Di-μ-acetato-bis­[(tri-p-tolyl­phosphine)silver(I)]

In the title compound, [Ag₂(O₂C₂H₃)₂(C₂₁H₂₁P)₂], the acetate groups function as bridging ligands to form a dimeric structure with approximate trigonal–planar geometry at the Ag^I atoms.

Key indicators

• Single-crystal X-ray study
• T = 293 K
• Mean [sigma](C-C) = 0.007 Å
• R factor = 0.045
• wR factor = 0.126
• Data-to-parameter ratio = 21.5

checkCIF/PLATON results

No syntax errors found



Alert level B
PLAT241_ALERT_2_B Check High      Ueq as Compared to Neighbors for         O3
PLAT242_ALERT_2_B Check Low       Ueq as Compared to Neighbors for         C3

Alert level C
PLAT094_ALERT_2_C Ratio of Maximum / Minimum Residual Density ....       2.59
PLAT220_ALERT_2_C Large Non-Solvent    C     Ueq(max)/Ueq(min) ...       2.96 Ratio
PLAT222_ALERT_3_C Large Non-Solvent    H     Ueq(max)/Ueq(min) ...       3.14 Ratio
PLAT232_ALERT_2_C Hirshfeld Test Diff (M-X)  Ag2    -   O1      ..       5.16 su
PLAT242_ALERT_2_C Check Low       Ueq as Compared to Neighbors for         C1
PLAT242_ALERT_2_C Check Low       Ueq as Compared to Neighbors for        C14
PLAT242_ALERT_2_C Check Low       Ueq as Compared to Neighbors for        C24
PLAT242_ALERT_2_C Check Low       Ueq as Compared to Neighbors for        C54
PLAT242_ALERT_2_C Check Low       Ueq as Compared to Neighbors for        C64

Alert level G
PLAT199_ALERT_1_G Check the Reported _cell_measurement_temperature        293 K
PLAT200_ALERT_1_G Check the Reported _diffrn_ambient_temperature .        293 K

   0 ALERT level A = In general: serious problem
   2 ALERT level B = Potentially serious problem
   9 ALERT level C = Check and explain
   2 ALERT level G = General alerts; check

   2 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
  10 ALERT type 2 Indicator that the structure model may be wrong or deficient
   1 ALERT type 3 Indicator that the structure quality may be low
   0 ALERT type 4 Improvement, methodology, query or suggestion
   0 ALERT type 5 Informative message, check

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Computing details

Data collection: SMART-NT (Bruker, 1998); cell refinement: SAINT-Plus (Bruker, 1999); data reduction: SAINT-Plus and XPREP (Bruker, 1999); program(s) used to solve structure: SIR97 (Altomare et al., 1999); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: DIAMOND (Brandenburg & Putz, 2005); software used to prepare material for publication: WinGX (Farrugia, 1999).

Di-µ₂-acetato-bis[(tri-p-tolylphosphine)silver(I)]

Crystal data

[Ag2(C2H3O2)2(C14H21P)]	F(000) = 1920
Mr = 942.52	Dx = 1.449 Mg m^−3
Monoclinic, P2/c	Mo Kα radiation, λ = 0.71069 Å
Hall symbol: -P 2yc	Cell parameters from 963 reflections
a = 18.621 (5) Å	θ = 2.7–23.5°
b = 10.254 (5) Å	µ = 1.02 mm^−1
c = 23.481 (5) Å	T = 293 K
β = 105.456 (5)°	Cuboid, colourless
V = 4321 (3) Å^3	0.37 × 0.36 × 0.12 mm
Z = 4

Data collection

Bruker SMART CCD 1K area-detector diffractometer	10655 independent reflections
Radiation source: fine-focus sealed tube	5873 reflections with I > 2σ(I)
Graphite monochromator	Rint = 0.044
φ and ω scans	θmax = 28.3°, θmin = 1.8°
Absorption correction: multi-scan (SADABS; Bruker, 1998)	h = −24→12
Tmin = 0.704, Tmax = 0.887	k = −13→12
29517 measured reflections	l = −30→31

Refinement

Refinement on F^2	0 restraints
Least-squares matrix: full	H-atom parameters constrained
R[F^2 > 2σ(F^2)] = 0.045	w = 1/[σ^2(Fo^2) + (0.0509P)^2 + 2.6206P] where P = (Fo^2 + 2Fc^2)/3
wR(F^2) = 0.126	(Δ/σ)max = 0.003
S = 1.00	Δρmax = 1.81 e Å^−3
10655 reflections	Δρmin = −0.70 e Å^−3
495 parameters

Special details

Experimental. The intensity data was collected on a Siemens SMART CCD 1 K diffractometer using an exposure time of 10 s/frame. A total of 1315 frames were collected with a frame width of 0.3° covering up to θ = 28.32° with 99.0% completeness accomplished. The first 50 frames were recollected at the end of each data collection to check for decay; none was found.

