Acta Cryst. (2006). E62, m2642-m2644  [ doi:10.1107/S1600536806036634 ]

cis-Dichlorobis(tri-2-furylphosphine)palladium(II) dichloromethane hemisolvate

R. Meijboom and A. Muller

Abstract: In the title compound, cis-[PdCl₂{P(C₄H₃O)₃}₂]·0.5CH₂Cl₂, where P(C₄H₃O)₃ is tri-2-furylphosphine, the Pd^II centre shows a slightly distorted square-planar geometry with the two chloro ligands in cis positions. Pd-P bond lengths are 2.2329 (10) and 2.2613 (9) Å and Pd-Cl bond lengths are 2.3393 (9) and 2.3501 (10) Å. The P-Pd-Cl angles are 89.07 (4) and 175.28 (4)°. The average effective cone angle for the tri-2-furylphosphine was calculated to be 149°.

Online 20 September 2006

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