Tetra­kis(1-ethyl-1H-imidazole-κN³)diisothio­cyanato­cobalt(II)

The structure of the title compound, [Co(NCS)₂(C₅H₈N₂)₄], consists of isolated mol­ecules of [Co(NCS)₂(Eim)₄] (Eim = 1-ethyl­imidazole), having an octa­hedral CoN₆ configuration. The NCS⁻ anions are positioned in a trans-configuration and four N atoms from the 1-ethyl­imidazole ligands define the equatorial plane. The mean Co—N(Eim) and Co—N(NCS) distances are 2.137 (6) and 2.152 (6) Å respectively.

Key indicators

• Single-crystal X-ray study
• T = 293 K
• Mean [sigma](C-C) = 0.012 Å
• R factor = 0.078
• wR factor = 0.195
• Data-to-parameter ratio = 17.2

checkCIF/PLATON results

No syntax errors found



Alert level B
PLAT220_ALERT_2_B Large Non-Solvent    C     Ueq(max)/Ueq(min) ...       3.95 Ratio
PLAT222_ALERT_3_B Large Non-Solvent    H     Ueq(max)/Ueq(min) ...       4.64 Ratio
PLAT242_ALERT_2_B Check Low       Ueq as Compared to Neighbors for        C11

Alert level C
PLAT026_ALERT_3_C Ratio Observed / Unique Reflections too Low ....         47 Perc.
PLAT066_ALERT_1_C Predicted and Reported Transmissions Identical .          ?
PLAT213_ALERT_2_C Atom C12     has ADP max/min Ratio .............       3.40 prola
PLAT242_ALERT_2_C Check Low       Ueq as Compared to Neighbors for         C1
PLAT242_ALERT_2_C Check Low       Ueq as Compared to Neighbors for         C2
PLAT242_ALERT_2_C Check Low       Ueq as Compared to Neighbors for         C6
PLAT341_ALERT_3_C Low Bond Precision on C-C bonds (x 1000) Ang ...         12
PLAT413_ALERT_2_C Short Inter XH3 .. XHn     H12A   ..  H17C    ..       2.14 Ang.

Alert level G
PLAT199_ALERT_1_G Check the Reported _cell_measurement_temperature        293 K
PLAT200_ALERT_1_G Check the Reported _diffrn_ambient_temperature .        293 K

   0 ALERT level A = In general: serious problem
   3 ALERT level B = Potentially serious problem
   8 ALERT level C = Check and explain
   2 ALERT level G = General alerts; check

   3 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
   7 ALERT type 2 Indicator that the structure model may be wrong or deficient
   3 ALERT type 3 Indicator that the structure quality may be low
   0 ALERT type 4 Improvement, methodology, query or suggestion
   0 ALERT type 5 Informative message, check

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Computing details

Data collection: CAD-4 Software (Enraf-Nonius, 1989); cell refinement: CAD-4 Software; data reduction: NRCVAX (Gabe et al., 1989); program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: SHELXTL-PC (Sheldrick, 1990); software used to prepare material for publication: WinGX (Farrugia, 1999).

(I)

Crystal data

[Co(C5H8N2)4(NCS)2]	F(000) = 2344
Mr = 559.65	Dx = 1.316 Mg m^−3
Orthorhombic, Pbca	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2ac 2ab	Cell parameters from 25 reflections
a = 16.096 (3) Å	θ = 4–14°
b = 17.769 (4) Å	µ = 0.79 mm^−1
c = 19.759 (4) Å	T = 293 K
V = 5651 (2) Å^3	Block, pink
Z = 8	0.30 × 0.20 × 0.10 mm

Data collection

Enraf-Nonius CAD-4 diffractometer	2610 reflections with I > 2σ(I)
Radiation source: fine-focus sealed tube	Rint = 0.020
Graphite monochromator	θmax = 26.0°, θmin = 2.0°
ω scans	h = 0→19
Absorption correction: multi-scan (SADABS; Sheldrick, 1996)	k = 0→21
Tmin = 0.828, Tmax = 0.924	l = 0→24
5632 measured reflections	3 standard reflections every 100 reflections
5531 independent reflections	intensity decay: none

