Acta Cryst. (2006). E62, m2588-m2590  [ doi:10.1107/S1600536806032314 ]

Bis(-N,N-diethyldithiocarbamato-³S,S':S')bis[(-N,N-diethyldithiocarbamato-²S,S')silver(II)]

N. Liu, J. Fan, W.-G. Zhang, X. Yin and M.-B. Xie

Abstract: The title Ag^II complex, [Ag₂(C₅H₁₀NS₂)₄], has been obtained by the reaction of AgNO₃ and Na(detc) with a 1:2 molar ratio in a methanol solution at 353 K (detc = N,N-diethyldithiocarbamate). In the crystal structure of the complex, two detc anions chelate to an Ag^II ion in an S,S'-bidentate manner, and an S atom of the detc anion bridges to the neighboring Ag^II ion to form the centrosymmetric dinuclear molecule.

Online 15 September 2006

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