Acta Cryst. (2006). E62, m2406-m2408  [ doi:10.1107/S1600536806034453 ]

catena-Poly[[(2-phenyl-1H-1,3,7,8,-tetraazacyclopenta[l]phenanthrene)manganese(II)]--succinato]

L. Wang, G.-B. Che and C.-B. Liu

Abstract: In the title compound, [Mn(C₄H₄O₄)(C₁₉H₁₂N₄)]_n or [Mn(suc)(L)]_n, where suc is the succinate dianion and L is 2-phenyl-1H-1,3,7,8-tetraazacyclopenta[l]phenanthrene, each Mn^II atom is five-coordinated by two N atoms from one bidentate L ligand and three O atoms from three suc anions in a distorted square-based pyramidal geometry, with the N atoms in the basal plane. The Mn^II atoms are bridged by the suc ligands, generating a one-dimensional chain structure. Neighboring chains interact through - contacts, leading to a two-dimensional supramolecular structure. N-HO hydrogen bonds complete the structure.

Online 6 September 2006

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