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Acta Cryst. (2006). E62, m2476-m2478 [ doi:10.1107/S1600536806035070 ]
![[mu]](/logos/entities/mu_rmgif.gif)
2-methanol)bis(methanol-![[kappa]](/logos/entities/kappa_rmgif.gif)
O)(2-tri-tert-butoxysilanethiolato-3S:S,O)bis(tri-tert-butoxysilanethiolato-2S,O)tetrasodium(I)Abstract: The title compound, [Na4(C12H27O3SSi)4(CH4O)6], may be regarded as an assembly of short-contact ion triplets built of a dinuclear [Na2(MeOH)6]2+ cation and two [Na{SSi(OtBu)3}2]- anions, related by a centre of symmetry. The presence of sulfur and oxygen bridges, as well as O-H
O and O-HS hydrogen bonds, results in a tetranuclear complex with all Na atoms pentacoordinated. The complex sits on a centre of symmetry.
Online 6 September 2006
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