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq
C1	0.3129 (3)	0.7364 (4)	0.28231 (19)	0.0558 (11)
C2	0.3581 (3)	0.6261 (5)	0.3165 (2)	0.0844 (16)
H2A	0.409	0.6535	0.3315	0.127*
H2B	0.356	0.5524	0.2909	0.127*
H2C	0.3383	0.6022	0.3488	0.127*
C3	0.1257 (3)	0.6785 (4)	0.18523 (19)	0.0587 (11)
C4	0.0710 (3)	0.6075 (6)	0.2089 (3)	0.114 (2)
H4A	0.0677	0.6479	0.245	0.17*
H4B	0.0866	0.5185	0.2165	0.17*
H4C	0.0231	0.61	0.1806	0.17*
C11	0.1749 (2)	1.2614 (4)	0.26607 (17)	0.0456 (9)
C12	0.1042 (2)	1.2491 (4)	0.27388 (19)	0.0578 (11)
H12	0.0691	1.1974	0.248	0.069*
C13	0.0851 (2)	1.3126 (5)	0.3196 (2)	0.0672 (12)
H13	0.0374	1.302	0.3243	0.081*
C14	0.1354 (2)	1.3916 (5)	0.35853 (18)	0.0590 (11)
C15	0.2062 (3)	1.4014 (5)	0.35093 (19)	0.0650 (12)
H15	0.2414	1.453	0.3768	0.078*
C16	0.2260 (2)	1.3372 (4)	0.30624 (18)	0.0586 (11)
H16	0.2744	1.3446	0.3028	0.07*
C17	0.1150 (3)	1.4604 (6)	0.4085 (2)	0.0968 (19)
H17A	0.1251	1.4043	0.4424	0.145*
H17B	0.063	1.4821	0.3969	0.145*
H17C	0.144	1.5387	0.4181	0.145*
C21	0.2820 (2)	1.2357 (4)	0.19573 (17)	0.0461 (9)
C22	0.2927 (2)	1.3695 (4)	0.19240 (18)	0.0553 (10)
H22	0.2566	1.427	0.198	0.066*
C23	0.3568 (3)	1.4173 (4)	0.18080 (19)	0.0620 (12)
H23	0.3633	1.507	0.179	0.074*
C24	0.4110 (3)	1.3353 (5)	0.17189 (19)	0.0641 (12)
C25	0.3996 (3)	1.2045 (5)	0.1746 (2)	0.0740 (14)
H25	0.4353	1.1475	0.1678	0.089*
C26	0.3370 (2)	1.1537 (4)	0.18706 (19)	0.0610 (11)
H26	0.3318	1.0639	0.1896	0.073*
C27	0.4805 (3)	1.3906 (7)	0.1584 (3)	0.105 (2)
H27A	0.5114	1.431	0.1933	0.157*
H27B	0.4663	1.4543	0.1275	0.157*
H27C	0.5076	1.3215	0.146	0.157*
C31	0.1248 (2)	1.1937 (4)	0.14181 (17)	0.0481 (9)
C32	0.0741 (2)	1.0948 (4)	0.11936 (19)	0.0585 (11)
H32	0.0781	1.0152	0.139	0.07*
C33	0.0177 (3)	1.1140 (5)	0.06785 (19)	0.0648 (12)
H33	−0.0163	1.0472	0.0542	0.078*
C34	0.0105 (3)	1.2280 (4)	0.03662 (19)	0.0611 (12)
C35	0.0610 (3)	1.3253 (4)	0.0588 (2)	0.0678 (13)
H35	0.0577	1.4037	0.0384	0.081*
C36	0.1171 (3)	1.3095 (4)	0.1113 (2)	0.0626 (12)
H36	0.1497	1.3779	0.1257	0.075*
C37	−0.0492 (3)	1.2474 (5)	−0.0208 (2)	0.0908 (18)
H37A	−0.034	1.2062	−0.0524	0.136*
H37B	−0.0564	1.3389	−0.0288	0.136*
H37C	−0.095	1.2092	−0.0176	0.136*
