Acta Cryst. (2006). E62, m2743-m2744  [ doi:10.1107/S1600536806039092 ]

-3,3'-Bisacetylacetonato-bis[(1,10-phenanthroline)palladium(II)] bis(hexafluorophosphate) acetonitrile solvate

G.-Q. Mei, K.-L. Huang and H.-P. Huang

Abstract: In the title complex, [Pd₂(C₁₀H₁₂O₄)(C₁₂H₈N₂)₂](PF₆)₂·CH₃CN, the Pd^II centre has a distorted cis square-planar geometry defined by an O,O'-bidentate bisacetylacetonate dianion ligand and a chelating 1,10-phenanthroline ligand. The crystal structure features electrostatic interactions between the cations and anions, intermolecular - interactions between pairs of 1,10-phenanthroline rings, and weak hydrogen bonds involving hexafluorophosphate anions (C-HF) and the acetonitrile solvent molecules (C-HN).

Online 30 September 2006

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