Bis[bis­(dicyclo­hexyl­phosphino)methane-κ²P,P′]platinum(II) bis­(perchlorate) 1,2-dichloro­ethane tetrasolvate

In the centrosymmetric title complex, [Pt(C₂₅H₄₆P₂)₂](ClO₄)₂·4C₂H₄Cl₂, the Pt atom is four-coordinated by P atoms in a distorted square-planar coordination geometry and the bis­(dicyclo­hexyl­phosphino)methane ligands form two planar four-membered chelate rings.

Key indicators

• Single-crystal X-ray study
• T = 294 K
• Mean [sigma](C-C) = 0.008 Å
• Disorder in solvent or counterion
• R factor = 0.032
• wR factor = 0.082
• Data-to-parameter ratio = 14.8

checkCIF/PLATON results

No syntax errors found





Alert level C
PLAT042_ALERT_1_C Calc. and Rep. MoietyFormula Strings Differ ....          ?
PLAT243_ALERT_4_C High  'Solvent' Ueq as Compared to Neighbors for        C26
PLAT243_ALERT_4_C High  'Solvent' Ueq as Compared to Neighbors for       C26'
PLAT243_ALERT_4_C High  'Solvent' Ueq as Compared to Neighbors for        Cl4
PLAT243_ALERT_4_C High  'Solvent' Ueq as Compared to Neighbors for       C29'
PLAT244_ALERT_4_C Low   'Solvent' Ueq as Compared to Neighbors for        C27
PLAT244_ALERT_4_C Low   'Solvent' Ueq as Compared to Neighbors for       C27'
PLAT244_ALERT_4_C Low   'Solvent' Ueq as Compared to Neighbors for        C28
PLAT244_ALERT_4_C Low   'Solvent' Ueq as Compared to Neighbors for       C28'
PLAT302_ALERT_4_C Anion/Solvent Disorder .........................      35.00 Perc.
PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... #          1
            P1  -PT1 -P1  -C1    100.00 13.00   2.756   1.555   1.555   1.555
PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... #          4
            P1  -PT1 -P1  -C7   -125.00 13.00   2.756   1.555   1.555   1.555
PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... #          7
            P1  -PT1 -P1  -C13   -14.00 13.00   2.756   1.555   1.555   1.555
PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... #         12
            P2  -PT1 -P2  -C20   -72.00  9.00   2.756   1.555   1.555   1.555
PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... #         15
            P2  -PT1 -P2  -C13    43.00  9.00   2.756   1.555   1.555   1.555
PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... #         18
            P2  -PT1 -P2  -C14   156.00  9.00   2.756   1.555   1.555   1.555
PLAT779_ALERT_2_C Suspect or Irrelevant (Bond) Angle in CIF ......      29.50 Deg.
              C28' -CL4  -C28     1.555   1.555   1.555

   0 ALERT level A = In general: serious problem
   0 ALERT level B = Potentially serious problem
  17 ALERT level C = Check and explain
   0 ALERT level G = General alerts; check

   1 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
   1 ALERT type 2 Indicator that the structure model may be wrong or deficient
   0 ALERT type 3 Indicator that the structure quality may be low
  15 ALERT type 4 Improvement, methodology, query or suggestion
   0 ALERT type 5 Informative message, check

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Computing details

Data collection: SMART (Bruker, 2000); cell refinement: SAINT (Bruker, 2000); data reduction: SAINT; program(s) used to solve structure: SHELXTL (Bruker, 2000); program(s) used to refine structure: SHELXTL; molecular graphics: SHELXTL; software used to prepare material for publication: SHELXTL.

Bis[bis(dicyclohexylphosphino)methane-κ²P,P']platinum(II) bis(perchlorate) 1,2-dichloroethane tetrasolvate

Crystal data

[Pt(C25H46P2)2](ClO4)2·4C2H4Cl2	Z = 1
Mr = 1606.91	F(000) = 828
Triclinic, P1	Dx = 1.464 Mg m^−3
Hall symbol: -P 1	Mo Kα radiation, λ = 0.71073 Å
a = 11.9213 (15) Å	Cell parameters from 6509 reflections
b = 13.7673 (16) Å	θ = 2.6–26.4°
c = 13.9489 (16) Å	µ = 2.43 mm^−1
α = 109.137 (2)°	T = 294 K
β = 112.534 (2)°	Block, pale yellow
γ = 103.398 (2)°	0.22 × 0.20 × 0.20 mm
V = 1822.5 (4) Å^3

Data collection

Bruker SMART CCD area-detector diffractometer	6377 independent reflections
Radiation source: fine-focus sealed tube	6254 reflections with I > 2σ(I)
Graphite monochromator	Rint = 0.020
φ and ω scans	θmax = 25.0°, θmin = 1.7°
Absorption correction: multi-scan (SADABS; Bruker, 2000)	h = −10→14
Tmin = 0.602, Tmax = 0.624	k = −16→8
9358 measured reflections	l = −16→16

