Tetra­kis{trans-4-[(N,N-diethyl­amino)styr­yl]-1-methyl­pyridinium} dodeca­tungstosilicate tetra­deca­hydrate

In the title compound, (C₁₈H₂₃N₂)₄[SiW₁₂O₄₀]·14H₂O, the asymmetric unit contains two trans-4-[(N,N-diethyl­amino)­styr­yl]-N-methyl­pyridinium (DEASP) cations, one half dodeca­tungstosilicate (SiW₁₂O₄₀) anion and seven water mol­ecules. The two DEASP cations form a periodically layered arrangement perpendicular to their mol­ecular planes and the SiW₁₂O₄₀ anions have a disordered `pseudo-Keggin' structure around an inversion centre. They are linked into an infinite three-dimensional assembly via electrostatic forces and C—H...O hydrogen bonds.

Key indicators

• Single-crystal X-ray study
• T = 298 K
• Mean [sigma](C-C) = 0.037 Å
• H-atom completeness 77%
• Disorder in main residue
• R factor = 0.061
• wR factor = 0.160
• Data-to-parameter ratio = 17.4

checkCIF/PLATON results

No syntax errors found



Alert level B
PLAT342_ALERT_3_B Low Bond Precision on C-C bonds (x 1000) Ang ...         37
PLAT430_ALERT_2_B Short Inter D...A Contact  OW6    ..  OW12    ..       2.76 Ang.

Alert level C
PLAT026_ALERT_3_C Ratio Observed / Unique Reflections too Low ....         49 Perc.
PLAT041_ALERT_1_C Calc. and Rep. SumFormula Strings    Differ ....          ?
PLAT042_ALERT_1_C Calc. and Rep. MoietyFormula Strings Differ ....          ?
PLAT242_ALERT_2_C Check Low       Ueq as Compared to Neighbors for        Si1
PLAT243_ALERT_4_C High  'Solvent' Ueq as Compared to Neighbors for        OW8
PLAT244_ALERT_4_C Low   'Solvent' Ueq as Compared to Neighbors for        OW2
PLAT244_ALERT_4_C Low   'Solvent' Ueq as Compared to Neighbors for        OW6
PLAT301_ALERT_3_C Main Residue  Disorder .........................       7.00 Perc.
PLAT302_ALERT_4_C Anion/Solvent Disorder .........................      50.00 Perc.
PLAT313_ALERT_2_C Oxygen with three covalent bonds (rare) ........        OW5
PLAT313_ALERT_2_C Oxygen with three covalent bonds (rare) ........        OW9
PLAT366_ALERT_2_C Short? C(sp?)-C(sp?) Bond  C21    -   C22    ...       1.37 Ang.
PLAT366_ALERT_2_C Short? C(sp?)-C(sp?) Bond  C24    -   C25    ...       1.35 Ang.
PLAT366_ALERT_2_C Short? C(sp?)-C(sp?) Bond  C28    -   C33    ...       1.38 Ang.
PLAT720_ALERT_4_C Number of Unusual/Non-Standard Label(s) ........         14
PLAT790_ALERT_4_C Centre of Gravity not Within Unit Cell: Resd.  #          7
              O

Alert level G
FORMU01_ALERT_2_G  There is a discrepancy between the atom counts in the
            _chemical_formula_sum and the formula from the _atom_site* data.
            Atom count from _chemical_formula_sum:C72 H120 N8 O54 Si1 W12
            Atom count from the _atom_site data:  C72 H92 N8 O54 Si1 W12
CELLZ01_ALERT_1_G Difference between formula and atom_site contents detected.
CELLZ01_ALERT_1_G WARNING: H atoms missing from atom site list. Is this intentional?
           From the CIF: _cell_formula_units_Z    1
           From the CIF: _chemical_formula_sum  C72 H120 N8 O54 Si W12
           TEST: Compare cell contents of formula and atom_site data

           atom    Z*formula  cif sites diff
           C         72.00     72.00    0.00
           H        120.00     92.00   28.00
           N          8.00      8.00    0.00
           O         54.00     54.00    0.00
           Si         1.00      1.00    0.00
           W         12.00     12.00    0.00

   0 ALERT level A = In general: serious problem
   2 ALERT level B = Potentially serious problem
  16 ALERT level C = Check and explain
   3 ALERT level G = General alerts; check

   4 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
   8 ALERT type 2 Indicator that the structure model may be wrong or deficient
   3 ALERT type 3 Indicator that the structure quality may be low
   6 ALERT type 4 Improvement, methodology, query or suggestion
   0 ALERT type 5 Informative message, check

---

Computing details

Data collection: SMART (Bruker, 2000); cell refinement: SAINT (Bruker, 2000); data reduction: SAINT; program(s) used to solve structure: SHELXTL (Bruker, 2000); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: SHELXTL; software used to prepare material for publication: SHELXL97.

Tetrakis{trans-4-[(N,N-diethylamino)styryl]-1-methylpyridinium} dodecatungstosilicate tetradecahydrate

Crystal data

(C18H23N2)4[W12O40SiW12]·14H2O	Z = 1
Mr = 4195.91	F(000) = 1914.0
Triclinic, P1	Dx = 2.318 Mg m^−3
Hall symbol: -P 1	Mo Kα radiation, λ = 0.71073 Å
a = 15.019 (4) Å	Cell parameters from 250 reflections
b = 15.056 (4) Å	θ = 1.7–25.5°
c = 16.080 (4) Å	µ = 11.60 mm^−1
α = 64.393 (3)°	T = 298 K
β = 79.436 (4)°	Block, red
γ = 65.578 (3)°	0.45 × 0.21 × 0.10 mm
V = 2985.5 (14) Å^3

Data collection

Bruker SMART CCD diffractometer	10904 independent reflections
Radiation source: fine-focus sealed tube	5387 reflections with I > 2σ(I)
Graphite monochromator	Rint = 0.049
φ and ω scans	θmax = 25.5°, θmin = 1.7°
Absorption correction: part of the refinement model (ΔF) (Parkin et al., 1995)	h = −10→18
Tmin = 0.065, Tmax = 0.311	k = −15→18
16302 measured reflections	l = −18→19

