geometric parameters (Å, º)

Fe1—C1	2.040 (2)	C9—C14	1.386 (5)
Fe1—C1^i	2.040 (2)	C10—C11	1.396 (5)
Fe1—C2	2.042 (3)	C11—C12	1.379 (5)
Fe1—C2^i	2.042 (3)	C12—C13	1.388 (5)
Fe1—C3	2.047 (3)	C12—C15	1.499 (5)
Fe1—C3^i	2.047 (3)	C13—C14	1.389 (5)
Fe1—C4	2.055 (3)	C2—H1	0.950
Fe1—C4^i	2.055 (3)	C3—H2	0.950
Fe1—C5	2.050 (3)	C4—H3	0.950
Fe1—C5^i	2.050 (3)	C5—H4	0.950
V1—Cl1	2.257 (1)	C6—H11	0.950
V1—N1	1.861 (2)	C6—H12	0.950
V1—N1^i	1.861 (2)	C6—H13	0.950
V1—N2	1.658 (3)	C7—H14	0.950
Si1—N1	1.759 (2)	C7—H15	0.950
Si1—C6	1.850 (3)	C7—H16	0.950
Si1—C7	1.851 (3)	C8—H17	0.950
Si1—C8	1.844 (3)	C8—H18	0.950
N1—C1	1.420 (3)	C8—H19	0.950
N2—C9	1.395 (4)	C10—H7	0.950
C1—C2	1.427 (3)	C11—H8	0.950
C1—C5	1.430 (3)	C13—H5	0.950
C2—C3	1.418 (4)	C14—H6	0.950
C3—C4	1.399 (4)	C15—H9	0.956
C4—C5	1.418 (4)	C15—H10	0.943
C9—C10	1.388 (5)	C15—H10^i	0.943
C1—Fe1—C1^i	108.4 (1)	Fe1—C5—C4	70.0 (2)
C1—Fe1—C2	40.94 (10)	C1—C5—C4	107.9 (2)
C1—Fe1—C2^i	122.72 (10)	N2—C9—C10	121.6 (3)
C1—Fe1—C3	68.3 (1)	N2—C9—C14	118.8 (3)
C1—Fe1—C3^i	158.1 (1)	C10—C9—C14	119.6 (3)
C1—Fe1—C4	68.44 (10)	C9—C10—C11	119.2 (3)
C1—Fe1—C4^i	161.0 (1)	C10—C11—C12	121.9 (3)
C1—Fe1—C5	40.93 (10)	C11—C12—C13	117.9 (3)
C1—Fe1—C5^i	125.02 (10)	C11—C12—C15	120.9 (3)
C2—Fe1—C2^i	106.0 (1)	C13—C12—C15	121.2 (3)
C2—Fe1—C3	40.6 (1)	C12—C13—C14	121.3 (3)
C2—Fe1—C3^i	121.2 (1)	C9—C14—C13	120.0 (3)
C2—Fe1—C4	68.1 (1)	Fe1—C2—H1	125.910
C2—Fe1—C4^i	156.8 (1)	C1—C2—H1	126.231
C2—Fe1—C5	68.5 (1)	C3—C2—H1	126.232
C2—Fe1—C5^i	160.4 (1)	Fe1—C3—H2	126.228
C3—Fe1—C3^i	106.2 (1)	C2—C3—H2	125.510
C3—Fe1—C4	39.9 (1)	C4—C3—H2	125.513
C3—Fe1—C4^i	121.8 (1)	Fe1—C4—H3	126.310
C3—Fe1—C5	67.7 (1)	C3—C4—H3	125.917
C3—Fe1—C5^i	158.5 (1)	C5—C4—H3	125.915
C4—Fe1—C4^i	108.0 (1)	Fe1—C5—H4	126.364
C4—Fe1—C5	40.4 (1)	C1—C5—H4	126.024
C4—Fe1—C5^i	124.4 (1)	C4—C5—H4	126.027
C5—Fe1—C5^i	110.0 (1)	Si1—C6—H11	109.470
CL1—V1—N1	109.09 (6)	Si1—C6—H12	109.469
CL1—V1—N1^i	109.09 (6)	Si1—C6—H13	109.472
CL1—V1—N2	100.1 (1)	H11—C6—H12	109.469
N1—V1—N1^i	125.2 (1)	H11—C6—H13	109.475
N1—V1—N2	105.16 (7)	H12—C6—H13	109.472
N1—V1^i—N2	105.16 (7)	Si1—C7—H14	109.463
N1—Si1—C6	107.5 (1)	Si1—C7—H15	109.463
N1—Si1—C7	108.5 (1)	Si1—C7—H16	109.465
N1—Si1—C8	109.2 (1)	H14—C7—H15	109.476
C6—Si1—C7	109.8 (2)	H14—C7—H16	109.481
