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Acta Cryst. (2006). E62, m2990-m2991  [ doi:10.1107/S1600536806042565 ]

Tetraphenylarsonium diiododiisothiocyanatocobaltate(II)

R. S. Prasad, S. S. Singh, S. Upreti, N. K. Jha and A. Ramanan

Abstract: The use of mixed-ligand (iodide and thiocyanate) coordination with cobalt has led to the crystallization of the title compound, (C24H20As)2[CoI2(NCS)2]. The structure comprises tetrahedral (C6H5)4As+ cations and tetrahedral [CoI2(NCS)2]2- anions, the latter lying on crystallographic twofold axes.

Online 25 October 2006


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