Refinement

Refinement on F^2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F^2 > 2σ(F^2)] = 0.061	Hydrogen site location: inferred from neighbouring sites
wR(F^2) = 0.160	H-atom parameters constrained
S = 0.89	w = 1/[σ^2(Fo^2) + (0.0704P)^2] where P = (Fo^2 + 2Fc^2)/3
10904 reflections	(Δ/σ)max < 0.001
627 parameters	Δρmax = 2.18 e Å^−3
118 restraints	Δρmin = −1.51 e Å^−3

Special details

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. The disorder of C atoms in DEASP cations contribute to the low bond precision on C—C bonds and also to the high U_eq(max)/U_eq(min) values of some of the carbons. So eighteen SHELXL97 (Sheldrick, 1997) ISOR restraints were used in the refinement to lower these values, and other geometric restraints (DFIX, DANG and SADI) were also used to make geometric structure reasonable. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq	Occ. (<1)
N1	−0.0254 (13)	1.0805 (14)	0.5913 (11)	0.081 (3)
N2	0.4099 (17)	0.2409 (17)	0.8961 (15)	0.143 (5)
C1	0.0629 (13)	1.0391 (16)	0.6241 (12)	0.084 (6)
H1A	0.0902	1.0844	0.6240	0.101*
C2	0.1149 (13)	0.9359 (18)	0.6572 (14)	0.083 (6)
H2A	0.1803	0.9125	0.6712	0.099*
C3	0.0779 (15)	0.8635 (15)	0.6715 (12)	0.082 (6)
C4	−0.0204 (14)	0.9090 (14)	0.6439 (13)	0.087 (4)
H4A	−0.0548	0.8659	0.6547	0.105*
C5	−0.0618 (14)	1.0101 (12)	0.6037 (12)	0.091 (6)
H5A	−0.1243	1.0364	0.5809	0.110*
C6	0.1199 (15)	0.7468 (15)	0.7105 (13)	0.108 (5)
H6A	0.0789	0.7152	0.7090	0.130*
C7	0.2046 (15)	0.6810 (18)	0.7466 (14)	0.115 (4)
H7A	0.2453	0.7139	0.7464	0.138*
C8	0.2463 (17)	0.5715 (19)	0.7853 (15)	0.110 (4)
C9	0.3408 (16)	0.5265 (19)	0.8142 (14)	0.107 (4)
H9A	0.3697	0.5730	0.8084	0.128*
C10	0.3952 (18)	0.4246 (19)	0.8494 (14)	0.111 (7)
H10A	0.4584	0.4004	0.8698	0.133*
C11	0.3534 (19)	0.352 (2)	0.8551 (16)	0.120 (8)
C12	0.2587 (16)	0.3909 (18)	0.8226 (14)	0.106 (4)
H12A	0.2305	0.3464	0.8223	0.127*
C13	0.2075 (17)	0.5053 (19)	0.7893 (15)	0.116 (4)
H13A	0.1434	0.5338	0.7696	0.140*
C14	−0.0790 (14)	1.1939 (15)	0.5467 (13)	0.100 (7)
H14A	−0.1422	1.2068	0.5288	0.151*
H14B	−0.0437	1.2236	0.4929	0.151*
H14C	−0.0866	1.2265	0.5886	0.151*
C15	0.524 (2)	0.194 (2)	0.9196 (16)	0.149 (4)
H15A	0.5579	0.1243	0.9175	0.179*
H15B	0.5558	0.2415	0.8791	0.179*
C16	0.5141 (19)	0.188 (2)	1.0169 (16)	0.162 (4)
H16A	0.5780	0.1598	1.0420	0.243*
H16B	0.4797	0.1423	1.0543	0.243*
H16C	0.4785	0.2578	1.0163	0.243*
C17	0.3860 (18)	0.160 (2)	0.8826 (16)	0.149 (4)
H17A	0.4440	0.0976	0.8869	0.179*
H17B	0.3545	0.1902	0.8238	0.179*
C18	0.3161 (19)	0.135 (2)	0.9630 (17)	0.163 (4)
H18A	0.2965	0.0822	0.9632	0.245*
H18B	0.2594	0.1989	0.9566	0.245*
H18C	0.3483	0.1095	1.0199	0.245*
C21	0.4443 (14)	0.5122 (15)	0.6031 (13)	0.089 (6)
H21A	0.4305	0.5844	0.5835	0.107*
C22	0.5332 (14)	0.4395 (16)	0.6421 (14)	0.086 (4)
H22A	0.5688	0.4729	0.6492	0.081*
C24	0.4889 (14)	0.3074 (14)	0.6611 (13)	0.089 (6)
H24A	0.5023	0.2351	0.6825	0.106*
C25	0.3998 (14)	0.3756 (13)	0.6244 (12)	0.092 (6)
H25A	0.3543	0.3501	0.6210	0.111*
C23A	0.5570 (15)	0.3345 (16)	0.6689 (13)	0.085 (4)	0.57 (3)
C26A	0.657 (2)	0.284 (3)	0.710 (2)	0.098 (11)	0.57 (3)
H26A	0.6873	0.3258	0.7114	0.118*	0.57 (3)
C27A	0.7014 (19)	0.180 (3)	0.743 (2)	0.101 (7)	0.57 (3)
H27A	0.6684	0.1394	0.7426	0.122*	0.57 (3)
C23B	0.5570 (15)	0.3345 (16)	0.6689 (13)	0.085 (4)	0.43 (3)
C26B	0.641 (2)	0.232 (3)	0.712 (3)	0.071 (4)	0.43 (3)
H26B	0.6565	0.1592	0.7435	0.081*	0.43 (3)