Refinement

Refinement on F^2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F^2 > 2σ(F^2)] = 0.033	Hydrogen site location: inferred from neighbouring sites
wR(F^2) = 0.082	H-atom parameters constrained
S = 1.03	w = 1/[σ^2(Fo^2) + (0.0452P)^2 + 2.2251P] where P = (Fo^2 + 2Fc^2)/3
6377 reflections	(Δ/σ)max = 0.003
432 parameters	Δρmax = 1.25 e Å^−3
104 restraints	Δρmin = −1.10 e Å^−3

Special details

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq	Occ. (<1)
Pt1	1.0000	0.0000	0.5000	0.02442 (8)
P1	0.88579 (9)	0.07708 (8)	0.58583 (8)	0.0260 (2)
P2	0.79417 (9)	−0.03316 (8)	0.34918 (8)	0.0272 (2)
C1	0.8490 (4)	0.0322 (3)	0.6846 (3)	0.0313 (8)
H1	0.9307	0.0725	0.7611	0.038*
C2	0.8123 (5)	−0.0940 (4)	0.6449 (4)	0.0418 (10)
H2A	0.7322	−0.1371	0.5686	0.050*
H2B	0.8836	−0.1123	0.6379	0.050*
C3	0.7892 (6)	−0.1259 (4)	0.7328 (5)	0.0544 (12)
H3A	0.7618	−0.2065	0.7044	0.065*
H3B	0.8720	−0.0883	0.8069	0.065*
C4	0.6837 (5)	−0.0934 (4)	0.7521 (5)	0.0562 (13)
H4A	0.5985	−0.1373	0.6801	0.067*
H4B	0.6757	−0.1106	0.8119	0.067*
C5	0.7182 (5)	0.0308 (4)	0.7896 (5)	0.0542 (12)
H5A	0.7978	0.0746	0.8662	0.065*
H5B	0.6462	0.0481	0.7960	0.065*
C6	0.7415 (5)	0.0645 (4)	0.7025 (4)	0.0424 (10)
H6A	0.7687	0.1452	0.7316	0.051*
H6B	0.6592	0.0270	0.6281	0.051*
C7	0.9352 (4)	0.2300 (3)	0.6504 (3)	0.0299 (8)
H7	0.8601	0.2430	0.6564	0.036*
C8	1.0543 (4)	0.2927 (3)	0.7745 (4)	0.0398 (9)
H8A	1.1307	0.2805	0.7731	0.048*
H8B	1.0342	0.2634	0.8232	0.048*
C9	1.0876 (5)	0.4190 (4)	0.8267 (4)	0.0525 (12)
H9A	1.0152	0.4314	0.8369	0.063*
H9B	1.1671	0.4577	0.9034	0.063*
C10	1.1101 (5)	0.4685 (4)	0.7505 (5)	0.0546 (12)
H10A	1.1892	0.4646	0.7480	0.065*
H10B	1.1247	0.5472	0.7842	0.065*
C11	0.9918 (5)	0.4057 (4)	0.6271 (4)	0.0464 (11)
H11A	1.0112	0.4363	0.5790	0.056*
H11B	0.9150	0.4167	0.6289	0.056*
C12	0.9590 (4)	0.2795 (3)	0.5726 (4)	0.0386 (9)
H12A	1.0321	0.2677	0.5633	0.046*
H12B	0.8800	0.2411	0.4956	0.046*
C13	0.7286 (4)	0.0160 (3)	0.4472 (3)	0.0293 (8)
H13A	0.6956	0.0720	0.4368	0.035*
H13B	0.6602	−0.0456	0.4390	0.035*
C14	0.8012 (4)	0.0560 (3)	0.2753 (3)	0.0335 (8)
H14	0.8846	0.1235	0.3305	0.040*
C15	0.6897 (5)	0.0984 (4)	0.2447 (4)	0.0454 (10)
H15A	0.6043	0.0346	0.1902	0.054*
H15B	0.6880	0.1393	0.3152	0.054*
C16	0.7128 (6)	0.1755 (5)	0.1900 (5)	0.0652 (15)
H16A	0.6387	0.1972	0.1666	0.078*
H16B	0.7929	0.2435	0.2483	0.078*
C17	0.7267 (7)	0.1190 (6)	0.0840 (5)	0.0727 (17)
H17A	0.6430	0.0560	0.0220	0.087*
H17B	0.7468	0.1723	0.0553	0.087*
C18	0.8359 (6)	0.0772 (5)	0.1145 (5)	0.0605 (14)
H18A	0.9209	0.1411	0.1704	0.073*
H18B	0.8391	0.0380	0.0444	0.073*
