Acta Cryst. (2006). E62, m3281-m3283  [ doi:10.1107/S1600536806046733 ]

catena-Poly[[diaqua(1,10-phenanthroline-²N,N')manganese(II)]--acetylenedicarboxylato-²O:O']

H.-Y. Wang, S. Gao, L.-H. Huo and J.-G. Zhao

Abstract: In the title complex, [Mn(C₄O₄)(C₁₂H₈N₂)(H₂O)₂]_n, each Mn^II ion is octahedrally coordinated by two N atoms of a 1,10-phenanthroline ligand, two carboxylate O atoms of different acetylenedicarboxylate (ace^2-) ligands and two coordinated water molecules, and the octahedral units are connected by ace^2- bridges, which adopt a bis-monodentate coordination mode, to form a one-dimensional structure along the [101] direction. A three-dimensional supramolecular architecture is constructed via hydrogen-bond and - interactions.

Online 10 November 2006

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