C27B	0.724 (2)	0.229 (2)	0.734 (3)	0.0740 (9)	0.43 (3)
H27B	0.7126	0.3021	0.7182	0.081*	0.43 (3)
C28	0.8012 (15)	0.1235 (17)	0.7811 (15)	0.104 (7)
C29	0.8788 (18)	0.1544 (17)	0.7843 (15)	0.119 (8)
H29A	0.8688	0.2261	0.7614	0.143*
C30	0.9670 (17)	0.079 (2)	0.8208 (17)	0.126 (9)
H30A	1.0172	0.0991	0.8219	0.151*
C31	0.983 (2)	−0.029 (3)	0.8566 (18)	0.122 (9)
C32	0.9045 (18)	−0.057 (2)	0.8569 (16)	0.125 (7)
H32A	0.9115	−0.1280	0.8865	0.150*
C33	0.8201 (17)	0.0160 (19)	0.8158 (16)	0.123 (7)
H33A	0.7727	−0.0060	0.8103	0.148*
C34	0.2837 (15)	0.5549 (16)	0.5553 (15)	0.116 (8)
H34A	0.2800	0.6261	0.5371	0.173*
H34B	0.2344	0.5421	0.6010	0.173*
H34C	0.2734	0.5463	0.5026	0.173*
C35	1.165 (2)	−0.075 (2)	0.8747 (16)	0.150 (4)
H35A	1.2231	−0.1328	0.8682	0.180*
H35B	1.1574	−0.0105	0.8200	0.180*
C36	1.1681 (19)	−0.061 (2)	0.9604 (17)	0.161 (4)
H36A	1.2222	−0.0411	0.9568	0.241*
H36B	1.1759	−0.1265	1.0130	0.241*
H36C	1.1082	−0.0062	0.9664	0.241*
C37	1.094 (2)	−0.222 (2)	0.9371 (17)	0.150 (4)
H37A	1.0668	−0.2425	0.9006	0.179*
H37B	1.1639	−0.2610	0.9414	0.179*
C38	1.0483 (19)	−0.245 (2)	1.0305 (16)	0.157 (4)
H38A	1.0583	−0.3192	1.0601	0.235*
H38B	0.9795	−0.2031	1.0251	0.235*
H38C	1.0779	−0.2279	1.0666	0.235*
N3	0.3776 (13)	0.4814 (14)	0.5928 (10)	0.086 (4)
N4	1.069 (2)	−0.104 (2)	0.8947 (16)	0.146 (7)
O1	0.4716 (13)	0.9822 (13)	0.6066 (12)	0.043 (4)	0.50
O2	0.4834 (14)	0.8928 (15)	0.5508 (13)	0.053 (5)	0.50
O3	0.3969 (13)	1.0999 (14)	0.5082 (12)	0.043 (5)	0.50
O4	0.5865 (13)	0.9951 (14)	0.5507 (12)	0.047 (5)	0.50
O5	0.4549 (8)	1.0636 (8)	0.7027 (8)	0.076 (3)
O6	0.5316 (8)	0.8573 (8)	0.7502 (7)	0.0696 (9)
O7	0.3464 (8)	0.9535 (8)	0.7044 (7)	0.0682 (9)
O8	0.2442 (10)	1.1216 (10)	0.5632 (9)	0.099 (4)
O9	0.3571 (8)	0.8311 (8)	0.6308 (7)	0.0688 (9)
O10	0.5476 (8)	0.7270 (9)	0.6729 (7)	0.0722 (9)
O11	0.4873 (8)	0.7532 (8)	0.5183 (7)	0.0670 (9)
O12	0.2578 (8)	0.9966 (9)	0.4845 (7)	0.0735 (9)
O13	0.6105 (8)	1.0825 (9)	0.6242 (8)	0.0796 (9)
O14	0.3520 (10)	1.2256 (11)	0.5609 (9)	0.105 (4)
O15	0.7100 (8)	0.7485 (9)	0.5951 (7)	0.0727 (9)
O16	0.6920 (8)	0.8754 (8)	0.6694 (7)	0.0675 (9)
O20	0.6134 (8)	0.9573 (8)	0.8057 (7)	0.0715 (9)
O21	0.2506 (8)	1.1494 (9)	0.7208 (7)	0.0748 (9)
O22	0.4078 (8)	0.7454 (8)	0.8101 (7)	0.0712 (9)
O23	0.2930 (8)	0.7963 (9)	0.5039 (7)	0.0745 (9)
O24	0.6613 (9)	0.5924 (10)	0.5896 (9)	0.094 (4)
O25	0.8652 (9)	0.7977 (10)	0.5867 (8)	0.091 (4)
OW1	0.684 (6)	0.388 (5)	0.857 (5)	0.32 (9)*	0.50
OW2	0.927 (4)	0.602 (4)	0.850 (4)	0.22 (9)*	0.50
OW3	0.893 (2)	0.400 (6)	0.595 (8)	0.26 (6)*	0.50
OW4	1.044 (7)	0.558 (6)	0.581 (2)	0.22 (6)*	0.50
OW5	0.980 (5)	0.432 (5)	0.668 (4)	0.26 (3)*	0.50
OW6	0.824 (4)	0.648 (4)	0.883 (4)	0.22 (3)*	0.50
OW7	0.651 (6)	0.480 (7)	0.865 (6)	0.35 (4)*	0.50
OW8	0.886 (4)	0.694 (5)	0.884 (4)	0.26 (9)*	0.50
OW9	0.950 (3)	0.440 (8)	0.575 (2)	0.25 (6)*	0.50
OW10	0.982 (5)	0.489 (5)	0.615 (5)	0.25 (3)*	0.50
OW11	1.072 (4)	0.365 (5)	0.645 (4)	0.27 (3)*	0.50
OW12	0.703 (4)	0.556 (4)	0.874 (4)	0.29 (4)*	0.50
OW13	1.113 (4)	0.428 (5)	1.035 (4)	0.25 (6)*	0.50
OW14	0.599 (6)	0.450 (7)	0.959 (6)	0.40 (4)*	0.50
Si1	0.5000	1.0000	0.5000	0.0281 (12)
W1	0.57850 (6)	0.96635 (6)	0.70863 (5)	0.0649 (2)
W2	0.32897 (5)	1.10249 (6)	0.64999 (5)	0.0650 (2)
W3	0.43981 (5)	0.82541 (6)	0.71236 (5)	0.0626 (2)
W4	0.35987 (5)	0.86064 (5)	0.50360 (5)	0.0602 (2)
W5	0.60966 (5)	0.72291 (5)	0.56158 (5)	0.0653 (2)
W6	0.74938 (5)	0.86112 (6)	0.55987 (5)	0.0674 (2)

