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Acta Cryst. (2006). E62, m2761-m2763  [ doi:10.1107/S1600536806039122 ]

catena-Poly[[tris(benzimidazole)cadmium(II)]-[mu]-benzene-1,2-dicarboxylato]

Y.-C. Cui, J.-J. Wang, G.-B. Che and C.-B. Li

Abstract: In the title compound, [Cd(C8H4O4)(C7H6N2)3]n, the Cd atom is seven-coordinated by four O atoms from two benzene-1,2-dicarboxylate (1,2-BDC) ligands and three N atoms from three benzimidazole ligands, resulting in a distorted pentagonal-bipyramid geometry. The 1,2-BDC ligands bridge the Cd atoms to form an extended helical chain structure. Neighbouring chains interact through [pi]-[pi] interactions, resulting in a two-dimensional structure.

Online 30 September 2006


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