C6—Si1—C8	111.1 (2)	H15—C7—H16	109.480
C7—Si1—C8	110.6 (2)	Si1—C8—H17	109.460
V1—N1—Si1	130.4 (1)	Si1—C8—H18	109.466
V1—N1—C1	107.3 (2)	Si1—C8—H19	109.464
Si1—N1—C1	120.9 (2)	H17—C8—H18	109.478
V1—N2—C9	165.7 (3)	H17—C8—H19	109.476
Fe1—C1—N1	125.6 (2)	H18—C8—H19	109.484
Fe1—C1—C2	69.6 (1)	C9—C10—H7	120.384
Fe1—C1—C5	69.9 (1)	C11—C10—H7	120.384
N1—C1—C2	125.8 (2)	C10—C11—H8	119.048
N1—C1—C5	126.9 (2)	C12—C11—H8	119.037
C2—C1—C5	107.4 (2)	C12—C13—H5	119.332
Fe1—C2—C1	69.5 (1)	C14—C13—H5	119.336
Fe1—C2—C3	69.9 (1)	C9—C14—H6	120.001
C1—C2—C3	107.5 (2)	C13—C14—H6	119.996
Fe1—C3—C2	69.5 (1)	C12—C15—H9	108.351
Fe1—C3—C4	70.4 (2)	C12—C15—H10	109.377
C2—C3—C4	109.0 (2)	C12—C15—H10^i	109.377
Fe1—C4—C3	69.8 (2)	H9—C15—H10	109.512
Fe1—C4—C5	69.6 (1)	H9—C15—H10^i	109.512
C3—C4—C5	108.2 (2)	H10—C15—H10^i	110.673
Fe1—C5—C1	69.2 (1)
Fe1—C1—N1—V1	21.1 (2)	C1—Fe1—C5—C4	−119.3 (2)
Fe1—C1—N1—Si1	−170.6 (1)	C1—Fe1—C5^i—C4^i	−163.3 (2)
Fe1—C1—C2—C3	−59.8 (2)	C1—N1—Si1—C6	12.5 (2)
Fe1—C1—C5—C4	59.5 (2)	C1—N1—Si1—C7	−106.3 (2)
Fe1—C1^i—N1^i—V1	−21.1 (2)	C1—N1—Si1—C8	133.1 (2)
Fe1—C1^i—N1^i—Si1^i	170.6 (1)	C1—C2—Fe1—C2^i	121.8 (1)
Fe1—C1^i—C2^i—C3^i	59.8 (2)	C1—C2—Fe1—C3	−118.6 (2)
Fe1—C1^i—C5^i—C4^i	−59.5 (2)	C1—C2—Fe1—C3^i	163.2 (1)
Fe1—C2—C1—N1	−119.9 (2)	C1—C2—Fe1—C4	−81.9 (2)
Fe1—C2—C1—C5	59.9 (2)	C1—C2—Fe1—C4^i	−166.6 (2)
Fe1—C2—C3—C4	−59.5 (2)	C1—C2—Fe1—C5	−38.3 (1)
Fe1—C2^i—C1^i—N1^i	119.9 (2)	C1—C2—Fe1—C5^i	51.2 (4)
Fe1—C2^i—C1^i—C5^i	−59.9 (2)	C1—C2—C3—C4	0.1 (3)
Fe1—C2^i—C3^i—C4^i	59.5 (2)	C1—C5—Fe1—C2	38.3 (1)
Fe1—C3—C2—C1	59.6 (2)	C1—C5—Fe1—C2^i	−38.8 (4)
Fe1—C3—C4—C5	−59.2 (2)	C1—C5—Fe1—C3	82.2 (2)
Fe1—C3^i—C2^i—C1^i	−59.6 (2)	C1—C5—Fe1—C3^i	159.4 (3)
Fe1—C3^i—C4^i—C5^i	59.2 (2)	C1—C5—Fe1—C4	119.3 (2)
Fe1—C4—C3—C2	58.9 (2)	C1—C5—Fe1—C4^i	−163.7 (1)
Fe1—C4—C5—C1	−59.0 (2)	C1—C5—Fe1—C5^i	−120.8 (1)
Fe1—C4^i—C3^i—C2^i	−58.9 (2)	C1—C5—C4—C3	0.3 (3)
Fe1—C4^i—C5^i—C1^i	59.0 (2)	C2—Fe1—C1—C5	−118.4 (2)
Fe1—C5—C1—N1	120.1 (3)	C2—Fe1—C1^i—C5^i	−165.5 (1)
Fe1—C5—C1—C2	−59.7 (2)	C2—Fe1—C2^i—C3^i	119.5 (1)
Fe1—C5—C4—C3	59.3 (2)	C2—Fe1—C3—C4	120.1 (2)
Fe1—C5^i—C1^i—N1^i	−120.1 (3)	C2—Fe1—C3^i—C4^i	162.0 (1)
Fe1—C5^i—C1^i—C2^i	59.7 (2)	C2—Fe1—C4—C3	−37.3 (2)
Fe1—C5^i—C4^i—C3^i	−59.3 (2)	C2—Fe1—C4—C5	82.1 (2)