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
N1	0.096	0.080 (6)	0.077 (6)	−0.037 (4)	−0.002 (4)	−0.034 (4)
N2	0.166	0.098 (16)	0.167	−0.043 (14)	−0.057 (15)	−0.040 (13)
C1	0.088 (16)	0.102 (17)	0.069 (13)	−0.047 (14)	0.013 (11)	−0.036 (13)
C2	0.038 (11)	0.098 (16)	0.115 (17)	−0.023 (11)	0.018 (10)	−0.054 (14)
C3	0.092 (10)	0.084 (9)	0.074 (9)	−0.028 (8)	0.002 (7)	−0.041 (7)
C4	0.081	0.090 (6)	0.089 (6)	−0.030 (4)	−0.003 (5)	−0.035 (4)
C5	0.085 (15)	0.071 (14)	0.084 (14)	−0.004 (11)	−0.049 (11)	−0.006 (11)
C6	0.115 (10)	0.095	0.101 (10)	−0.022 (7)	0.003 (8)	−0.045 (7)
C7	0.107	0.114	0.111 (10)	−0.030 (7)	0.007 (8)	−0.049 (7)
C8	0.122	0.103 (6)	0.107 (6)	−0.042 (4)	0.001 (5)	−0.045 (4)
C9	0.107	0.105 (6)	0.109 (6)	−0.042 (4)	0.002 (5)	−0.043 (4)
C10	0.116 (11)	0.106 (11)	0.112 (11)	−0.039 (8)	−0.008 (8)	−0.045 (8)
C11	0.118 (11)	0.118 (11)	0.119 (11)	−0.041 (9)	−0.006 (8)	−0.043 (8)
C12	0.092	0.110 (6)	0.111 (6)	−0.039 (4)	−0.002 (5)	−0.037 (4)
C13	0.109	0.118 (6)	0.115 (6)	−0.040 (4)	0.000 (5)	−0.043 (4)
C14	0.111 (18)	0.077 (15)	0.094 (16)	−0.020 (13)	−0.003 (12)	−0.029 (12)
C15	0.150	0.150 (7)	0.148 (7)	−0.056 (4)	0.002 (5)	−0.060 (4)
C16	0.157	0.163 (7)	0.160 (7)	−0.058 (5)	−0.002 (5)	−0.061 (5)
C17	0.143	0.151 (7)	0.151 (7)	−0.053 (5)	−0.003 (5)	−0.060 (5)
C18	0.153	0.165 (7)	0.165 (7)	−0.062 (5)	0.000 (5)	−0.059 (5)
C21	0.120 (19)	0.062 (13)	0.091 (15)	−0.040 (13)	−0.012 (13)	−0.025 (11)
C22	0.077	0.089 (6)	0.089 (6)	−0.031 (4)	0.002 (5)	−0.033 (4)
C24	0.092 (10)	0.077 (9)	0.092 (10)	−0.026 (8)	0.000 (8)	−0.036 (7)
C25	0.107 (10)	0.085 (9)	0.093 (10)	−0.044 (8)	0.014 (8)	−0.042 (8)
C23A	0.080	0.084 (6)	0.082 (6)	−0.027 (4)	0.004 (5)	−0.032 (4)
C26A	0.094	0.109	0.09 (3)	−0.056 (17)	0.03 (2)	−0.04 (2)
C27A	0.099 (13)	0.111	0.101 (12)	−0.050 (8)	0.004 (9)	−0.040 (8)
C23B	0.080	0.084 (6)	0.082 (6)	−0.027 (4)	0.004 (5)	−0.032 (4)
C26B	0.074	0.068 (7)	0.070 (7)	−0.026 (5)	0.002 (5)	−0.029 (5)
C27B	0.0741 (14)	0.074	0.0740 (14)	−0.0279 (9)	−0.0004 (10)	−0.0295 (9)
C28	0.087 (17)	0.109	0.079 (16)	0.008 (15)	−0.030 (13)	−0.036 (13)
C29	0.11 (2)	0.100	0.104 (19)	−0.005 (16)	−0.007 (16)	−0.035 (13)
C30	0.09 (2)	0.15 (3)	0.12 (2)	−0.02 (2)	−0.011 (16)	−0.07 (2)
C31	0.09 (2)	0.15 (3)	0.11 (2)	−0.02 (2)	−0.016 (16)	−0.06 (2)
C32	0.10 (2)	0.185	0.13 (2)	−0.072 (18)	0.004 (16)	−0.084 (17)
C33	0.078 (18)	0.180	0.12 (2)	−0.048 (17)	−0.003 (15)	−0.065 (19)
C34	0.087 (17)	0.121 (19)	0.119 (19)	0.004 (15)	−0.033 (14)	−0.058 (16)
C35	0.146	0.150 (7)	0.146 (7)	−0.052 (5)	0.002 (5)	−0.057 (4)
C36	0.155	0.164 (7)	0.162 (7)	−0.056 (5)	−0.006 (5)	−0.066 (5)
C37	0.147	0.151 (7)	0.150 (7)	−0.057 (5)	0.000 (5)	−0.059 (5)
C38	0.151	0.158 (7)	0.157 (7)	−0.055 (4)	−0.003 (5)	−0.061 (5)
N3	0.100 (15)	0.103	0.073 (11)	−0.048 (11)	0.007 (9)	−0.045 (9)
N4	0.14 (2)	0.15 (2)	0.150	−0.063 (18)	0.003 (16)	−0.053 (15)
O1	0.045	0.042 (8)	0.054 (9)	−0.031 (6)	0.001 (6)	−0.016 (6)
O2	0.062 (14)	0.058 (13)	0.066 (14)	−0.045 (12)	0.014 (11)	−0.034 (11)
O3	0.042 (8)	0.046 (8)	0.050 (8)	−0.028 (7)	−0.002 (6)	−0.016 (6)
O4	0.044 (6)	0.047 (6)	0.052 (6)	−0.019 (5)	−0.003 (4)	−0.018 (4)
O5	0.086	0.058 (6)	0.102 (7)	−0.036 (5)	−0.017 (5)	−0.033 (5)
O6	0.068	0.0700 (14)	0.0709 (14)	−0.0263 (9)	−0.0010 (10)	−0.0271 (9)
O7	0.067	0.0688 (14)	0.0693 (14)	−0.0264 (9)	−0.0013 (10)	−0.0266 (9)
O8	0.099 (4)	0.099 (4)	0.100 (4)	−0.0388 (18)	−0.0009 (10)	−0.0385 (19)
O9	0.066	0.0700 (14)	0.0695 (14)	−0.0248 (9)	−0.0009 (10)	−0.0278 (9)
O10	0.070	0.0735 (14)	0.0724 (14)	−0.0263 (9)	−0.0013 (10)	−0.0288 (9)
O11	0.065	0.0679 (14)	0.0674 (14)	−0.0241 (9)	−0.0009 (10)	−0.0273 (9)
O12	0.071	0.0736 (14)	0.0738 (14)	−0.0271 (9)	0.0014 (10)	−0.0285 (9)
O13	0.078	0.0794 (14)	0.0802 (14)	−0.0290 (9)	0.0007 (10)	−0.0314 (9)
O14	0.105 (4)	0.105 (4)	0.106 (4)	−0.0407 (19)	−0.0013 (10)	−0.041 (2)
O15	0.071	0.0740 (14)	0.0735 (14)	−0.0286 (9)	−0.0011 (10)	−0.0281 (9)
O16	0.065	0.0671 (14)	0.0681 (14)	−0.0247 (9)	0.0013 (10)	−0.0260 (9)
O20	0.070	0.0720 (14)	0.0725 (14)	−0.0269 (9)	−0.0014 (10)	−0.0284 (9)
O21	0.073	0.0752 (14)	0.0755 (14)	−0.0280 (9)	0.0001 (10)	−0.0299 (9)
O22	0.069	0.0718 (14)	0.0719 (14)	−0.0270 (9)	−0.0005 (10)	−0.0270 (9)
O23	0.073	0.0748 (14)	0.0756 (14)	−0.0284 (9)	−0.0003 (10)	−0.0296 (9)
O24	0.099 (6)	0.090 (6)	0.102 (6)	−0.038 (4)	−0.011 (4)	−0.039 (4)
O25	0.086 (7)	0.089 (7)	0.103 (7)	−0.048 (6)	−0.002 (6)	−0.027 (6)
Si1	0.030 (3)	0.028 (3)	0.034 (3)	−0.016 (2)	−0.003 (2)	−0.012 (2)
W1	0.0733 (6)	0.0643 (5)	0.0641 (5)	−0.0262 (4)	−0.0138 (4)	−0.0260 (4)
W2	0.0584 (5)	0.0737 (5)	0.0790 (5)	−0.0308 (4)	0.0105 (4)	−0.0432 (4)
W3	0.0619 (5)	0.0606 (5)	0.0648 (5)	−0.0339 (4)	−0.0006 (4)	−0.0142 (4)
W4	0.0500 (5)	0.0564 (5)	0.0943 (6)	−0.0321 (4)	0.0020 (4)	−0.0370 (4)
W5	0.0659 (5)	0.0423 (4)	0.0931 (6)	−0.0207 (4)	−0.0157 (4)	−0.0255 (4)
W6	0.0426 (5)	0.0628 (5)	0.0922 (6)	−0.0211 (4)	−0.0124 (4)	−0.0210 (4)

