Acta Cryst. (2006). E62, m2634-m2635  [ doi:10.1107/S1600536806037020 ]

Bis[acetonitrilesilver(I)] hexafluorosilicate

T. M. Klapötke, B. Krumm and M. Scherr

Abstract: In the title compound, poly[₄-hexafluorosilicato-bis[acetonitrilesilver(I)]], [Ag₂(SiF₆)(CH₃CN)₂]_n, the Ag atom is bonded to acetonitrile and four F atoms of three different SiF₆^2- ions. The cations are linked via the SiF₆^2- counter-ion by secondary AgF interactions, leading to a five-coordinated Ag atom.

Online 20 September 2006

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