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Acta Cryst. (2006). E62, m2739-m2740  [ doi:10.1107/S1600536806038694 ]

Bis[1,3-dihydroxy-2-hydroxymethyl-2-(5-nitro-2-oxidobenzylideneamino)propane-[kappa]3N,O,O']nickel(II) pyridine solvate

H. M. Ali, S. Puvaneswary and S. W. Ng

Abstract: The NiII atom in the title complex, [Ni(C11H13N2O6)2]·C5H5N, is chelated by a terdentate Schiff base anion in a slightly octahedral geometry. One of the coordinated hydroxyl groups forms a hydrogen bond with the pyridine solvent molecule. In the crystal structure, other hydroxyl groups are involved in intermolecular hydrogen bonding, forming a two-dimensional layer.

Online 30 September 2006


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