C19	0.8127 (5)	−0.0021 (4)	0.1666 (4)	0.0435 (10)
H19A	0.8861	−0.0249	0.1884	0.052*
H19B	0.7316	−0.0693	0.1084	0.052*
C20	0.6788 (4)	−0.1790 (3)	0.2369 (3)	0.0337 (9)
H20	0.7151	−0.2030	0.1855	0.040*
C21	0.6729 (4)	−0.2585 (3)	0.2924 (4)	0.0399 (9)
H21A	0.7622	−0.2505	0.3399	0.048*
H21B	0.6355	−0.2386	0.3429	0.048*
C22	0.5874 (5)	−0.3804 (4)	0.1970 (5)	0.0530 (12)
H22A	0.6298	−0.4019	0.1514	0.064*
H22B	0.5817	−0.4292	0.2333	0.064*
C23	0.4481 (5)	−0.3971 (4)	0.1160 (5)	0.0621 (14)
H23A	0.3995	−0.4741	0.0535	0.074*
H23B	0.4014	−0.3849	0.1594	0.074*
C24	0.4523 (5)	−0.3167 (4)	0.0637 (5)	0.0653 (15)
H24A	0.3624	−0.3256	0.0170	0.078*
H24B	0.4889	−0.3355	0.0123	0.078*
C25	0.5371 (4)	−0.1934 (4)	0.1587 (4)	0.0505 (12)
H25A	0.4966	−0.1721	0.2062	0.061*
H25B	0.5410	−0.1446	0.1222	0.061*
Cl1	0.60680 (11)	0.28215 (11)	0.59639 (12)	0.0555 (3)
O1	0.6474 (4)	0.2532 (4)	0.5110 (4)	0.0807 (12)
O2	0.7214 (4)	0.3443 (4)	0.7094 (4)	0.1045 (18)
O3	0.5308 (5)	0.1819 (4)	0.5900 (5)	0.1012 (16)
O4	0.5238 (6)	0.3389 (5)	0.5734 (6)	0.119 (2)
Cl2	0.8751 (6)	0.6324 (5)	0.5976 (4)	0.0879 (15)	0.651 (12)
Cl3	0.5192 (4)	0.3699 (5)	0.2892 (6)	0.148 (3)	0.651 (12)
C26	0.7008 (11)	0.5505 (14)	0.4883 (14)	0.151 (6)	0.651 (12)
H26A	0.6491	0.5360	0.5254	0.182*	0.651 (12)
H26B	0.6682	0.5915	0.4473	0.182*	0.651 (12)
C27	0.6876 (10)	0.4420 (13)	0.4044 (12)	0.128 (5)	0.651 (12)
H27A	0.7106	0.3970	0.4435	0.153*	0.651 (12)
H27B	0.7466	0.4563	0.3736	0.153*	0.651 (12)
Cl2'	0.838 (2)	0.6253 (14)	0.551 (2)	0.202 (9)	0.349 (12)
Cl3'	0.599 (3)	0.3812 (11)	0.2986 (16)	0.238 (11)	0.349 (12)
C26'	0.737 (3)	0.536 (4)	0.546 (3)	0.196 (11)	0.349 (12)
H26C	0.7170	0.5691	0.6070	0.236*	0.349 (12)
H26D	0.7730	0.4831	0.5612	0.236*	0.349 (12)
C27'	0.608 (2)	0.472 (2)	0.430 (2)	0.099 (6)	0.349 (12)
H27C	0.5772	0.5271	0.4147	0.118*	0.349 (12)
H27D	0.5443	0.4263	0.4415	0.118*	0.349 (12)
Cl4	1.0607 (2)	0.6712 (2)	0.9977 (2)	0.1344 (10)
Cl5	0.8417 (5)	0.7783 (4)	0.9664 (3)	0.0907 (16)	0.523 (9)
C28	0.9252 (11)	0.6394 (15)	0.8645 (9)	0.096 (4)	0.523 (9)
H28A	0.9467	0.6978	0.8420	0.115*	0.523 (9)
H28B	0.9068	0.5684	0.8033	0.115*	0.523 (9)
C29	0.8035 (14)	0.6313 (9)	0.8782 (15)	0.095 (5)	0.523 (9)
H29A	0.7927	0.5871	0.9183	0.113*	0.523 (9)
H29B	0.7234	0.5981	0.8028	0.113*	0.523 (9)
Cl5'	0.7717 (6)	0.7307 (5)	0.9575 (4)	0.0987 (18)	0.477 (9)
C28'	0.8924 (15)	0.5940 (13)	0.8895 (14)	0.083 (4)	0.477 (9)
H28C	0.8894	0.5400	0.8221	0.100*	0.477 (9)
H28D	0.8508	0.5507	0.9186	0.100*	0.477 (9)
C29'	0.804 (2)	0.6488 (19)	0.8447 (19)	0.125 (8)	0.477 (9)
H29C	0.7204	0.5914	0.7764	0.151*	0.477 (9)
H29D	0.8461	0.6984	0.8210	0.151*	0.477 (9)

