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Acta Cryst. (2006). E62, m2866-m2868  [ doi:10.1107/S1600536806040475 ]

catena-Poly[[[(2,2'-bipyridine-[kappa]2N,N')(formato-[kappa]O)copper(II)]-[mu]-formato-[kappa]2O:O'] formic acid solvate]

J.-L. Lin, L.-J. Hu, L. Wu, Y.-Y. Wang and Y.-Q. Zheng

Abstract: The title compound, [Cu(HCOO)([mu]-HCOO)2/2(2,2'-bpy)]·HCOOH (2,2'-bpy is 2,2'-bipyridine, C10H8N2), consists of formic acid molecules and [Cu(2,2'-bpy)(HCOO)([mu]-HCOO)2/2]n polymeric chains; the chains have square-pyramidal Cu atoms bridged by formate anions. The polymeric chains are further extended into three-dimensional networks via interchain [pi]-[pi] interactions as well as C-H...O and O-H...O hydrogen bonds.

Online 13 October 2006


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