C41	0.3963 (2)	0.8778 (4)	0.08948 (15)	0.0452 (9)
C42	0.4422 (2)	0.8521 (4)	0.14584 (17)	0.0536 (10)
H42	0.4257	0.7975	0.1713	0.064*
C43	0.5123 (2)	0.9079 (4)	0.16380 (18)	0.0586 (11)
H43	0.5429	0.8877	0.201	0.07*
C44	0.5376 (2)	0.9919 (4)	0.12825 (17)	0.0506 (10)
C45	0.4916 (2)	1.0185 (4)	0.07306 (18)	0.0558 (11)
H45	0.5078	1.0752	0.0482	0.067*
C46	0.4218 (2)	0.9627 (4)	0.05394 (17)	0.0550 (11)
H46	0.3917	0.9828	0.0166	0.066*
C47	0.6136 (3)	1.0565 (5)	0.1485 (2)	0.0790 (15)
H47A	0.629	1.0595	0.1909	0.119*
H47B	0.6107	1.1436	0.1331	0.119*
H47C	0.6492	1.0073	0.1344	0.119*
C51	0.2517 (2)	0.9018 (4)	0.00712 (17)	0.0467 (9)
C52	0.2135 (3)	1.0068 (5)	0.0215 (2)	0.0689 (12)
H52	0.216	1.0232	0.0609	0.083*
C53	0.1718 (3)	1.0877 (5)	−0.0217 (3)	0.0812 (15)
H53	0.1477	1.1592	−0.0109	0.097*
C54	0.1654 (3)	1.0645 (5)	−0.0809 (2)	0.0680 (13)
C55	0.2035 (3)	0.9600 (5)	−0.0949 (2)	0.0692 (13)
H55	0.2011	0.9437	−0.1343	0.083*
C56	0.2454 (2)	0.8787 (4)	−0.05187 (17)	0.0583 (11)
H56	0.2697	0.8075	−0.0628	0.07*
C57	0.1186 (4)	1.1512 (7)	−0.1297 (3)	0.119 (2)
H57A	0.1508	1.1985	−0.1481	0.178*
H57B	0.0905	1.2115	−0.1129	0.178*
H57C	0.0852	1.098	−0.1586	0.178*
C61	0.3233 (2)	0.6473 (4)	0.03345 (17)	0.0539 (10)
C62	0.3786 (3)	0.6308 (5)	0.0042 (2)	0.0670 (12)
H62	0.4077	0.7016	−0.0005	0.08*
C63	0.3908 (3)	0.5093 (6)	−0.0180 (2)	0.0790 (15)
H63	0.4277	0.5003	−0.0377	0.095*
C64	0.3490 (4)	0.4022 (5)	−0.0113 (2)	0.0844 (17)
C65	0.2946 (4)	0.4181 (5)	0.0175 (2)	0.0886 (18)
H65	0.2658	0.347	0.0224	0.106*
C66	0.2819 (3)	0.5381 (5)	0.0392 (2)	0.0690 (13)
H66	0.2444	0.5462	0.0584	0.083*
C67	0.3660 (5)	0.2696 (5)	−0.0333 (3)	0.134 (3)
H67A	0.3273	0.2462	−0.0677	0.201*
H67B	0.3686	0.2057	−0.0029	0.201*
H67C	0.4128	0.273	−0.0431	0.201*
O1	0.32931 (18)	0.7763 (3)	0.23721 (14)	0.0754 (9)
O2	0.2626 (2)	0.7844 (3)	0.30126 (14)	0.0684 (8)
O3	0.1232 (2)	0.7982 (3)	0.18108 (18)	0.1057 (15)
O4	0.17277 (19)	0.6122 (3)	0.16926 (15)	0.0751 (9)
P1	0.19871 (6)	1.16310 (10)	0.20889 (5)	0.0472 (3)
P2	0.30518 (6)	0.80006 (11)	0.06660 (4)	0.0504 (3)
Ag1	0.21343 (2)	0.94313 (3)	0.237484 (15)	0.06124 (12)
Ag2	0.24707 (2)	0.75609 (4)	0.141290 (15)	0.06766 (13)