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Pt1	0.02457 (11)	0.02354 (12)	0.02328 (11)	0.00966 (8)	0.01119 (8)	0.00986 (8)
P1	0.0264 (5)	0.0249 (5)	0.0255 (5)	0.0103 (4)	0.0130 (4)	0.0105 (4)
P2	0.0255 (5)	0.0294 (5)	0.0239 (5)	0.0117 (4)	0.0104 (4)	0.0113 (4)
C1	0.034 (2)	0.032 (2)	0.032 (2)	0.0140 (17)	0.0191 (17)	0.0157 (17)
C2	0.051 (3)	0.036 (2)	0.049 (3)	0.021 (2)	0.031 (2)	0.023 (2)
C3	0.069 (3)	0.047 (3)	0.067 (3)	0.027 (3)	0.041 (3)	0.039 (3)
C4	0.060 (3)	0.063 (3)	0.057 (3)	0.018 (3)	0.036 (3)	0.035 (3)
C5	0.066 (3)	0.064 (3)	0.058 (3)	0.031 (3)	0.047 (3)	0.033 (3)
C6	0.050 (3)	0.048 (3)	0.048 (3)	0.026 (2)	0.034 (2)	0.026 (2)
C7	0.0308 (19)	0.0251 (19)	0.034 (2)	0.0131 (16)	0.0174 (17)	0.0113 (16)
C8	0.040 (2)	0.033 (2)	0.035 (2)	0.0119 (18)	0.0128 (19)	0.0117 (18)
C9	0.052 (3)	0.033 (2)	0.046 (3)	0.008 (2)	0.016 (2)	0.005 (2)
C10	0.051 (3)	0.033 (2)	0.067 (3)	0.011 (2)	0.025 (3)	0.019 (2)
C11	0.051 (3)	0.037 (2)	0.059 (3)	0.021 (2)	0.029 (2)	0.027 (2)
C12	0.042 (2)	0.035 (2)	0.041 (2)	0.0158 (19)	0.023 (2)	0.0179 (19)
C13	0.0277 (19)	0.0290 (19)	0.0292 (19)	0.0106 (16)	0.0139 (16)	0.0122 (16)
C14	0.036 (2)	0.037 (2)	0.031 (2)	0.0170 (18)	0.0158 (17)	0.0186 (18)
C15	0.050 (3)	0.051 (3)	0.048 (3)	0.030 (2)	0.026 (2)	0.030 (2)
C16	0.082 (4)	0.070 (4)	0.075 (4)	0.052 (3)	0.041 (3)	0.052 (3)
C17	0.089 (4)	0.099 (5)	0.069 (4)	0.054 (4)	0.044 (3)	0.065 (4)
C18	0.072 (4)	0.082 (4)	0.057 (3)	0.039 (3)	0.042 (3)	0.047 (3)
C19	0.050 (3)	0.055 (3)	0.036 (2)	0.028 (2)	0.024 (2)	0.024 (2)
C20	0.031 (2)	0.031 (2)	0.0284 (19)	0.0122 (16)	0.0103 (16)	0.0082 (16)
C21	0.037 (2)	0.035 (2)	0.038 (2)	0.0109 (18)	0.0155 (19)	0.0144 (19)
C22	0.050 (3)	0.034 (2)	0.056 (3)	0.009 (2)	0.021 (2)	0.014 (2)
C23	0.043 (3)	0.042 (3)	0.060 (3)	0.001 (2)	0.014 (2)	0.007 (2)
C24	0.039 (3)	0.055 (3)	0.050 (3)	0.006 (2)	−0.003 (2)	0.008 (3)
C25	0.032 (2)	0.045 (3)	0.047 (3)	0.013 (2)	0.004 (2)	0.014 (2)
Cl1	0.0404 (6)	0.0521 (7)	0.0759 (8)	0.0223 (5)	0.0311 (6)	0.0269 (6)
O1	0.069 (3)	0.108 (3)	0.082 (3)	0.048 (3)	0.047 (2)	0.042 (3)
O2	0.059 (3)	0.105 (4)	0.083 (3)	0.017 (3)	0.028 (2)	−0.006 (3)
O3	0.076 (3)	0.082 (3)	0.155 (5)	0.022 (3)	0.063 (3)	0.067 (3)
O4	0.136 (5)	0.136 (5)	0.191 (6)	0.113 (4)	0.113 (5)	0.114 (5)
Cl2	0.109 (3)	0.075 (2)	0.076 (2)	0.047 (2)	0.042 (2)	0.0303 (17)
Cl3	0.088 (3)	0.111 (3)	0.193 (6)	0.018 (2)	0.019 (3)	0.091 (4)
C26	0.151 (6)	0.151 (6)	0.151 (6)	0.063 (3)	0.075 (3)	0.070 (3)
C27	0.128 (5)	0.128 (5)	0.128 (5)	0.053 (2)	0.064 (3)	0.060 (3)
Cl2'	0.30 (2)	0.135 (10)	0.35 (2)	0.110 (13)	0.29 (2)	0.142 (14)
Cl3'	0.48 (3)	0.104 (9)	0.255 (18)	0.134 (14)	0.29 (2)	0.075 (10)
C26'	0.196 (11)	0.196 (11)	0.196 (11)	0.081 (5)	0.098 (6)	0.091 (5)
C27'	0.099 (6)	0.099 (6)	0.099 (6)	0.040 (3)	0.050 (3)	0.046 (3)
Cl4	0.1075 (16)	0.1012 (16)	0.1239 (18)	0.0085 (12)	0.0673 (15)	−0.0116 (13)
Cl5	0.0954 (18)	0.0886 (18)	0.0874 (17)	0.0457 (12)	0.0412 (11)	0.0396 (10)
C28	0.096 (4)	0.096 (5)	0.095 (4)	0.039 (2)	0.048 (2)	0.045 (2)
C29	0.095 (5)	0.094 (5)	0.094 (5)	0.039 (2)	0.047 (3)	0.044 (2)
Cl5'	0.100 (2)	0.100 (2)	0.096 (2)	0.0467 (13)	0.0492 (12)	0.0407 (11)
C28'	0.083 (4)	0.083 (4)	0.083 (4)	0.034 (2)	0.042 (2)	0.038 (2)
C29'	0.126 (8)	0.126 (8)	0.125 (8)	0.052 (3)	0.063 (4)	0.058 (4)

