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Acta Cryst. (2006). E62, m2732-m2734  [ doi:10.1107/S1600536806038803 ]

[7,16-Bis(benzyloxycarbonyl)-6,18,15,17-tetramethyldibenzo[b,i][1,4,8,11]tetraazacyclotetradecinato-[kappa]4N]nickel(II)

P. D. W. Boyd, J. B. Challis and C. E. F. Rickard

Abstract: The title compound, [Ni(C38H34N4O4)], is a four-coordinate nickel(II) complex of the 5,15-dihydro-7,16-bis(benzyloxycarbonyl)-6,18,15,17-tetramethyldibenzo[b,i][1,4,8,11]tetraazacyclotetradecine ligand, which forms a saddle-shaped molecule with divergent concave surfaces. The molecules assemble in the crystal structure via C-H...O interactions with the ester carbonyl O atoms and C-H...[pi] interactions with the propanediiminate portion of the complex.

Online 30 September 2006


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