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
C1	0.061 (3)	0.049 (2)	0.052 (2)	−0.007 (2)	0.005 (2)	−0.002 (2)
C2	0.093 (4)	0.059 (3)	0.093 (4)	0.011 (3)	0.010 (3)	0.013 (3)
C3	0.061 (3)	0.048 (3)	0.059 (3)	−0.008 (2)	0.001 (2)	0.004 (2)
C4	0.090 (4)	0.116 (5)	0.161 (6)	0.016 (4)	0.079 (4)	0.036 (5)
C11	0.038 (2)	0.046 (2)	0.048 (2)	0.0001 (17)	0.0054 (17)	0.0074 (17)
C12	0.044 (2)	0.066 (3)	0.059 (3)	−0.010 (2)	0.007 (2)	−0.013 (2)
C13	0.041 (2)	0.095 (4)	0.066 (3)	−0.007 (2)	0.015 (2)	−0.005 (3)
C14	0.056 (3)	0.073 (3)	0.050 (2)	−0.004 (2)	0.018 (2)	−0.003 (2)
C15	0.062 (3)	0.077 (3)	0.054 (3)	−0.024 (2)	0.012 (2)	−0.015 (2)
C16	0.043 (2)	0.072 (3)	0.059 (3)	−0.014 (2)	0.010 (2)	−0.004 (2)
C17	0.092 (4)	0.124 (5)	0.080 (4)	−0.016 (4)	0.033 (3)	−0.031 (3)
C21	0.041 (2)	0.046 (2)	0.049 (2)	0.0027 (17)	0.0077 (18)	−0.0015 (17)
C22	0.049 (2)	0.053 (3)	0.064 (3)	0.007 (2)	0.015 (2)	0.005 (2)
C23	0.058 (3)	0.062 (3)	0.064 (3)	−0.008 (2)	0.012 (2)	0.010 (2)
C24	0.052 (3)	0.083 (3)	0.059 (3)	−0.010 (3)	0.017 (2)	−0.003 (2)
C25	0.054 (3)	0.088 (4)	0.087 (3)	0.011 (3)	0.029 (3)	−0.013 (3)
C26	0.055 (3)	0.054 (3)	0.072 (3)	0.003 (2)	0.015 (2)	−0.012 (2)
C27	0.071 (4)	0.139 (5)	0.114 (5)	−0.016 (4)	0.041 (3)	0.006 (4)
C31	0.047 (2)	0.043 (2)	0.050 (2)	0.0028 (18)	0.0046 (18)	−0.0039 (17)
C32	0.057 (3)	0.051 (2)	0.062 (3)	−0.007 (2)	0.006 (2)	−0.001 (2)
C33	0.059 (3)	0.060 (3)	0.064 (3)	−0.011 (2)	−0.002 (2)	−0.011 (2)
C34	0.056 (3)	0.063 (3)	0.055 (2)	0.011 (2)	−0.002 (2)	−0.012 (2)
C35	0.072 (3)	0.049 (3)	0.070 (3)	0.007 (2)	−0.001 (3)	0.007 (2)
C36	0.060 (3)	0.047 (2)	0.069 (3)	−0.008 (2)	−0.004 (2)	−0.002 (2)
C37	0.091 (4)	0.083 (4)	0.073 (3)	0.011 (3)	−0.022 (3)	−0.008 (3)
C41	0.042 (2)	0.055 (2)	0.041 (2)	−0.0030 (18)	0.0145 (17)	−0.0040 (17)
C42	0.053 (3)	0.060 (3)	0.047 (2)	0.003 (2)	0.012 (2)	0.0075 (19)
C43	0.044 (2)	0.077 (3)	0.047 (2)	0.002 (2)	−0.0007 (19)	0.005 (2)
C44	0.039 (2)	0.060 (2)	0.051 (2)	0.0022 (19)	0.0072 (19)	−0.007 (2)
C45	0.055 (3)	0.064 (3)	0.051 (2)	−0.010 (2)	0.018 (2)	0.003 (2)
C46	0.049 (2)	0.072 (3)	0.041 (2)	−0.010 (2)	0.0083 (19)	0.0019 (19)
C47	0.049 (3)	0.101 (4)	0.081 (3)	−0.011 (3)	0.007 (3)	−0.003 (3)
C51	0.041 (2)	0.052 (2)	0.048 (2)	−0.0066 (18)	0.0136 (18)	−0.0035 (18)
C52	0.066 (3)	0.083 (3)	0.062 (3)	0.002 (3)	0.025 (2)	−0.013 (3)
C53	0.076 (4)	0.073 (3)	0.101 (4)	0.021 (3)	0.035 (3)	−0.006 (3)
C54	0.053 (3)	0.072 (3)	0.078 (3)	0.005 (2)	0.017 (2)	0.012 (3)
C55	0.070 (3)	0.080 (3)	0.052 (3)	0.004 (3)	0.007 (2)	−0.002 (2)
C56	0.064 (3)	0.062 (3)	0.046 (2)	0.007 (2)	0.010 (2)	−0.005 (2)
C57	0.103 (5)	0.127 (6)	0.123 (5)	0.043 (4)	0.026 (4)	0.052 (4)
C61	0.054 (3)	0.058 (3)	0.045 (2)	0.000 (2)	0.005 (2)	0.0055 (19)
C62	0.063 (3)	0.067 (3)	0.071 (3)	0.000 (2)	0.016 (2)	−0.001 (2)
C63	0.078 (4)	0.079 (4)	0.074 (3)	0.019 (3)	0.010 (3)	−0.007 (3)
C64	0.108 (5)	0.056 (3)	0.071 (3)	0.011 (3)	−0.009 (3)	0.007 (3)
C65	0.119 (5)	0.057 (3)	0.076 (4)	−0.019 (3)	0.002 (4)	0.015 (3)
C66	0.077 (3)	0.065 (3)	0.060 (3)	−0.012 (3)	0.010 (2)	0.012 (2)
C67	0.200 (8)	0.062 (4)	0.125 (6)	0.037 (4)	0.016 (6)	−0.003 (3)
O1	0.063 (2)	0.108 (3)	0.0535 (18)	−0.0179 (18)	0.0114 (16)	0.0101 (17)
O2	0.082 (2)	0.0602 (19)	0.0668 (19)	0.0099 (17)	0.0256 (18)	0.0100 (15)
O3	0.104 (3)	0.0413 (19)	0.133 (3)	0.0003 (18)	−0.036 (2)	−0.0016 (19)
O4	0.074 (2)	0.068 (2)	0.096 (2)	−0.0101 (18)	0.045 (2)	−0.0028 (18)
P1	0.0411 (6)	0.0417 (6)	0.0543 (6)	0.0006 (4)	0.0047 (5)	0.0005 (4)
P2	0.0490 (6)	0.0622 (7)	0.0408 (5)	−0.0108 (5)	0.0130 (5)	−0.0004 (5)
Ag1	0.0659 (2)	0.04512 (18)	0.0699 (2)	0.00647 (16)	0.01319 (18)	0.00499 (15)
Ag2	0.0653 (2)	0.0889 (3)	0.0556 (2)	−0.01477 (19)	0.02793 (17)	0.00420 (18)