Refinement

Refinement on F^2	Secondary atom site location: difference Fourier map
Least-squares matrix: full	Hydrogen site location: inferred from neighbouring sites
R[F^2 > 2σ(F^2)] = 0.078	H-atom parameters constrained
wR(F^2) = 0.195	w = 1/[σ^2(Fo^2) + (0.0702P)^2] where P = (Fo^2 + 2Fc^2)/3
S = 1.01	(Δ/σ)max < 0.001
5531 reflections	Δρmax = 0.62 e Å^−3
321 parameters	Δρmin = −0.42 e Å^−3
0 restraints	Extinction correction: SHELXL97, Fc^*=kFc[1+0.001xFc^2λ^3/sin(2θ)]^-1/4
Primary atom site location: structure-invariant direct methods	Extinction coefficient: 0.0016 (2)

Special details

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq
Co	0.27705 (5)	0.21299 (4)	0.70427 (4)	0.0383 (3)
S1	0.12621 (14)	0.40480 (12)	0.57623 (11)	0.0757 (7)
S2	0.35929 (14)	−0.01063 (11)	0.81766 (12)	0.0772 (7)
N1	0.1990 (4)	0.2989 (3)	0.6608 (3)	0.0541 (16)
N2	0.3527 (3)	0.1257 (3)	0.7475 (3)	0.0477 (14)
N3	0.2073 (3)	0.2207 (3)	0.7966 (3)	0.0432 (13)
N4	0.1278 (3)	0.2638 (3)	0.8784 (3)	0.0501 (15)
N5	0.1928 (3)	0.1293 (3)	0.6706 (3)	0.0428 (13)
N6	0.1382 (4)	0.0236 (3)	0.6306 (3)	0.0523 (15)
N7	0.3455 (3)	0.2003 (3)	0.6119 (3)	0.0413 (13)
N8	0.3742 (4)	0.2054 (3)	0.5029 (3)	0.0538 (15)
N9	0.3601 (3)	0.2992 (3)	0.7380 (3)	0.0397 (13)
N10	0.4081 (4)	0.4061 (3)	0.7775 (3)	0.0523 (15)
C1	0.1679 (4)	0.3423 (4)	0.6257 (3)	0.0455 (17)
C2	0.3565 (4)	0.0683 (4)	0.7751 (3)	0.0430 (16)
C3	0.1629 (4)	0.2768 (4)	0.8187 (3)	0.0456 (17)
H3A	0.1563	0.3216	0.7950	0.055*
C4	0.1518 (5)	0.1916 (4)	0.8978 (4)	0.059 (2)
H4A	0.1375	0.1663	0.9373	0.070*
C5	0.2004 (4)	0.1663 (4)	0.8467 (3)	0.0523 (19)
H5A	0.2256	0.1193	0.8453	0.063*
C6	0.0783 (5)	0.3155 (4)	0.9194 (4)	0.067 (2)
H6A	0.0278	0.2902	0.9334	0.080*
H6B	0.0626	0.3583	0.8918	0.080*
C7	0.1228 (7)	0.3430 (5)	0.9806 (5)	0.118 (4)
H7A	0.0885	0.3786	1.0041	0.178*
H7B	0.1738	0.3668	0.9672	0.178*
H7C	0.1348	0.3013	1.0099	0.178*
C8	0.2081 (4)	0.0611 (4)	0.6461 (3)	0.0490 (18)
H8A	0.2613	0.0415	0.6403	0.059*
C9	0.0746 (4)	0.0685 (4)	0.6460 (4)	0.056 (2)
H9A	0.0184	0.0578	0.6412	0.067*
C10	0.1085 (4)	0.1333 (4)	0.6703 (3)	0.0510 (18)
H10A	0.0780	0.1748	0.6847	0.061*
C11	0.1343 (6)	−0.0532 (4)	0.6009 (5)	0.080 (3)
H11A	0.1853	−0.0798	0.6117	0.096*
H11B	0.0886	−0.0805	0.6214	0.096*
C12	0.1234 (9)	−0.0524 (5)	0.5288 (5)	0.170 (7)
H12A	0.1103	−0.1022	0.5134	0.255*
H12B	0.1737	−0.0355	0.5076	0.255*
H12C	0.0787	−0.0189	0.5173	0.255*
C13	0.3268 (4)	0.2307 (4)	0.5529 (3)	0.0506 (19)
H13A	0.2848	0.2661	0.5469	0.061*
C14	0.4281 (5)	0.1563 (4)	0.5311 (4)	0.061 (2)
H14A	0.4700	0.1298	0.5090	0.074*
C15	0.4093 (5)	0.1532 (4)	0.5976 (4)	0.063 (2)
H15A	0.4362	0.1231	0.6291	0.075*
C16	0.3671 (6)	0.2276 (5)	0.4307 (4)	0.081 (3)
H16A	0.3683	0.1827	0.4028	0.097*
H16B	0.3140	0.2521	0.4237	0.097*
C17	0.4336 (7)	0.2784 (5)	0.4088 (4)	0.111 (4)
H17A	0.4244	0.2929	0.3627	0.166*
H17B	0.4861	0.2531	0.4125	0.166*
H17C	0.4339	0.3223	0.4370	0.166*
C18	0.3402 (4)	0.3679 (4)	0.7597 (3)	0.0515 (18)
H18A	0.2864	0.3866	0.7621	0.062*
C19	0.4756 (5)	0.3609 (4)	0.7685 (4)	0.061 (2)
H19A	0.5308	0.3719	0.7782	0.073*
C20	0.4442 (4)	0.2964 (4)	0.7423 (3)	0.0506 (18)
H20A	0.4763	0.2555	0.7290	0.061*
C21	0.4093 (6)	0.4836 (4)	0.8068 (4)	0.077 (3)
H21A	0.4605	0.5084	0.7935	0.092*
H21B	0.3635	0.5123	0.7880	0.092*
C22	0.4029 (6)	0.4843 (4)	0.8811 (4)	0.096 (3)
H22A	0.4063	0.5352	0.8972	0.144*
H22B	0.4476	0.4554	0.9001	0.144*
H22C	0.3508	0.4628	0.8945	0.144*