Geometric parameters (Å, º)

Pt1—P1^i	2.3450 (9)	C17—H17A	0.9700
Pt1—P1	2.3451 (9)	C17—H17B	0.9700
Pt1—P2	2.3558 (9)	C18—C19	1.528 (7)
Pt1—P2^i	2.3558 (9)	C18—H18A	0.9700
P1—C1	1.835 (4)	C18—H18B	0.9700
P1—C7	1.835 (4)	C19—H19A	0.9700
P1—C13	1.839 (4)	C19—H19B	0.9700
P2—C20	1.839 (4)	C20—C21	1.538 (6)
P2—C13	1.843 (4)	C20—C25	1.540 (6)
P2—C14	1.850 (4)	C20—H20	0.9800
C1—C6	1.529 (5)	C21—C22	1.526 (6)
C1—C2	1.532 (6)	C21—H21A	0.9700
C1—H1	0.9800	C21—H21B	0.9700
C2—C3	1.526 (6)	C22—C23	1.517 (7)
C2—H2A	0.9700	C22—H22A	0.9700
C2—H2B	0.9700	C22—H22B	0.9700
C3—C4	1.515 (7)	C23—C24	1.514 (8)
C3—H3A	0.9700	C23—H23A	0.9700
C3—H3B	0.9700	C23—H23B	0.9700
C4—C5	1.513 (7)	C24—C25	1.537 (7)
C4—H4A	0.9700	C24—H24A	0.9700
C4—H4B	0.9700	C24—H24B	0.9700
C5—C6	1.528 (6)	C25—H25A	0.9700
C5—H5A	0.9700	C25—H25B	0.9700
C5—H5B	0.9700	Cl1—O4	1.405 (5)
C6—H6A	0.9700	Cl1—O2	1.416 (5)
C6—H6B	0.9700	Cl1—O3	1.418 (4)
C7—C8	1.525 (5)	Cl1—O1	1.426 (4)
C7—C12	1.534 (6)	Cl2—C26	1.809 (10)
C7—H7	0.9800	Cl3—C27	1.777 (9)
C8—C9	1.530 (6)	C26—C27	1.494 (10)
C8—H8A	0.9700	C26—H26A	0.9700
C8—H8B	0.9700	C26—H26B	0.9700
C9—C10	1.508 (7)	C27—H27A	0.9700
C9—H9A	0.9700	C27—H27B	0.9700
C9—H9B	0.9700	Cl2'—C26'	1.47 (4)
C10—C11	1.516 (7)	Cl3'—C27'	1.79 (2)
C10—H10A	0.9700	C26'—C27'	1.504 (10)
C10—H10B	0.9700	C26'—H26C	0.9700
C11—C12	1.530 (6)	C26'—H26D	0.9700
C11—H11A	0.9700	C27'—H27C	0.9700
C11—H11B	0.9700	C27'—H27D	0.9700
C12—H12A	0.9700	Cl4—C28'	1.752 (15)
C12—H12B	0.9700	Cl4—C28	1.758 (9)
C13—H13A	0.9700	Cl5—C29	1.825 (9)
C13—H13B	0.9700	C28—C29	1.518 (9)
C14—C19	1.540 (6)	C28—H28A	0.9700
C14—C15	1.542 (6)	C28—H28B	0.9700
C14—H14	0.9800	C29—H29A	0.9700
C15—C16	1.530 (7)	C29—H29B	0.9700
C15—H15A	0.9700	Cl5'—C29'	1.84 (2)
C15—H15B	0.9700	C28'—C29'	1.497 (10)
C16—C17	1.522 (8)	C28'—H28C	0.9700
C16—H16A	0.9700	C28'—H28D	0.9700
C16—H16B	0.9700	C29'—H29C	0.9700
C17—C18	1.513 (8)	C29'—H29D	0.9700
P1^i—Pt1—P1	180.00 (2)	C15—C16—H16B	109.2
P1^i—Pt1—P2	108.32 (3)	H16A—C16—H16B	107.9
P1—Pt1—P2	71.68 (3)	C18—C17—C16	111.2 (4)
P1^i—Pt1—P2^i	71.69 (3)	C18—C17—H17A	109.4
P1—Pt1—P2^i	108.32 (3)	C16—C17—H17A	109.4
P2—Pt1—P2^i	180.0	C18—C17—H17B	109.4