Geometric parameters (Å, º)

N1—C1	1.31 (2)	C36—H36C	0.9600
N1—C5	1.31 (2)	C37—C38	1.49 (4)
N1—C14	1.45 (2)	C37—N4	1.51 (3)
N2—C11	1.42 (3)	C37—H37A	0.9700
N2—C17	1.50 (3)	C37—H37B	0.9700
N2—C15	1.60 (3)	C38—H38A	0.9600
C1—C2	1.32 (2)	C38—H38B	0.9600
C1—H1A	0.9300	C38—H38C	0.9600
C2—C3	1.34 (2)	Si1—O1^i	1.619 (17)
C2—H2A	0.9300	Si1—O2	1.566 (17)
C3—C4	1.41 (2)	Si1—O3	1.687 (18)
C3—C6	1.468 (16)	Si1—O4	1.618 (18)
C4—C5	1.279 (15)	O1—Si1	1.619 (17)
C4—H4A	0.9300	O1—W1	2.375 (18)
C5—H5A	0.9300	O1—W2	2.386 (18)
C6—C7	1.29 (3)	O1—W3	2.419 (16)
C6—H6A	0.9300	O2—W4	2.414 (18)
C7—C8	1.38 (3)	O2—W3	2.420 (18)
C7—H7A	0.9300	O2—W5	2.428 (19)
C8—C13	1.32 (3)	O3—W2	2.330 (17)
C8—C9	1.37 (4)	O3—W5^i	2.371 (17)
C9—C10	1.31 (3)	O3—W6^i	2.374 (17)
C9—H9A	0.9300	O4—W1	2.374 (18)
C10—C11	1.43 (3)	O4—W4^i	2.382 (18)
C10—H10A	0.9300	O4—W6	2.423 (18)
C11—C12	1.40 (3)	O5—W1	1.815 (11)
C12—C13	1.45 (3)	O5—W2	1.971 (11)
C12—H12A	0.9300	O6—W1	1.863 (11)
C13—H13A	0.9300	O6—W3	1.901 (11)
C14—H14A	0.9600	O7—W3	1.823 (11)
C14—H14B	0.9600	O7—W2	1.941 (10)
C14—H14C	0.9600	O8—W6^i	1.871 (13)
C15—C16	1.511 (17)	O8—W2	1.910 (13)
C15—H15A	0.9700	O9—W4	1.892 (10)
C15—H15B	0.9700	O9—W3	1.919 (11)
C16—H16A	0.9600	O10—W5	1.874 (10)
C16—H16B	0.9600	O10—W3	1.916 (11)
C16—H16C	0.9600	O11—W5	1.890 (11)
C17—C18	1.52 (4)	O11—W4	1.900 (10)
C17—H17A	0.9700	O12—W6^i	1.903 (11)
C17—H17B	0.9700	O12—W4	1.916 (11)
C18—H18A	0.9600	O13—W1	1.880 (11)
C18—H18B	0.9600	O13—W4^i	1.900 (11)
C18—H18C	0.9600	O14—W5^i	1.856 (13)
C21—N3	1.33 (2)	O14—W2	1.913 (13)
C21—C22	1.37 (2)	O15—W6	1.850 (11)
C21—H21A	0.9300	O15—W5	1.915 (11)
C22—C23A	1.35 (2)	O16—W6	1.873 (10)
C22—H22A	0.9200	O16—W1	1.898 (10)
C24—C23A	1.29 (2)	O20—W1	1.669 (11)
C24—C25	1.350 (16)	O21—W2	1.642 (11)
C24—H24A	0.9300	O22—W3	1.649 (10)
C25—N3	1.35 (2)	O23—W4	1.656 (11)
C25—H25A	0.9300	O24—W5	1.663 (12)
C23A—C26A	1.50 (2)	O25—W6	1.634 (12)
C26A—C27A	1.32 (3)	OW1—OW7	1.32 (8)
C26A—H26A	0.9300	OW2—OW6	1.50 (6)
C26A—H27B	1.03 (3)	OW2—OW8	1.55 (7)
C27A—C28	1.476 (19)	OW2—OW13^ii	1.74 (6)
C27A—H27A	0.9300	OW3—OW9	1.1668 (2)
C27A—H26B	0.85 (3)	OW4—OW10	1.55 (7)
C26B—C27B	1.34 (3)	OW5—OW10	0.92 (8)
C26B—H26B	0.93 (3)	OW5—OW11	1.44 (7)
C27B—C28	1.483 (19)	OW5—OW9	1.57 (6)
C27B—H27B	0.96 (3)	OW6—OW8	1.38 (7)
C28—C33	1.38 (4)	OW6—OW13^ii	1.48 (6)
C28—C29	1.44 (4)	OW7—OW14	1.55 (9)
C29—C30	1.36 (4)	OW7—OW12	1.69 (8)
C29—H29A	0.9300	OW8—OW13^ii	1.73 (7)
C30—C31	1.40 (5)	OW9—OW10	1.41 (7)
C30—H30A	0.9300	OW10—OW11	1.72 (8)
C31—N4	1.35 (3)	OW13—OW6^ii	1.48 (6)
C31—C32	1.41 (5)	OW13—OW8^ii	1.73 (7)
C32—C33	1.33 (4)	OW13—OW2^ii	1.74 (6)
C32—H32A	0.9300	Si1—O2^i	1.566 (17)
C33—H33A	0.9300	Si1—O4^i	1.618 (18)
C34—N3	1.42 (2)	Si1—O1^i	1.619 (17)
C34—H34A	0.9600	Si1—O3^i	1.687 (18)