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Co	0.0474 (5)	0.0302 (4)	0.0373 (5)	0.0014 (4)	0.0037 (4)	0.0015 (4)
S1	0.0902 (16)	0.0679 (14)	0.0691 (14)	0.0140 (13)	−0.0206 (13)	0.0183 (11)
S2	0.0860 (16)	0.0388 (11)	0.1067 (18)	−0.0030 (11)	−0.0113 (14)	0.0265 (11)
N1	0.067 (4)	0.049 (4)	0.046 (3)	0.003 (3)	0.000 (3)	0.009 (3)
N2	0.056 (4)	0.041 (3)	0.046 (3)	0.002 (3)	−0.001 (3)	0.009 (3)
N3	0.053 (3)	0.030 (3)	0.046 (3)	0.005 (3)	0.012 (3)	−0.003 (3)
N4	0.064 (4)	0.039 (3)	0.048 (3)	0.001 (3)	0.013 (3)	−0.003 (3)
N5	0.042 (3)	0.044 (3)	0.043 (3)	−0.008 (3)	−0.003 (3)	−0.007 (3)
N6	0.056 (4)	0.040 (3)	0.061 (4)	−0.010 (3)	−0.008 (3)	−0.006 (3)
N7	0.044 (3)	0.039 (3)	0.042 (3)	0.007 (3)	0.004 (3)	−0.002 (3)
N8	0.069 (4)	0.057 (4)	0.036 (3)	−0.002 (3)	0.003 (3)	−0.005 (3)
N9	0.044 (3)	0.032 (3)	0.043 (3)	0.001 (3)	0.002 (3)	0.003 (3)
N10	0.069 (4)	0.038 (3)	0.051 (4)	−0.010 (3)	−0.006 (3)	0.001 (3)
C1	0.060 (5)	0.041 (4)	0.035 (4)	−0.007 (4)	0.000 (4)	−0.003 (3)
C2	0.048 (4)	0.033 (3)	0.048 (4)	0.001 (3)	−0.008 (3)	−0.002 (3)
C3	0.055 (4)	0.037 (4)	0.046 (4)	−0.009 (3)	0.011 (3)	0.002 (3)
C4	0.090 (6)	0.031 (4)	0.055 (5)	0.002 (4)	0.025 (4)	0.010 (3)
C5	0.067 (5)	0.029 (4)	0.061 (5)	0.004 (3)	0.019 (4)	0.003 (3)
C6	0.082 (6)	0.050 (5)	0.067 (5)	0.016 (4)	0.031 (5)	−0.004 (4)
C7	0.167 (10)	0.097 (8)	0.092 (7)	0.017 (7)	0.028 (7)	−0.050 (6)
C8	0.052 (5)	0.047 (4)	0.048 (4)	0.004 (4)	−0.003 (4)	0.000 (3)
C9	0.040 (4)	0.064 (5)	0.065 (5)	−0.008 (4)	−0.005 (4)	0.011 (4)
C10	0.047 (4)	0.048 (4)	0.058 (5)	0.001 (4)	0.000 (4)	−0.002 (4)
C11	0.099 (7)	0.038 (4)	0.104 (7)	−0.005 (5)	−0.027 (6)	−0.002 (5)
C12	0.348 (19)	0.058 (6)	0.105 (8)	0.025 (9)	−0.115 (11)	−0.033 (6)
C13	0.053 (4)	0.054 (5)	0.044 (4)	0.007 (4)	0.005 (4)	0.000 (4)
C14	0.066 (5)	0.071 (5)	0.047 (5)	0.015 (4)	0.009 (4)	−0.007 (4)
C15	0.068 (5)	0.058 (5)	0.062 (5)	0.017 (4)	0.006 (4)	0.006 (4)
C16	0.107 (7)	0.099 (7)	0.037 (4)	−0.009 (6)	−0.004 (5)	−0.004 (5)
C17	0.170 (10)	0.110 (8)	0.052 (6)	−0.036 (8)	0.025 (6)	0.007 (6)
C18	0.049 (4)	0.043 (4)	0.062 (5)	0.000 (4)	0.000 (4)	0.011 (4)
C19	0.058 (5)	0.053 (5)	0.072 (6)	−0.014 (4)	−0.013 (4)	−0.003 (4)
C20	0.047 (4)	0.049 (4)	0.056 (4)	0.007 (4)	0.002 (4)	−0.001 (4)
C21	0.109 (7)	0.035 (4)	0.085 (6)	−0.005 (5)	−0.011 (5)	−0.011 (4)
C22	0.165 (10)	0.047 (5)	0.077 (6)	0.025 (6)	−0.033 (7)	−0.018 (5)

