Acta Cryst. (2006). E62, m3068-m3070  [ doi:10.1107/S1600536806042991 ]

Bis(dicyanamidato-N)(di-2-pyridylamine-²N,N')nickel(II)

C.-Y. Huang, Y. Fang, Y.-P. Gu, L.-C. Zhang and W.-S. You

Abstract: The central Ni^II ion of the title complex, [Ni(C₂N₃)₂(C₁₀H₉N₃)₂], has an approximate octahedral geometry, coordinated by four N atoms from the pyridine rings of the two bidentate di-2-pyridylamine ligands, and by two terminal N atoms from the two dicyanamide ligands. The coordination octahedron around each nickel ion has C₂ symmetry and the two dicyanamide ligands are in cis positions.

Online 25 October 2006

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