C34—H34B	0.9600	W4—O13^i	1.900 (11)
C34—H34C	0.9600	W4—O4^i	2.382 (18)
C35—C36	1.49 (4)	W5—O14^i	1.856 (13)
C35—N4	1.61 (3)	W5—O3^i	2.371 (17)
C35—H35A	0.9700	W6—O8^i	1.871 (13)
C35—H35B	0.9700	W6—O12^i	1.903 (11)
C36—H36A	0.9600	W6—O3^i	2.374 (17)
C36—H36B	0.9600
C1—N1—C5	114.0 (19)	W5—O11—W4	136.9 (6)
C1—N1—C14	123.2 (15)	W6^i—O12—W4	135.8 (6)
C5—N1—C14	122.7 (15)	W1—O13—W4^i	137.8 (7)
C11—N2—C17	122 (2)	W5^i—O14—W2	138.9 (8)
C11—N2—C15	123 (2)	W6—O15—W5	137.0 (6)
C17—N2—C15	110 (2)	W6—O16—W1	139.1 (6)
N1—C1—C2	123 (2)	OW6—OW2—OW8	54 (3)
N1—C1—H1A	118.5	OW6—OW2—OW13^ii	54 (3)
C2—C1—H1A	118.5	OW8—OW2—OW13^ii	63 (3)
C1—C2—C3	123 (2)	OW10—OW5—OW11	91 (7)
C1—C2—H2A	118.5	OW10—OW5—OW9	63 (7)
C3—C2—H2A	118.5	OW11—OW5—OW9	81 (4)
C2—C3—C4	113.2 (18)	OW8—OW6—OW13^ii	75 (4)
C2—C3—C6	132 (2)	OW8—OW6—OW2	65 (4)
C4—C3—C6	114.5 (19)	OW13^ii—OW6—OW2	72 (4)
C5—C4—C3	119 (2)	OW1—OW7—OW14	99 (8)
C5—C4—H4A	120.3	OW1—OW7—OW12	136 (7)
C3—C4—H4A	120.3	OW14—OW7—OW12	101 (7)
C4—C5—N1	127 (2)	OW6—OW8—OW2	61 (4)
C4—C5—H5A	116.6	OW6—OW8—OW13^ii	55 (3)
N1—C5—H5A	116.6	OW2—OW8—OW13^ii	64 (3)
C7—C6—C3	130 (2)	OW3—OW9—OW10	134 (3)
C7—C6—H6A	114.8	OW3—OW9—OW5	105 (2)
C3—C6—H6A	114.8	OW5—OW10—OW9	82 (7)
C6—C7—C8	132 (2)	OW5—OW10—OW4	135 (9)
C6—C7—H7A	113.8	OW9—OW10—OW4	135 (5)
C8—C7—H7A	113.8	OW5—OW10—OW11	57 (6)
C13—C8—C9	116 (2)	OW9—OW10—OW11	77 (4)
C13—C8—C7	127 (2)	OW4—OW10—OW11	101 (4)
C9—C8—C7	117 (2)	OW6^ii—OW13—OW8^ii	50 (3)
C10—C9—C8	127 (3)	OW6^ii—OW13—OW2^ii	55 (3)
C10—C9—H9A	116.6	OW8^ii—OW13—OW2^ii	53 (3)
C8—C9—H9A	116.6	O2—Si1—O1^i	108.9 (9)
C9—C10—C11	117 (2)	O3—Si1—O1^i	111.3 (9)
C9—C10—H10A	121.3	O4—Si1—O1^i	110.7 (9)
C11—C10—H10A	121.3	O2—Si1—O3	108.9 (9)
C12—C11—N2	122 (3)	O2—Si1—O4	109.3 (10)
C12—C11—C10	120 (3)	O3—Si1—O4	107.8 (9)
N2—C11—C10	118 (2)	O2—Si1—O2^i	180.0 (8)
C11—C12—C13	115 (2)	O2—Si1—O4^i	70.7 (10)
C11—C12—H12A	122.3	O2^i—Si1—O4^i	109.3 (10)
C13—C12—H12A	122.3	O2^i—Si1—O4	70.7 (10)
C8—C13—C12	124 (2)	O4^i—Si1—O4	180.000 (4)
C8—C13—H13A	117.9	O2^i—Si1—O1^i	71.1 (9)
C12—C13—H13A	117.9	O4^i—Si1—O1^i	69.3 (9)
N1—C14—H14A	109.5	O2—Si1—O1	71.1 (9)
N1—C14—H14B	109.5	O2^i—Si1—O1	108.9 (9)
H14A—C14—H14B	109.5	O4^i—Si1—O1	110.7 (9)
N1—C14—H14C	109.5	O4—Si1—O1	69.3 (9)
H14A—C14—H14C	109.5	O1^i—Si1—O1	180.000 (3)
H14B—C14—H14C	109.5	O2^i—Si1—O3	71.1 (9)
C16—C15—N2	99 (2)	O4^i—Si1—O3	72.2 (9)
C16—C15—H15A	112.0	O3—Si1—O1	68.7 (9)
N2—C15—H15A	112.0	O2—Si1—O3^i	71.1 (9)
C16—C15—H15B	112.0	O2^i—Si1—O3^i	108.9 (9)
N2—C15—H15B	112.0	O4^i—Si1—O3^i	107.8 (9)
H15A—C15—H15B	109.7	O4—Si1—O3^i	72.2 (9)
C15—C16—H16A	109.5	O1^i—Si1—O3^i	68.7 (9)
C15—C16—H16B	109.5	O1—Si1—O3^i	111.3 (9)
H16A—C16—H16B	109.5	O3—Si1—O3^i	180.000 (3)
C15—C16—H16C	109.5	O20—W1—O5	98.5 (5)
