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Acta Cryst. (2006). E62, m2813-m2815  [ doi:10.1107/S160053680603193X ]

Poly[[[(4,7-diphenyl-1,10-phenanthroline)zinc(II)]-[mu]-benzene-1,3-dicarboxylato] monohydrate]

X.-M. Li, Q.-W. Wang and B. Liu

Abstract: In the title compound, {[Zn(C8H4O4)(C24H16N2)]·H2O}n, the Zn center is coordinated by three O atoms from three different benzene-1,3-dicarboxylate dianions and two N atoms from the bidentate 4,7-diphenyl-1,10-phenanthroline ligand to display a distorted trigonal-bipyramidal geometry. The benzene-1,3-dicarboxylate ligand acts as a [mu]3-bridge, resulting in a two-dimensional coordination polymer with rhombus-shaped channels.

Online 4 October 2006


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