V1—N1—Si1—C6	177.8 (2)	C2—Fe1—C4^i—C3^i	−42.0 (3)
V1—N1—Si1—C7	59.0 (2)	C2—Fe1—C4^i—C5^i	−161.5 (2)
V1—N1—Si1—C8	−61.6 (2)	C2—Fe1—C5—C4	−81.0 (2)
V1—N1—C1—C2	110.4 (2)	C2—Fe1—C5^i—C4^i	158.1 (3)
V1—N1—C1—C5	−69.4 (3)	C2—C1—Fe1—C3	37.9 (2)
V1—N1^i—C1^i—C2^i	−110.4 (2)	C2—C1—Fe1—C3^i	−41.4 (3)
V1—N1^i—C1^i—C5^i	69.4 (3)	C2—C1—Fe1—C4	81.0 (2)
V1—N2—C9—C10	180.0	C2—C1—Fe1—C4^i	163.8 (3)
V1—N2—C9—C14	0.0	C2—C1—Fe1—C5	118.4 (2)
CL1—V1—N1—Si1	−88.4 (1)	C2—C1—Fe1—C5^i	−161.4 (1)
CL1—V1—N1—C1	78.5 (2)	C2—C1—C5—C4	−0.3 (3)
CL1—V1—N1^i—Si1^i	88.4 (1)	C2—C3—Fe1—C3^i	119.3 (1)
CL1—V1—N1^i—C1^i	−78.5 (2)	C2—C3—Fe1—C4	−120.1 (2)
CL1—V1—N2—C9	0.0	C2—C3—Fe1—C4^i	159.8 (2)
Si1—N1—V1—N1^i	139.78 (10)	C2—C3—Fe1—C5	−82.5 (2)
Si1—N1—V1—N2	18.3 (2)	C2—C3—Fe1—C5^i	−170.7 (3)
Si1—N1—C1—C2	−81.3 (3)	C2—C3—C4—C5	−0.3 (3)
Si1—N1—C1—C5	98.9 (3)	C3—Fe1—C1—C5	−80.5 (2)
N1—V1—N1^i—C1^i	53.4 (2)	C3—Fe1—C1^i—C5^i	159.8 (2)
N1—V1—N2—C9	−113.11 (7)	C3—Fe1—C3^i—C4^i	120.5 (1)
N1—C1—Fe1—C1^i	1.0 (3)	C3—Fe1—C4—C5	119.5 (2)
N1—C1—Fe1—C2	120.0 (3)	C3—Fe1—C4^i—C5^i	163.8 (2)
N1—C1—Fe1—C2^i	43.9 (2)	C3—Fe1—C5—C4	−37.1 (2)
N1—C1—Fe1—C3	157.9 (2)	C3—Fe1—C5^i—C4^i	−40.2 (3)
N1—C1—Fe1—C3^i	78.6 (3)	C3—C2—Fe1—C4	36.7 (2)
N1—C1—Fe1—C4	−159.0 (2)	C3—C2—Fe1—C4^i	−48.0 (3)
N1—C1—Fe1—C4^i	−76.2 (4)	C3—C2—Fe1—C5	80.4 (2)
N1—C1—Fe1—C5	−121.6 (3)	C3—C2—Fe1—C5^i	169.8 (3)
N1—C1—Fe1—C5^i	−41.4 (3)	C3—C2—C1—C5	0.1 (3)
N1—C1—C2—C3	−179.7 (2)	C3—C4—Fe1—C4^i	118.3 (2)
N1—C1—C5—C4	179.5 (2)	C3—C4—Fe1—C5	−119.5 (2)
N2—V1—N1—C1	−174.9 (2)	C3—C4—Fe1—C5^i	159.9 (2)
N2—V1—N1^i—C1^i	174.9 (2)	C4—Fe1—C1—C5	−37.4 (2)
N2—C9—C10—C11	180.0	C4—Fe1—C1^i—C5^i	−45.4 (4)
N2—C9—C14—C13	180.0	C4—Fe1—C4^i—C5^i	122.2 (1)
C1—Fe1—C1^i—C2^i	119.0 (1)	C4—C3—Fe1—C5	37.6 (2)
C1—Fe1—C1^i—C5^i	−122.6 (1)	C4—C3—Fe1—C5^i	−50.6 (3)
C1—Fe1—C2—C3	118.6 (2)	C4—C5—Fe1—C5^i	119.9 (2)
C1—Fe1—C2^i—C3^i	161.0 (1)	C9—C10—C11—C12	0.0
C1—Fe1—C3—C2	−38.2 (1)	C9—C14—C13—C12	0.0
C1—Fe1—C3—C4	81.9 (2)	C10—C9—C14—C13	0.0
C1—Fe1—C3^i—C2^i	−47.4 (3)	C10—C11—C12—C13	0.0
C1—Fe1—C3^i—C4^i	−167.5 (2)	C10—C11—C12—C15	180.0
C1—Fe1—C4—C3	−81.6 (2)	C11—C10—C9—C14	0.0
C1—Fe1—C4—C5	37.9 (2)	C11—C12—C13—C14	0.0
C1—Fe1—C4^i—C3^i	165.7 (3)	C14—C13—C12—C15	180.0
C1—Fe1—C4^i—C5^i	46.2 (4)

Symmetry code: (i) x, −y+1/2, z.