H16A—C16—H16C	109.5	O20—W1—O6	103.0 (5)
H16B—C16—H16C	109.5	O5—W1—O6	90.9 (5)
N2—C17—C18	101 (2)	O20—W1—O13	99.0 (5)
N2—C17—H17A	111.5	O5—W1—O13	85.4 (5)
C18—C17—H17A	111.5	O6—W1—O13	158.0 (5)
N2—C17—H17B	111.5	O20—W1—O16	103.8 (5)
C18—C17—H17B	111.5	O5—W1—O16	157.6 (5)
H17A—C17—H17B	109.3	O6—W1—O16	86.6 (4)
C17—C18—H18A	109.5	O13—W1—O16	88.6 (5)
C17—C18—H18B	109.5	O20—W1—O4	156.8 (6)
H18A—C18—H18B	109.5	O5—W1—O4	94.9 (6)
C17—C18—H18C	109.5	O6—W1—O4	95.6 (5)
H18A—C18—H18C	109.5	O13—W1—O4	63.2 (6)
H18B—C18—H18C	109.5	O16—W1—O4	63.2 (5)
N3—C21—C22	121.1 (18)	O20—W1—O1	157.2 (6)
N3—C21—H21A	119.4	O5—W1—O1	64.3 (5)
C22—C21—H21A	119.4	O6—W1—O1	64.4 (5)
C23A—C22—C21	121.3 (17)	O13—W1—O1	94.7 (5)
C23A—C22—H22A	128 (2)	O16—W1—O1	94.7 (5)
C21—C22—H22A	111.00	O4—W1—O1	45.6 (6)
C23A—C24—C25	125.2 (18)	O21—W2—O8	101.9 (6)
C23A—C24—H24A	117.4	O21—W2—O14	102.4 (5)
C25—C24—H24A	117.4	O8—W2—O14	88.3 (6)
C24—C25—N3	119 (2)	O21—W2—O7	102.6 (5)
C24—C25—H25A	120.4	O8—W2—O7	86.9 (5)
N3—C25—H25A	120.4	O14—W2—O7	155.0 (5)
C24—C23A—C22	115.7 (18)	O21—W2—O5	101.7 (5)
C24—C23A—C26A	139 (2)	O8—W2—O5	156.3 (5)
C22—C23A—C26A	104 (2)	O14—W2—O5	85.1 (5)
C27A—C26A—C23A	120 (3)	O7—W2—O5	89.5 (4)
C27A—C26A—H26A	120.2	O21—W2—O3	156.8 (6)
C23A—C26A—H26A	120.2	O8—W2—O3	63.0 (6)
C26A—C27A—C28	123 (3)	O14—W2—O3	61.8 (6)
C26A—C27A—H27A	118.5	O7—W2—O3	94.3 (5)
C28—C27A—H27A	118.5	O5—W2—O3	94.1 (6)
C27B—C26B—H26B	94 (3)	O21—W2—O1	156.6 (6)
C26B—C27B—C28	118 (3)	O8—W2—O1	95.6 (6)
C26B—C27B—H27B	104 (3)	O14—W2—O1	93.5 (6)
C28—C27B—H27B	137 (3)	O7—W2—O1	62.6 (5)
C33—C28—C29	117.7 (15)	O5—W2—O1	62.3 (5)
C33—C28—C27A	107 (2)	O3—W2—O1	46.6 (6)
C29—C28—C27A	136 (2)	O22—W3—O7	100.6 (5)
C33—C28—C27B	142 (2)	O22—W3—O6	103.2 (5)
C29—C28—C27B	101 (2)	O7—W3—O6	89.6 (5)
C30—C29—C28	119.9 (19)	O22—W3—O10	102.0 (5)
C30—C29—H29A	120.0	O7—W3—O10	157.3 (5)
C28—C29—H29A	120.0	O6—W3—O10	88.2 (5)
C29—C30—C31	121 (3)	O22—W3—O9	98.5 (5)
C29—C30—H30A	119.5	O7—W3—O9	85.0 (5)
C31—C30—H30A	119.5	O6—W3—O9	158.3 (4)
N4—C31—C30	121 (2)	O10—W3—O9	88.7 (5)
N4—C31—C32	121 (3)	O22—W3—O1	157.2 (6)
C30—C31—C32	118 (3)	O7—W3—O1	63.2 (5)
C33—C32—C31	121 (3)	O6—W3—O1	63.0 (5)
C33—C32—H32A	119.3	O10—W3—O1	95.9 (5)
C31—C32—H32A	119.3	O9—W3—O1	96.0 (5)
C32—C33—C28	121.6 (19)	O22—W3—O2	157.6 (6)
C32—C33—H33A	119.2	O7—W3—O2	93.5 (6)
C28—C33—H33A	119.2	O6—W3—O2	94.2 (5)
N3—C34—H34A	109.5	O10—W3—O2	64.2 (6)
N3—C34—H34B	109.5	O9—W3—O2	65.2 (5)
H34A—C34—H34B	109.5	O1—W3—O2	45.0 (6)
N3—C34—H34C	109.5	O23—W4—O9	100.1 (5)
H34A—C34—H34C	109.5	O23—W4—O13^i	100.6 (5)
H34B—C34—H34C	109.5	O9—W4—O13^i	159.3 (5)
C36—C35—N4	100.6 (19)	O23—W4—O11	100.9 (5)
C36—C35—H35A	111.7	O9—W4—O11	89.4 (5)
N4—C35—H35A	111.7	O13^i—W4—O11	87.1 (5)
C36—C35—H35B	111.7	O23—W4—O12	99.0 (5)
