Acta Cryst. (2006). E62, m2549-m2551  [ doi:10.1107/S1600536806036397 ]

Poly[(₃-5-bromosalicylato)silver(I)]

K. Cheng and H.-L. Liu

Abstract: The title complex, [Ag(C₇H₄BrO₃)]_n, is a polymer based on a carboxylate double-bridged centrosymmetric binuclear Ag^I fragment, the AgAg distance being 2.8666 (8) Å. The Ag atom is coordinated also by the hydroxy O atom of 5-bromosalicylate, showing a deformed trigonal coordination geometry. In the crystal structure, two-dimensional sheets are formed parallel to (01).

Online 13 September 2006

Copyright © International Union of Crystallography
IUCr Webmaster