Geometric parameters (Å, º)

C1—O2	1.242 (5)	C37—H37B	0.96
C1—O1	1.247 (5)	C37—H37C	0.96
C1—C2	1.507 (6)	C41—C46	1.375 (5)
C2—H2A	0.96	C41—C42	1.396 (5)
C2—H2B	0.96	C41—P2	1.821 (4)
C2—H2C	0.96	C42—C43	1.384 (6)
C3—O3	1.232 (5)	C42—H42	0.93
C3—O4	1.244 (5)	C43—C44	1.368 (6)
C3—C4	1.476 (7)	C43—H43	0.93
C4—H4A	0.96	C44—C45	1.377 (5)
C4—H4B	0.96	C44—C47	1.519 (6)
C4—H4C	0.96	C45—C46	1.380 (6)
C11—C12	1.383 (6)	C45—H45	0.93
C11—C16	1.386 (5)	C46—H46	0.93
C11—P1	1.825 (4)	C47—H47A	0.96
C12—C13	1.381 (6)	C47—H47B	0.96
C12—H12	0.93	C47—H47C	0.96
C13—C14	1.383 (6)	C51—C56	1.379 (5)
C13—H13	0.93	C51—C52	1.380 (6)
C14—C15	1.381 (6)	C51—P2	1.814 (4)
C14—C17	1.501 (7)	C52—C53	1.378 (7)
C15—C16	1.370 (6)	C52—H52	0.93
C15—H15	0.93	C53—C54	1.383 (7)
C16—H16	0.93	C53—H53	0.93
C17—H17A	0.96	C54—C55	1.372 (7)
C17—H17B	0.96	C54—C57	1.526 (7)
C17—H17C	0.96	C55—C56	1.380 (6)
C21—C26	1.382 (6)	C55—H55	0.93
C21—C22	1.392 (5)	C56—H56	0.93
C21—P1	1.819 (4)	C57—H57A	0.96
C22—C23	1.383 (6)	C57—H57B	0.96
C22—H22	0.93	C57—H57C	0.96
C23—C24	1.372 (6)	C61—C66	1.387 (6)
C23—H23	0.93	C61—C62	1.390 (6)
C24—C25	1.362 (7)	C61—P2	1.821 (4)
C24—C27	1.521 (7)	C62—C63	1.392 (7)
C25—C26	1.377 (6)	C62—H62	0.93
C25—H25	0.93	C63—C64	1.379 (8)
C26—H26	0.93	C63—H63	0.93
C27—H27A	0.96	C64—C65	1.370 (8)
C27—H27B	0.96	C64—C67	1.517 (8)
C27—H27C	0.96	C65—C66	1.376 (7)
C31—C36	1.375 (6)	C65—H65	0.93
C31—C32	1.390 (5)	C66—H66	0.93
C31—P1	1.822 (4)	C67—H67A	0.96
C32—C33	1.389 (6)	C67—H67B	0.96
C32—H32	0.93	C67—H67C	0.96
C33—C34	1.368 (6)	O1—Ag2	2.371 (3)
C33—H33	0.93	O2—Ag1	2.235 (3)
C34—C35	1.374 (6)	O3—Ag1	2.366 (3)
C34—C37	1.515 (6)	O4—Ag2	2.237 (3)
C35—C36	1.397 (6)	P1—Ag1	2.3485 (15)
C35—H35	0.93	P2—Ag2	2.3372 (12)
C36—H36	0.93	Ag1—Ag2	3.1507 (9)
C37—H37A	0.96
O2—C1—O1	123.6 (4)	C41—C42—H42	120
O2—C1—C2	118.4 (4)	C44—C43—C42	121.7 (4)
O1—C1—C2	118.0 (5)	C44—C43—H43	119.2
C1—C2—H2A	109.5	C42—C43—H43	119.2
C1—C2—H2B	109.5	C43—C44—C45	118.0 (4)
H2A—C2—H2B	109.5	C43—C44—C47	121.8 (4)
C1—C2—H2C	109.5	C45—C44—C47	120.2 (4)
H2A—C2—H2C	109.5	C44—C45—C46	121.3 (4)
H2B—C2—H2C	109.5	C44—C45—H45	119.3
O3—C3—O4	122.3 (5)	C46—C45—H45	119.3
O3—C3—C4	120.5 (5)	C41—C46—C45	120.8 (4)
O4—C3—C4	117.2 (4)	C41—C46—H46	119.6
C3—C4—H4A	109.5	C45—C46—H46	119.6
C3—C4—H4B	109.5	C44—C47—H47A	109.5
H4A—C4—H4B	109.5	C44—C47—H47B	109.5