N4—C35—H35B	111.7	O9—W4—O12	88.9 (5)
H35A—C35—H35B	109.4	O13^i—W4—O12	87.5 (5)
C35—C36—H36A	109.5	O11—W4—O12	160.1 (5)
C35—C36—H36B	109.5	O23—W4—O4^i	156.1 (6)
H36A—C36—H36B	109.5	O9—W4—O4^i	97.3 (5)
C35—C36—H36C	109.5	O13^i—W4—O4^i	62.8 (6)
H36A—C36—H36C	109.5	O11—W4—O4^i	95.5 (5)
H36B—C36—H36C	109.5	O12—W4—O4^i	65.0 (5)
C38—C37—N4	105 (2)	O23—W4—O2	158.7 (6)
C38—C37—H37A	110.7	O9—W4—O2	65.7 (5)
N4—C37—H37A	110.7	O13^i—W4—O2	94.5 (6)
C38—C37—H37B	110.7	O11—W4—O2	64.8 (5)
N4—C37—H37B	112.0	O12—W4—O2	96.6 (6)
H37A—C37—H37B	108.8	O4^i—W4—O2	45.2 (6)
C37—C38—H38A	109.5	O24—W5—O14^i	101.1 (6)
C37—C38—H38B	109.5	O24—W5—O10	100.9 (5)
H38A—C38—H38B	109.5	O14^i—W5—O10	158.0 (5)
C37—C38—H38C	109.5	O24—W5—O11	100.4 (5)
H38A—C38—H38C	109.5	O14^i—W5—O11	87.5 (5)
H38B—C38—H38C	109.5	O10—W5—O11	88.0 (5)
C21—N3—C25	117.3 (19)	O24—W5—O15	101.3 (5)
C21—N3—C34	122.2 (15)	O14^i—W5—O15	89.3 (5)
C25—N3—C34	120.3 (15)	O10—W5—O15	86.9 (5)
C31—N4—C37	125 (3)	O11—W5—O15	158.2 (5)
C31—N4—C35	120 (2)	O24—W5—O3^i	155.3 (6)
C37—N4—C35	113 (2)	O14^i—W5—O3^i	61.6 (6)
Si1—O1—W1	122.5 (9)	O10—W5—O3^i	97.6 (5)
Si1—O1—W2	122.5 (9)	O11—W5—O3^i	96.4 (5)
W1—O1—W2	95.4 (6)	O15—W5—O3^i	63.4 (5)
Si1—O1—W3	120.6 (9)	O24—W5—O2	158.2 (6)
W1—O1—W3	94.2 (6)	O14^i—W5—O2	94.3 (6)
W2—O1—W3	94.4 (6)	O10—W5—O2	64.5 (5)
Si1—O2—W4	122.4 (11)	O11—W5—O2	64.6 (5)
Si1—O2—W3	123.2 (9)	O15—W5—O2	94.2 (5)
W4—O2—W3	93.5 (6)	O3^i—W5—O2	46.5 (6)
Si1—O2—W5	122.6 (10)	O25—W6—O15	100.9 (5)
W4—O2—W5	93.4 (6)	O25—W6—O8^i	100.3 (6)
W3—O2—W5	93.6 (7)	O15—W6—O8^i	90.2 (5)
Si1—O3—W2	122.2 (9)	O25—W6—O16	102.1 (5)
Si1—O3—W5^i	119.8 (8)	O15—W6—O16	87.1 (5)
W2—O3—W5^i	97.3 (6)	O8^i—W6—O16	157.5 (5)
Si1—O3—W6^i	119.6 (9)	O25—W6—O12^i	99.2 (5)
W2—O3—W6^i	96.9 (6)	O15—W6—O12^i	159.9 (5)
W5^i—O3—W6^i	95.2 (6)	O8^i—W6—O12^i	87.6 (5)
Si1—O4—W1	122.6 (9)	O16—W6—O12^i	87.3 (5)
Si1—O4—W4^i	121.7 (9)	O25—W6—O3^i	155.5 (6)
W1—O4—W4^i	95.7 (7)	O15—W6—O3^i	64.1 (5)
Si1—O4—W6	120.3 (9)	O8^i—W6—O3^i	62.5 (6)
W1—O4—W6	94.9 (6)	O16—W6—O3^i	96.5 (5)
W4^i—O4—W6	94.9 (6)	O12^i—W6—O3^i	97.4 (5)
W1—O5—W2	137.0 (6)	O25—W6—O4	156.5 (6)
W1—O6—W3	138.0 (6)	O15—W6—O4	96.0 (5)
W3—O7—W2	139.1 (6)	O8^i—W6—O4	95.8 (6)
W6^i—O8—W2	137.2 (7)	O16—W6—O4	62.4 (5)
W4—O9—W3	135.0 (6)	O12^i—W6—O4	64.3 (5)
W5—O10—W3	137.5 (6)	O3^i—W6—O4	47.9 (6)

Symmetry codes: (i) −x+1, −y+2, −z+1; (ii) −x+2, −y+1, −z+2.

Hydrogen-bond geometry (Å, º)

D—H···A	D—H	H···A	D···A	D—H···A
C1—H1A···O8	0.93	2.53	3.27 (2)	137
C2—H2A···O9	0.93	2.52	3.34 (2)	148
C4—H4A···O25^iii	0.93	2.48	3.30 (2)	147
C14—H14A···O23^iv	0.96	2.44	3.39 (2)	169
C22—H22A···O24	0.92	2.48	3.33 (2)	153
C25—H25A···O14^v	0.93	2.47	3.20 (2)	136

Symmetry codes: (iii) x−1, y, z; (iv) −x, −y+2, −z+1; (v) x, y−1, z.