Geometric parameters (Å, º)

Co—N5	2.119 (5)	C6—H6A	0.9700
Co—N9	2.140 (5)	C6—H6B	0.9700
Co—N7	2.143 (5)	C7—H7A	0.9600
Co—N3	2.147 (5)	C7—H7B	0.9600
Co—N2	2.148 (5)	C7—H7C	0.9600
Co—N1	2.156 (6)	C8—H8A	0.9300
S1—C1	1.625 (7)	C9—C10	1.362 (9)
S2—C2	1.636 (7)	C9—H9A	0.9300
N1—C1	1.152 (7)	C10—H10A	0.9300
N2—C2	1.159 (7)	C11—C12	1.435 (11)
N3—C3	1.302 (7)	C11—H11A	0.9700
N3—C5	1.387 (7)	C11—H11B	0.9700
N4—C3	1.328 (8)	C12—H12A	0.9600
N4—C4	1.393 (8)	C12—H12B	0.9600
N4—C6	1.460 (8)	C12—H12C	0.9600
N5—C8	1.329 (8)	C13—H13A	0.9300
N5—C10	1.358 (8)	C14—C15	1.349 (9)
N6—C9	1.333 (8)	C14—H14A	0.9300
N6—C8	1.344 (8)	C15—H15A	0.9300
N6—C11	1.486 (8)	C16—C17	1.465 (11)
N7—C13	1.319 (8)	C16—H16A	0.9700
N7—C15	1.355 (8)	C16—H16B	0.9700
N8—C13	1.327 (8)	C17—H17A	0.9600
N8—C14	1.351 (8)	C17—H17B	0.9600
N8—C16	1.485 (8)	C17—H17C	0.9600
N9—C18	1.332 (7)	C18—H18A	0.9300
N9—C20	1.357 (7)	C19—C20	1.355 (9)
N10—C18	1.334 (8)	C19—H19A	0.9300
N10—C19	1.362 (8)	C20—H20A	0.9300
N10—C21	1.494 (8)	C21—C22	1.472 (10)
C3—H3A	0.9300	C21—H21A	0.9700
C4—C5	1.354 (8)	C21—H21B	0.9700
C4—H4A	0.9300	C22—H22A	0.9600
C5—H5A	0.9300	C22—H22B	0.9600
C6—C7	1.487 (11)	C22—H22C	0.9600
N5—Co—N9	178.8 (2)	N5—C8—N6	112.3 (6)
N5—Co—N7	89.33 (19)	N5—C8—H8A	123.9
N9—Co—N7	91.10 (19)	N6—C8—H8A	123.9
N5—Co—N3	88.66 (19)	N6—C9—C10	106.3 (6)
N9—Co—N3	90.94 (19)	N6—C9—H9A	126.9
N7—Co—N3	177.59 (19)	C10—C9—H9A	126.9
N5—Co—N2	88.9 (2)	N5—C10—C9	111.0 (6)
N9—Co—N2	92.23 (19)	N5—C10—H10A	124.5
N7—Co—N2	88.4 (2)	C9—C10—H10A	124.5
N3—Co—N2	90.3 (2)	C12—C11—N6	112.7 (7)
N5—Co—N1	89.9 (2)	C12—C11—H11A	109.0
N9—Co—N1	88.9 (2)	N6—C11—H11A	109.0
N7—Co—N1	92.0 (2)	C12—C11—H11B	109.0
N3—Co—N1	89.3 (2)	N6—C11—H11B	109.0
N2—Co—N1	178.8 (2)	H11A—C11—H11B	107.8
C1—N1—Co	165.4 (6)	C11—C12—H12A	109.5
C2—N2—Co	148.5 (5)	C11—C12—H12B	109.5
C3—N3—C5	104.5 (5)	H12A—C12—H12B	109.5