C1—P1—C7	106.37 (18)	C16—C17—H17B	109.4
C1—P1—C13	107.64 (18)	H17A—C17—H17B	108.0
C7—P1—C13	105.85 (18)	C17—C18—C19	111.4 (4)
C1—P1—Pt1	120.52 (13)	C17—C18—H18A	109.3
C7—P1—Pt1	119.07 (13)	C19—C18—H18A	109.3
C13—P1—Pt1	95.22 (12)	C17—C18—H18B	109.3
C20—P2—C13	108.46 (18)	C19—C18—H18B	109.3
C20—P2—C14	108.45 (18)	H18A—C18—H18B	108.0
C13—P2—C14	108.99 (18)	C18—C19—C14	110.7 (4)
C20—P2—Pt1	118.98 (13)	C18—C19—H19A	109.5
C13—P2—Pt1	94.77 (12)	C14—C19—H19A	109.5
C14—P2—Pt1	115.82 (13)	C18—C19—H19B	109.5
C6—C1—C2	110.7 (3)	C14—C19—H19B	109.5
C6—C1—P1	112.2 (3)	H19A—C19—H19B	108.1
C2—C1—P1	112.5 (3)	C21—C20—C25	109.9 (4)
C6—C1—H1	107.0	C21—C20—P2	111.0 (3)
C2—C1—H1	107.0	C25—C20—P2	114.5 (3)
P1—C1—H1	107.0	C21—C20—H20	107.0
C3—C2—C1	110.4 (4)	C25—C20—H20	107.0
C3—C2—H2A	109.6	P2—C20—H20	107.0
C1—C2—H2A	109.6	C22—C21—C20	110.1 (4)
C3—C2—H2B	109.6	C22—C21—H21A	109.6
C1—C2—H2B	109.6	C20—C21—H21A	109.6
H2A—C2—H2B	108.1	C22—C21—H21B	109.6
C4—C3—C2	111.8 (4)	C20—C21—H21B	109.6
C4—C3—H3A	109.3	H21A—C21—H21B	108.2
C2—C3—H3A	109.3	C23—C22—C21	112.2 (4)
C4—C3—H3B	109.3	C23—C22—H22A	109.2
C2—C3—H3B	109.3	C21—C22—H22A	109.2
H3A—C3—H3B	107.9	C23—C22—H22B	109.2
C5—C4—C3	111.1 (4)	C21—C22—H22B	109.2
C5—C4—H4A	109.4	H22A—C22—H22B	107.9
C3—C4—H4A	109.4	C24—C23—C22	111.1 (4)
C5—C4—H4B	109.4	C24—C23—H23A	109.4
C3—C4—H4B	109.4	C22—C23—H23A	109.4
H4A—C4—H4B	108.0	C24—C23—H23B	109.4
C4—C5—C6	111.7 (4)	C22—C23—H23B	109.4
C4—C5—H5A	109.3	H23A—C23—H23B	108.0
C6—C5—H5A	109.3	C23—C24—C25	111.8 (4)
C4—C5—H5B	109.3	C23—C24—H24A	109.2
C6—C5—H5B	109.3	C25—C24—H24A	109.2
H5A—C5—H5B	107.9	C23—C24—H24B	109.2
C5—C6—C1	110.8 (4)	C25—C24—H24B	109.2
C5—C6—H6A	109.5	H24A—C24—H24B	107.9
C1—C6—H6A	109.5	C24—C25—C20	109.9 (4)
C5—C6—H6B	109.5	C24—C25—H25A	109.7
C1—C6—H6B	109.5	C20—C25—H25A	109.7
H6A—C6—H6B	108.1	C24—C25—H25B	109.7
C8—C7—C12	111.2 (3)	C20—C25—H25B	109.7
C8—C7—P1	112.5 (3)	H25A—C25—H25B	108.2
C12—C7—P1	112.7 (3)	O4—Cl1—O2	113.4 (4)
C8—C7—H7	106.6	O4—Cl1—O3	106.7 (3)
C12—C7—H7	106.6	O2—Cl1—O3	107.7 (4)
P1—C7—H7	106.6	O4—Cl1—O1	111.0 (3)
C7—C8—C9	110.6 (4)	O2—Cl1—O1	109.0 (3)
C7—C8—H8A	109.5	O3—Cl1—O1	109.0 (3)
C9—C8—H8A	109.5	C27—C26—Cl2	107.9 (9)
