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Acta Cryst. (2006). E62, m2509-m2511  [ doi:10.1107/S1600536806034428 ]

Tris(guanidinium) tris(pyridine-2,6-dicarboxylato-[kappa]3O,N,O)cerate(III) trihydrate

H. Aghabozorg, F. Mohammad Panah and E. Sadr-Khanlou

Abstract: The nine-coordinate cerium(III) complex with guanidinium as cation, (CH6N3)3[Ce(C7H3NO4)3]·3H2O or (GH)3[Ce(pydc)3]·3H2O (G = guanidine and pydc = pyridine-2,6-dicarboxylate), shows a tricapped trigonal-prismatic coordination. Hydrogen-bonding interactions between the cation, anion and water molecules result in a three-dimensional supramolecular network structure.

Online 8 September 2006


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