C3—N3—Co	128.4 (4)	C11—C12—H12C	109.5
C5—N3—Co	127.1 (4)	H12A—C12—H12C	109.5
C3—N4—C4	106.6 (6)	H12B—C12—H12C	109.5
C3—N4—C6	128.0 (6)	N7—C13—N8	112.8 (6)
C4—N4—C6	125.3 (6)	N7—C13—H13A	123.6
C8—N5—C10	103.4 (6)	N8—C13—H13A	123.6
C8—N5—Co	129.4 (5)	C15—C14—N8	106.4 (7)
C10—N5—Co	127.2 (5)	C15—C14—H14A	126.8
C9—N6—C8	107.1 (6)	N8—C14—H14A	126.8
C9—N6—C11	127.5 (6)	C14—C15—N7	110.5 (7)
C8—N6—C11	125.4 (7)	C14—C15—H15A	124.8
C13—N7—C15	103.9 (6)	N7—C15—H15A	124.8
C13—N7—Co	126.3 (4)	C17—C16—N8	113.0 (7)
C15—N7—Co	129.2 (5)	C17—C16—H16A	109.0
C13—N8—C14	106.4 (6)	N8—C16—H16A	109.0
C13—N8—C16	125.5 (7)	C17—C16—H16B	109.0
C14—N8—C16	128.1 (6)	N8—C16—H16B	109.0
C18—N9—C20	104.6 (6)	H16A—C16—H16B	107.8
C18—N9—Co	127.3 (5)	C16—C17—H17A	109.5
C20—N9—Co	128.1 (4)	C16—C17—H17B	109.5
C18—N10—C19	108.5 (6)	H17A—C17—H17B	109.5
C18—N10—C21	125.6 (7)	C16—C17—H17C	109.5
C19—N10—C21	125.7 (6)	H17A—C17—H17C	109.5
N1—C1—S1	178.5 (7)	H17B—C17—H17C	109.5
N2—C2—S2	176.8 (6)	N9—C18—N10	110.8 (6)
N3—C3—N4	113.5 (6)	N9—C18—H18A	124.6
N3—C3—H3A	123.3	N10—C18—H18A	124.6
N4—C3—H3A	123.3	C20—C19—N10	104.6 (6)
C5—C4—N4	105.1 (6)	C20—C19—H19A	127.7
C5—C4—H4A	127.4	N10—C19—H19A	127.7
N4—C4—H4A	127.4	C19—C20—N9	111.4 (6)
C4—C5—N3	110.3 (6)	C19—C20—H20A	124.3
C4—C5—H5A	124.9	N9—C20—H20A	124.3
N3—C5—H5A	124.9	C22—C21—N10	113.2 (6)
N4—C6—C7	113.3 (7)	C22—C21—H21A	108.9
N4—C6—H6A	108.9	N10—C21—H21A	108.9
C7—C6—H6A	108.9	C22—C21—H21B	108.9
N4—C6—H6B	108.9	N10—C21—H21B	108.9
C7—C6—H6B	108.9	H21A—C21—H21B	107.8
H6A—C6—H6B	107.7	C21—C22—H22A	109.5
C6—C7—H7A	109.5	C21—C22—H22B	109.5
C6—C7—H7B	109.5	H22A—C22—H22B	109.5
H7A—C7—H7B	109.5	C21—C22—H22C	109.5
C6—C7—H7C	109.5	H22A—C22—H22C	109.5
H7A—C7—H7C	109.5	H22B—C22—H22C	109.5
H7B—C7—H7C	109.5
N5—Co—N1—C1	−91 (2)	C4—N4—C3—N3	0.2 (8)
N9—Co—N1—C1	90 (2)	C6—N4—C3—N3	176.1 (7)
