Acta Cryst. (2006). E62, m2661-m2663  [ doi:10.1107/S1600536806037433 ]

Tris[bis(-1,10-phenanthrolin-2-olato)dicopper(I)] monosodium trihydrogen -octamolybdate hemihydrate

M.-X. Li, P.-T. Ma and J.-P. Wang

Abstract: The title compound, Na[H₃Mo₈O₂₆][Cu₂(C₁₂H₇N₂O)₂]₃·0.5H₂O, contains neutral dinuclear copper(I) complexes and infinite chain-like polyoxoanions comprising -[Mo₈O₂₆]^4- units linked by Na⁺ cations which lie on centres of inversion. The polyoxoanion chains are protonated, rendering them neutral.

Online 22 September 2006

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