C7—C8—H8B	109.5	C27—C26—H26A	110.1
C9—C8—H8B	109.5	Cl2—C26—H26A	110.1
H8A—C8—H8B	108.1	C27—C26—H26B	110.1
C10—C9—C8	112.3 (4)	Cl2—C26—H26B	110.1
C10—C9—H9A	109.1	H26A—C26—H26B	108.4
C8—C9—H9A	109.1	C26—C27—Cl3	107.2 (9)
C10—C9—H9B	109.1	C26—C27—H27A	110.3
C8—C9—H9B	109.1	Cl3—C27—H27A	110.3
H9A—C9—H9B	107.9	C26—C27—H27B	110.3
C9—C10—C11	111.1 (4)	Cl3—C27—H27B	110.3
C9—C10—H10A	109.4	H27A—C27—H27B	108.5
C11—C10—H10A	109.4	Cl2'—C26'—C27'	114 (3)
C9—C10—H10B	109.4	Cl2'—C26'—H26C	108.7
C11—C10—H10B	109.4	C27'—C26'—H26C	108.7
H10A—C10—H10B	108.0	Cl2'—C26'—H26D	108.7
C10—C11—C12	111.5 (4)	C27'—C26'—H26D	108.7
C10—C11—H11A	109.3	H26C—C26'—H26D	107.6
C12—C11—H11A	109.3	C26'—C27'—Cl3'	122 (3)
C10—C11—H11B	109.3	C26'—C27'—H27C	106.8
C12—C11—H11B	109.3	Cl3'—C27'—H27C	106.8
H11A—C11—H11B	108.0	C26'—C27'—H27D	106.8
C11—C12—C7	110.5 (3)	Cl3'—C27'—H27D	106.8
C11—C12—H12A	109.6	H27C—C27'—H27D	106.7
C7—C12—H12A	109.6	C28'—Cl4—C28	29.5 (6)
C11—C12—H12B	109.6	C29—C28—Cl4	109.5 (10)
C7—C12—H12B	109.6	C29—C28—H28A	109.8
H12A—C12—H12B	108.1	Cl4—C28—H28A	109.8
P1—C13—P2	96.75 (17)	C29—C28—H28B	109.8
P1—C13—H13A	112.4	Cl4—C28—H28B	109.8
P2—C13—H13A	112.4	H28A—C28—H28B	108.2
P1—C13—H13B	112.4	C28—C29—Cl5	102.7 (9)
P2—C13—H13B	112.4	C28—C29—H29A	111.2
H13A—C13—H13B	110.0	Cl5—C29—H29A	111.2
C19—C14—C15	110.7 (3)	C28—C29—H29B	111.2
C19—C14—P2	110.7 (3)	Cl5—C29—H29B	111.2
C15—C14—P2	116.4 (3)	H29A—C29—H29B	109.1
C19—C14—H14	106.1	C29'—C28'—Cl4	122.6 (14)
C15—C14—H14	106.1	C29'—C28'—H28C	106.7
P2—C14—H14	106.1	Cl4—C28'—H28C	106.7
C16—C15—C14	110.3 (4)	C29'—C28'—H28D	106.7
C16—C15—H15A	109.6	Cl4—C28'—H28D	106.7
C14—C15—H15A	109.6	H28C—C28'—H28D	106.6
C16—C15—H15B	109.6	C28'—C29'—Cl5'	111.2 (15)
C14—C15—H15B	109.6	C28'—C29'—H29C	109.4
H15A—C15—H15B	108.1	Cl5'—C29'—H29C	109.4
C17—C16—C15	112.2 (5)	C28'—C29'—H29D	109.4
C17—C16—H16A	109.2	Cl5'—C29'—H29D	109.4
C15—C16—H16A	109.2	H29C—C29'—H29D	108.0
C17—C16—H16B	109.2
P1^i—Pt1—P1—C1	100 (13)	C10—C11—C12—C7	56.0 (5)
P2—Pt1—P1—C1	122.63 (16)	C8—C7—C12—C11	−55.9 (4)
P2^i—Pt1—P1—C1	−57.37 (16)	P1—C7—C12—C11	176.7 (3)
P1^i—Pt1—P1—C7	−125 (13)	C1—P1—C13—P2	−134.88 (17)
P2—Pt1—P1—C7	−102.77 (15)	C7—P1—C13—P2	111.68 (18)