N7—Co—N1—C1	−1 (2)	C3—N4—C4—C5	−0.2 (8)
N3—Co—N1—C1	−179 (2)	C6—N4—C4—C5	−176.3 (7)
N5—Co—N2—C2	−36.5 (10)	N4—C4—C5—N3	0.2 (8)
N9—Co—N2—C2	143.1 (10)	C3—N3—C5—C4	−0.1 (8)
N7—Co—N2—C2	−125.8 (10)	Co—N3—C5—C4	179.4 (5)
N3—Co—N2—C2	52.2 (10)	C3—N4—C6—C7	−107.4 (9)
N5—Co—N3—C3	−112.9 (6)	C4—N4—C6—C7	67.9 (10)
N9—Co—N3—C3	66.0 (6)	C10—N5—C8—N6	0.3 (7)
N2—Co—N3—C3	158.2 (6)	Co—N5—C8—N6	179.4 (4)
N1—Co—N3—C3	−22.9 (6)	C9—N6—C8—N5	−0.6 (8)
N5—Co—N3—C5	67.8 (5)	C11—N6—C8—N5	178.7 (6)
N9—Co—N3—C5	−113.4 (5)	C8—N6—C9—C10	0.5 (8)
N2—Co—N3—C5	−21.2 (5)	C11—N6—C9—C10	−178.7 (7)
N1—Co—N3—C5	157.7 (5)	C8—N5—C10—C9	0.0 (8)
N7—Co—N5—C8	50.2 (6)	Co—N5—C10—C9	−179.1 (4)
N3—Co—N5—C8	−128.5 (6)	N6—C9—C10—N5	−0.4 (8)
N2—Co—N5—C8	−38.2 (6)	C9—N6—C11—C12	81.5 (11)
N1—Co—N5—C8	142.2 (6)	C8—N6—C11—C12	−97.7 (10)
N7—Co—N5—C10	−130.9 (6)	C15—N7—C13—N8	0.4 (8)
N3—Co—N5—C10	50.4 (6)	Co—N7—C13—N8	−171.9 (4)
N2—Co—N5—C10	140.7 (6)	C14—N8—C13—N7	−0.9 (8)
N1—Co—N5—C10	−38.9 (6)	C16—N8—C13—N7	178.6 (6)
N5—Co—N7—C13	80.8 (6)	C13—N8—C14—C15	1.1 (8)
N9—Co—N7—C13	−98.1 (6)	C16—N8—C14—C15	−178.4 (7)
N2—Co—N7—C13	169.7 (6)	N8—C14—C15—N7	−1.0 (9)
N1—Co—N7—C13	−9.1 (6)	C13—N7—C15—C14	0.4 (8)
N5—Co—N7—C15	−89.6 (6)	Co—N7—C15—C14	172.4 (5)
N9—Co—N7—C15	91.6 (6)	C13—N8—C16—C17	105.9 (9)
N2—Co—N7—C15	−0.6 (6)	C14—N8—C16—C17	−74.7 (10)
N1—Co—N7—C15	−179.5 (6)	C20—N9—C18—N10	−0.7 (7)
N7—Co—N9—C18	127.3 (5)	Co—N9—C18—N10	179.2 (4)
N3—Co—N9—C18	−54.0 (5)	C19—N10—C18—N9	−1.2 (8)
N2—Co—N9—C18	−144.3 (5)	C21—N10—C18—N9	−177.2 (6)
N1—Co—N9—C18	35.3 (5)	C18—N10—C19—C20	2.4 (8)
N7—Co—N9—C20	−52.9 (5)	C21—N10—C19—C20	178.5 (6)
N3—Co—N9—C20	125.8 (5)	N10—C19—C20—N9	−2.9 (8)
N2—Co—N9—C20	35.5 (6)	C18—N9—C20—C19	2.3 (8)
N1—Co—N9—C20	−144.9 (6)	Co—N9—C20—C19	−177.6 (5)
C5—N3—C3—N4	0.0 (7)	C18—N10—C21—C22	88.5 (9)
Co—N3—C3—N4	−179.5 (4)	C19—N10—C21—C22	−86.9 (10)