C3—C4—H4C	109.5	H47A—C47—H47B	109.5
H4A—C4—H4C	109.5	C44—C47—H47C	109.5
H4B—C4—H4C	109.5	H47A—C47—H47C	109.5
C12—C11—C16	117.7 (4)	H47B—C47—H47C	109.5
C12—C11—P1	118.3 (3)	C56—C51—C52	117.9 (4)
C16—C11—P1	123.6 (3)	C56—C51—P2	123.8 (3)
C13—C12—C11	120.8 (4)	C52—C51—P2	118.3 (3)
C13—C12—H12	119.6	C53—C52—C51	121.0 (4)
C11—C12—H12	119.6	C53—C52—H52	119.5
C12—C13—C14	121.4 (4)	C51—C52—H52	119.5
C12—C13—H13	119.3	C52—C53—C54	121.1 (5)
C14—C13—H13	119.3	C52—C53—H53	119.5
C15—C14—C13	117.3 (4)	C54—C53—H53	119.5
C15—C14—C17	121.0 (4)	C55—C54—C53	117.6 (4)
C13—C14—C17	121.6 (4)	C55—C54—C57	120.2 (5)
C16—C15—C14	121.7 (4)	C53—C54—C57	122.2 (5)
C16—C15—H15	119.2	C54—C55—C56	121.6 (4)
C14—C15—H15	119.2	C54—C55—H55	119.2
C15—C16—C11	121.0 (4)	C56—C55—H55	119.2
C15—C16—H16	119.5	C51—C56—C55	120.7 (4)
C11—C16—H16	119.5	C51—C56—H56	119.6
C14—C17—H17A	109.5	C55—C56—H56	119.6
C14—C17—H17B	109.5	C54—C57—H57A	109.5
H17A—C17—H17B	109.5	C54—C57—H57B	109.5
C14—C17—H17C	109.5	H57A—C57—H57B	109.5
H17A—C17—H17C	109.5	C54—C57—H57C	109.5
H17B—C17—H17C	109.5	H57A—C57—H57C	109.5
C26—C21—C22	117.9 (4)	H57B—C57—H57C	109.5
C26—C21—P1	118.4 (3)	C66—C61—C62	117.0 (4)
C22—C21—P1	123.7 (3)	C66—C61—P2	118.8 (4)
C23—C22—C21	120.3 (4)	C62—C61—P2	124.2 (3)
C23—C22—H22	119.8	C61—C62—C63	120.7 (5)
C21—C22—H22	119.8	C61—C62—H62	119.7
C24—C23—C22	121.5 (4)	C63—C62—H62	119.7
C24—C23—H23	119.3	C64—C63—C62	121.1 (5)
C22—C23—H23	119.3	C64—C63—H63	119.4
C25—C24—C23	117.7 (4)	C62—C63—H63	119.4
C25—C24—C27	121.9 (5)	C65—C64—C63	118.4 (5)
C23—C24—C27	120.3 (5)	C65—C64—C67	121.6 (6)
C24—C25—C26	122.2 (4)	C63—C64—C67	120.0 (7)
C24—C25—H25	118.9	C64—C65—C66	120.8 (5)
C26—C25—H25	118.9	C64—C65—H65	119.6
C25—C26—C21	120.3 (4)	C66—C65—H65	119.6
C25—C26—H26	119.9	C65—C66—C61	122.1 (5)
C21—C26—H26	119.9	C65—C66—H66	119
C24—C27—H27A	109.5	C61—C66—H66	119
C24—C27—H27B	109.5	C64—C67—H67A	109.5
H27A—C27—H27B	109.5	C64—C67—H67B	109.5
C24—C27—H27C	109.5	H67A—C67—H67B	109.5
H27A—C27—H27C	109.5	C64—C67—H67C	109.5
H27B—C27—H27C	109.5	H67A—C67—H67C	109.5
C36—C31—C32	117.8 (4)	H67B—C67—H67C	109.5
C36—C31—P1	123.3 (3)	C1—O1—Ag2	122.4 (3)
C32—C31—P1	118.8 (3)	C1—O2—Ag1	105.2 (3)
C33—C32—C31	120.4 (4)	C3—O3—Ag1	125.2 (3)
C33—C32—H32	119.8	C3—O4—Ag2	105.6 (3)
C31—C32—H32	119.8	C21—P1—C31	105.33 (18)
C34—C33—C32	122.1 (4)	C21—P1—C11	106.50 (18)
