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Acta Cryst. (2006). E62, m3122-m3124  [ doi:10.1107/S160053680604400X ]

Di-[mu]-sulfato-bis[diaqua(dipyrido[3,2-a:2',3'-c]phenazine)iron(II)] monohydrate

C.-B. Li, E.-J. Dong, W. Fang, B. Liu and Y.-W. Li

Abstract: In the title compound, [Fe2(SO4)2(C18H10N4)2(H2O)4]·H2O, the FeII atoms are octahedrally coordinated by two N atoms from one bidentate dipyrido[3,2-a:2',3'-c]phenazine (dppz) ligand, two O atoms belonging to two SO42- anions and two water O atoms. The two crystallographically independent dinuclear complex molecules are both generated by inversion symmetry with the sulfate ions acting as bridges. Neighbouring dinuclear complexes interact via O-H...O hydrogen bonds, leading to a chain structure.

Online 27 October 2006


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