Acta Cryst. (2006). E62, m2602-m2604  [ doi:10.1107/S1600536806036750 ]

Bis(tri-tert-butoxysilanethiolato-S)bis(pyrrolidine-N)cobalt(II)

A. Pladzyk and K. Baranowska

Abstract: The reaction of [Co{SSi(O^tBu)₃}₂(NH₃)]₂ with pyrrolidine leads to the formation of the title silanethiolate complex, [Co(C₁₂H₂₇O₃SSi)₂(C₄H₉N)₂], where the Co^II ion is coordinated by the two S atoms derived from the silanethiolate residues and the two N atoms of the pyrrolidine residues. The specific spatial arrangement of the pyrrolidine residues allows them to form two intramolecular N-HO hydrogen bonds.

Online 15 September 2006

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