Acta Cryst. (2006). E62, m2567-m2569  [ doi:10.1107/S1600536806036373 ]

Tetrakis(triphenylarsine)silver(I) hexafluorophosphate

R. Meijboom, J. M. Janse van Rensburg, L. Kirsten and J. A. Viljoen

Abstract: The title compound, [Ag(AsC₁₈H₁₅)₄]PF₆, crystallizes with the cation on a threefold rotation axis and the anions on positions with site symmetry . The Ag atom is surrounded by four arsine ligands forming a distorted tetrahedral configuration. The Ag-As distances are 2.6381 (6) and 2.6499 (9) Å, and the As-Ag-As angles are 108.91 (1) and 110.03 (1)°.

Online 13 September 2006

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