P2^i—Pt1—P1—C7	77.23 (15)	Pt1—P1—C13—P2	−10.54 (15)
P1^i—Pt1—P1—C13	−14 (13)	C20—P2—C13—P1	133.19 (18)
P2—Pt1—P1—C13	8.61 (12)	C14—P2—C13—P1	−108.93 (19)
P2^i—Pt1—P1—C13	−171.39 (12)	Pt1—P2—C13—P1	10.48 (15)
P1^i—Pt1—P2—C20	57.25 (16)	C20—P2—C14—C19	−44.5 (3)
P1—Pt1—P2—C20	−122.75 (16)	C13—P2—C14—C19	−162.3 (3)
P2^i—Pt1—P2—C20	−72 (9)	Pt1—P2—C14—C19	92.3 (3)
P1^i—Pt1—P2—C13	171.42 (12)	C20—P2—C14—C15	83.1 (3)
P1—Pt1—P2—C13	−8.58 (12)	C13—P2—C14—C15	−34.8 (4)
P2^i—Pt1—P2—C13	43 (9)	Pt1—P2—C14—C15	−140.1 (3)
P1^i—Pt1—P2—C14	−74.81 (15)	C19—C14—C15—C16	−55.3 (5)
P1—Pt1—P2—C14	105.19 (15)	P2—C14—C15—C16	177.1 (3)
P2^i—Pt1—P2—C14	156 (9)	C14—C15—C16—C17	55.1 (6)
C7—P1—C1—C6	57.1 (3)	C15—C16—C17—C18	−55.4 (7)
C13—P1—C1—C6	−56.0 (3)	C16—C17—C18—C19	55.9 (7)
Pt1—P1—C1—C6	−163.3 (2)	C17—C18—C19—C14	−56.7 (6)
C7—P1—C1—C2	−177.3 (3)	C15—C14—C19—C18	56.4 (5)
C13—P1—C1—C2	69.6 (3)	P2—C14—C19—C18	−173.0 (3)
Pt1—P1—C1—C2	−37.7 (3)	C13—P2—C20—C21	−64.1 (3)
C6—C1—C2—C3	−56.3 (5)	C14—P2—C20—C21	177.7 (3)
P1—C1—C2—C3	177.3 (3)	Pt1—P2—C20—C21	42.4 (3)
C1—C2—C3—C4	56.2 (6)	C13—P2—C20—C25	61.1 (4)
C2—C3—C4—C5	−55.6 (6)	C14—P2—C20—C25	−57.2 (4)
C3—C4—C5—C6	55.1 (6)	Pt1—P2—C20—C25	167.6 (3)
C4—C5—C6—C1	−55.7 (6)	C25—C20—C21—C22	57.8 (5)
C2—C1—C6—C5	56.1 (5)	P2—C20—C21—C22	−174.5 (3)
P1—C1—C6—C5	−177.3 (3)	C20—C21—C22—C23	−56.6 (5)
C1—P1—C7—C8	57.7 (3)	C21—C22—C23—C24	54.9 (6)
C13—P1—C7—C8	172.0 (3)	C22—C23—C24—C25	−54.8 (6)
Pt1—P1—C7—C8	−82.5 (3)	C23—C24—C25—C20	56.7 (6)
C1—P1—C7—C12	−175.5 (3)	C21—C20—C25—C24	−57.8 (5)
C13—P1—C7—C12	−61.2 (3)	P2—C20—C25—C24	176.4 (4)
Pt1—P1—C7—C12	44.2 (3)	Cl2—C26—C27—Cl3	−173.7 (10)
C12—C7—C8—C9	55.1 (5)	Cl2'—C26'—C27'—Cl3'	68 (4)
P1—C7—C8—C9	−177.3 (3)	C28'—Cl4—C28—C29	44.8 (12)
C7—C8—C9—C10	−55.0 (5)	Cl4—C28—C29—Cl5	73.4 (14)
C8—C9—C10—C11	55.1 (6)	C28—Cl4—C28'—C29'	−49.6 (17)
C9—C10—C11—C12	−55.6 (5)	Cl4—C28'—C29'—Cl5'	−69 (2)

Symmetry code: (i) −x+2, −y, −z+1.

Hydrogen-bond geometry (Å, º)

D—H···A	D—H	H···A	D···A	D—H···A
C7—H7···O2	0.98	2.56	3.502 (7)	161
C13—H13B···O3^ii	0.97	2.38	3.346 (8)	171
C27—H27A···O1	0.97	2.54	3.421 (19)	151

Symmetry code: (ii) −x+1, −y, −z+1.