C34—C33—H33	119	C31—P1—C11	105.39 (17)
C32—C33—H33	119	C21—P1—Ag1	113.69 (13)
C33—C34—C35	117.3 (4)	C31—P1—Ag1	114.62 (13)
C33—C34—C37	122.2 (4)	C11—P1—Ag1	110.65 (13)
C35—C34—C37	120.5 (4)	C51—P2—C61	106.98 (18)
C34—C35—C36	121.7 (4)	C51—P2—C41	104.65 (18)
C34—C35—H35	119.2	C61—P2—C41	103.81 (19)
C36—C35—H35	119.2	C51—P2—Ag2	114.80 (14)
C31—C36—C35	120.7 (4)	C61—P2—Ag2	109.30 (15)
C31—C36—H36	119.7	C41—P2—Ag2	116.37 (12)
C35—C36—H36	119.7	O2—Ag1—P1	152.43 (9)
C34—C37—H37A	109.5	O2—Ag1—O3	91.17 (12)
C34—C37—H37B	109.5	P1—Ag1—O3	115.59 (9)
H37A—C37—H37B	109.5	O2—Ag1—Ag2	85.01 (9)
C34—C37—H37C	109.5	P1—Ag1—Ag2	114.21 (4)
H37A—C37—H37C	109.5	O3—Ag1—Ag2	57.55 (12)
H37B—C37—H37C	109.5	O4—Ag2—P2	142.53 (9)
C46—C41—C42	118.1 (4)	O4—Ag2—O1	94.15 (12)
C46—C41—P2	122.9 (3)	P2—Ag2—O1	112.64 (9)
C42—C41—P2	119.0 (3)	O4—Ag2—Ag1	86.23 (9)
C43—C42—C41	120.0 (4)	P2—Ag2—Ag1	129.85 (4)
C43—C42—H42	120	O1—Ag2—Ag1	57.81 (9)
C16—C11—C12—C13	1.2 (6)	C26—C21—P1—Ag1	17.7 (4)
P1—C11—C12—C13	174.6 (3)	C22—C21—P1—Ag1	−164.0 (3)
C11—C12—C13—C14	0.8 (7)	C36—C31—P1—C21	−40.5 (4)
C12—C13—C14—C15	−1.9 (7)	C32—C31—P1—C21	138.2 (3)
C12—C13—C14—C17	−179.7 (5)	C36—C31—P1—C11	71.9 (4)
C13—C14—C15—C16	0.9 (7)	C32—C31—P1—C11	−109.4 (4)
C17—C14—C15—C16	178.7 (5)	C36—C31—P1—Ag1	−166.2 (3)
C14—C15—C16—C11	1.2 (7)	C32—C31—P1—Ag1	12.5 (4)
C12—C11—C16—C15	−2.2 (6)	C12—C11—P1—C21	163.6 (3)
P1—C11—C16—C15	−175.2 (3)	C16—C11—P1—C21	−23.5 (4)
C26—C21—C22—C23	−0.1 (6)	C12—C11—P1—C31	52.1 (4)
P1—C21—C22—C23	−178.4 (3)	C16—C11—P1—C31	−135.0 (3)
C21—C22—C23—C24	0.4 (7)	C12—C11—P1—Ag1	−72.4 (3)
C22—C23—C24—C25	0.3 (7)	C16—C11—P1—Ag1	100.5 (3)
C22—C23—C24—C27	179.2 (4)	C56—C51—P2—C61	−15.9 (4)
C23—C24—C25—C26	−1.4 (7)	C52—C51—P2—C61	162.6 (3)
C27—C24—C25—C26	179.7 (5)	C56—C51—P2—C41	93.8 (4)
C24—C25—C26—C21	1.8 (7)	C52—C51—P2—C41	−87.7 (4)
C22—C21—C26—C25	−1.0 (6)	C56—C51—P2—Ag2	−137.4 (3)
P1—C21—C26—C25	177.4 (4)	C52—C51—P2—Ag2	41.1 (4)
C36—C31—C32—C33	−0.3 (6)	C66—C61—P2—C51	−103.3 (3)
P1—C31—C32—C33	−179.1 (4)	C62—C61—P2—C51	79.3 (4)
C31—C32—C33—C34	1.5 (7)	C66—C61—P2—C41	146.4 (3)
C32—C33—C34—C35	−1.1 (7)	C62—C61—P2—C41	−31.0 (4)
C32—C33—C34—C37	177.6 (5)	C66—C61—P2—Ag2	21.6 (4)
C33—C34—C35—C36	−0.4 (7)	C62—C61—P2—Ag2	−155.8 (3)
C37—C34—C35—C36	−179.2 (5)	C46—C41—P2—C51	−20.5 (4)
C32—C31—C36—C35	−1.2 (7)	C42—C41—P2—C51	158.6 (3)
