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Acta Cryst. (2006). E62, m2981-m2983  [ doi:10.1107/S1600536806040190 ]

Carbonyl(8-hydroxyquinolinato-[kappa]2N,O)[tris(2,3,4,5,6-pentafluorophenyl)phosphine-[kappa]P]rhodium(I)

J. M. Janse van Rensburg and A. Roodt

Abstract: Molecules of the title compound, [Rh(C9H6NO)(C18F15P)(CO)], pack in a tail-to-tail fashion, with an intermolecular ligand-to-ligand [pi]-[pi] stacking distance of 3.399 (8) Å. The effective cone angle ([Theta]E) for the phosphine ligand is 163°. The bite angle of the bidentate oxine ligand is 80.77 (10)° and the Rh-P bond length is 2.2145 (11) Å.

Online 18 October 2006


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