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Acta Cryst. (2006). E62, m2799-m2801  [ doi:10.1107/S1600536806039377 ]

Di-[mu]-homophthalato-[kappa]3O:O',O'';[kappa]3O',O'':O-bis[aqua(1,10-phenanthroline)zinc(II)]

J.-H. Sun

Abstract: In the title compound, [Zn2(C9H6O4)2(C12H8N2)2(H2O)2], each ZnII atom is surrounded by three O atoms from two homophthalate dianions, one aqua O atom and two N atoms from a 1,10-phenanthroline (phen) heterocycle in a distorted octahedral geometry [Zn-O = 2.0440 (19)-2.256 (2) Å, and Zn-N = 2.113 (2) and 2.158 (2) Å]. Two [Zn(phen)(H2O)]2+ cations are linked by two bridging homophthalate dianions, resulting in a centrosymmetric binuclear complex.

Online 4 October 2006


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