P1—C31—C36—C35	177.5 (4)	C46—C41—P2—C61	91.5 (4)
C34—C35—C36—C31	1.6 (8)	C42—C41—P2—C61	−89.4 (3)
C46—C41—C42—C43	−2.2 (6)	C46—C41—P2—Ag2	−148.4 (3)
P2—C41—C42—C43	178.6 (3)	C42—C41—P2—Ag2	30.7 (4)
C41—C42—C43—C44	2.1 (7)	C1—O2—Ag1—P1	−101.4 (3)
C42—C43—C44—C45	−1.0 (7)	C1—O2—Ag1—O3	92.1 (3)
C42—C43—C44—C47	178.1 (4)	C1—O2—Ag1—Ag2	34.9 (3)
C43—C44—C45—C46	0.2 (6)	C21—P1—Ag1—O2	67.9 (3)
C47—C44—C45—C46	−178.9 (4)	C31—P1—Ag1—O2	−170.9 (2)
C42—C41—C46—C45	1.4 (6)	C11—P1—Ag1—O2	−51.9 (3)
P2—C41—C46—C45	−179.5 (3)	C21—P1—Ag1—O3	−127.12 (19)
C44—C45—C46—C41	−0.4 (7)	C31—P1—Ag1—O3	−5.9 (2)
C56—C51—C52—C53	−1.4 (7)	C11—P1—Ag1—O3	113.10 (19)
P2—C51—C52—C53	−180.0 (4)	C21—P1—Ag1—Ag2	−63.03 (14)
C51—C52—C53—C54	1.6 (8)	C31—P1—Ag1—Ag2	58.21 (16)
C52—C53—C54—C55	−1.7 (8)	C11—P1—Ag1—Ag2	177.19 (13)
C52—C53—C54—C57	179.0 (5)	C3—O3—Ag1—O2	−14.7 (5)
C53—C54—C55—C56	1.6 (8)	C3—O3—Ag1—P1	172.2 (4)
C57—C54—C55—C56	−179.0 (5)	C3—O3—Ag1—Ag2	68.7 (5)
C52—C51—C56—C55	1.3 (7)	C3—O4—Ag2—P2	−134.7 (2)
P2—C51—C56—C55	179.8 (4)	C3—O4—Ag2—O1	88.5 (3)
C54—C55—C56—C51	−1.5 (7)	C3—O4—Ag2—Ag1	31.2 (3)
C66—C61—C62—C63	0.1 (6)	C51—P2—Ag2—O4	91.7 (2)
P2—C61—C62—C63	177.6 (3)	C61—P2—Ag2—O4	−28.5 (2)
C61—C62—C63—C64	−0.6 (7)	C41—P2—Ag2—O4	−145.6 (2)
C62—C63—C64—C65	0.5 (7)	C51—P2—Ag2—O1	−136.01 (17)
C62—C63—C64—C67	−177.0 (5)	C61—P2—Ag2—O1	103.80 (17)
C63—C64—C65—C66	0.0 (8)	C41—P2—Ag2—O1	−13.33 (18)
C67—C64—C65—C66	177.4 (5)	C51—P2—Ag2—Ag1	−69.83 (14)
C64—C65—C66—C61	−0.4 (8)	C61—P2—Ag2—Ag1	169.98 (13)
C62—C61—C66—C65	0.3 (6)	C41—P2—Ag2—Ag1	52.85 (15)
P2—C61—C66—C65	−177.2 (4)	C1—O1—Ag2—O4	−14.6 (4)
O2—C1—O1—Ag2	−66.6 (5)	C1—O1—Ag2—P2	−167.8 (3)
C2—C1—O1—Ag2	115.1 (4)	C1—O1—Ag2—Ag1	68.3 (4)
O1—C1—O2—Ag1	1.0 (5)	O2—Ag1—Ag2—O4	59.29 (13)
C2—C1—O2—Ag1	179.3 (3)	P1—Ag1—Ag2—O4	−141.27 (10)
O4—C3—O3—Ag1	−68.9 (6)	O3—Ag1—Ag2—O4	−35.29 (14)
C4—C3—O3—Ag1	112.1 (5)	O2—Ag1—Ag2—P2	−131.85 (10)
O3—C3—O4—Ag2	3.8 (5)	P1—Ag1—Ag2—P2	27.60 (5)
C4—C3—O4—Ag2	−177.1 (4)	O3—Ag1—Ag2—P2	133.57 (11)
C26—C21—P1—C31	−108.6 (3)	O2—Ag1—Ag2—O1	−38.01 (13)
C22—C21—P1—C31	69.7 (4)	P1—Ag1—Ag2—O1	121.43 (10)
C26—C21—P1—C11	139.8 (3)	O3—Ag1—Ag2—O1	−132.59 (14)
C22—C21—P1—C11	−41.9 (4)

Hydrogen-bond geometry (Å, º)

D—H···A	D—H	H···A	D···A	D—H···A
C22—H22···O4^i	0.93	2.44	3.291 (6)	153
C32—H32···O3	0.93	2.49	3.388 (6)	163

Symmetry code: (i) x, y+1, z.