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The title complex, [Co(CH3)2(C8H7O3)(C3H9P)2], crystallizes with two mol­ecules in the asymmetric unit. The CoIII centre has a distorted octa­hedral geometry in both mol­ecules.

Supporting information

cif

Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536806048860/bh2057sup1.cif
Contains datablocks global, I

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S1600536806048860/bh2057Isup2.hkl
Contains datablock I

CCDC reference: 629429

Key indicators

  • Single-crystal X-ray study
  • T = 294 K
  • Mean [sigma](C-C) = 0.008 Å
  • R factor = 0.042
  • wR factor = 0.109
  • Data-to-parameter ratio = 17.5

checkCIF/PLATON results

No syntax errors found



Alert level B PLAT242_ALERT_2_B Check Low Ueq as Compared to Neighbors for P1 PLAT242_ALERT_2_B Check Low Ueq as Compared to Neighbors for P4
Alert level C PLAT034_ALERT_1_C No Flack Parameter Given. Z .GT. Si, NonCentro . ? PLAT220_ALERT_2_C Large Non-Solvent C Ueq(max)/Ueq(min) ... 3.13 Ratio PLAT220_ALERT_2_C Large Non-Solvent C Ueq(max)/Ueq(min) ... 2.93 Ratio PLAT242_ALERT_2_C Check Low Ueq as Compared to Neighbors for P2 PLAT242_ALERT_2_C Check Low Ueq as Compared to Neighbors for P3 PLAT341_ALERT_3_C Low Bond Precision on C-C bonds (x 1000) Ang ... 8
Alert level G REFLT03_ALERT_4_G Please check that the estimate of the number of Friedel pairs is correct. If it is not, please give the correct count in the _publ_section_exptl_refinement section of the submitted CIF. From the CIF: _diffrn_reflns_theta_max 25.01 From the CIF: _reflns_number_total 7286 Count of symmetry unique reflns 4121 Completeness (_total/calc) 176.80% TEST3: Check Friedels for noncentro structure Estimate of Friedel pairs measured 3165 Fraction of Friedel pairs measured 0.768 Are heavy atom types Z>Si present yes
0 ALERT level A = In general: serious problem 2 ALERT level B = Potentially serious problem 6 ALERT level C = Check and explain 1 ALERT level G = General alerts; check 1 ALERT type 1 CIF construction/syntax error, inconsistent or missing data 6 ALERT type 2 Indicator that the structure model may be wrong or deficient 1 ALERT type 3 Indicator that the structure quality may be low 1 ALERT type 4 Improvement, methodology, query or suggestion 0 ALERT type 5 Informative message, check

Computing details top

Data collection: SMART (Bruker, 1997); cell refinement: SMART; data reduction: SAINT (Bruker, 1997); program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: SHELXTL (Bruker, 1997); software used to prepare material for publication: SHELXTL.

(2-Formyl-6-methoxyphenolato-κ2O,O')-cis-dimethyl-trans- bis(trimethylphosphine-κP)cobalt(III) top
Crystal data top
[Co(CH3)2(C8H7O3)(C3H9P)2]F(000) = 1664
Mr = 392.28Dx = 1.259 Mg m3
Orthorhombic, P212121Mo Kα radiation, λ = 0.71073 Å
Hall symbol: P 2ac 2abCell parameters from 4681 reflections
a = 9.0948 (9) Åθ = 2.3–24.3°
b = 12.9794 (13) ŵ = 0.99 mm1
c = 35.070 (3) ÅT = 294 K
V = 4139.8 (7) Å3Block, red
Z = 80.30 × 0.24 × 0.15 mm
Data collection top
Bruker APEX-II CCD area-detector
diffractometer
7286 independent reflections
Radiation source: fine-focus sealed tube5070 reflections with I > 2σ(I)
Graphite monochromatorRint = 0.048
φ and ω scansθmax = 25.0°, θmin = 1.2°
Absorption correction: multi-scan
(SADABS; Sheldrick, 1996)
h = 109
Tmin = 0.755, Tmax = 0.866k = 1415
19456 measured reflectionsl = 4137
Refinement top
Refinement on F2Secondary atom site location: difference Fourier map
Least-squares matrix: fullHydrogen site location: inferred from neighbouring sites
R[F2 > 2σ(F2)] = 0.042H-atom parameters constrained
wR(F2) = 0.109 w = 1/[σ2(Fo2) + (0.0518P)2 + 1.3024P]
where P = (Fo2 + 2Fc2)/3
S = 0.97(Δ/σ)max = 0.028
7286 reflectionsΔρmax = 0.40 e Å3
416 parametersΔρmin = 0.37 e Å3
0 restraintsAbsolute structure: Flack (1983), 3165 Friedel pairs
Primary atom site location: structure-invariant direct methodsAbsolute structure parameter: 0.50 (2)
Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
Co10.63298 (7)0.61577 (5)0.094726 (17)0.04034 (17)
Co20.98007 (7)0.11692 (5)0.097483 (17)0.04283 (18)
P10.44395 (16)0.58151 (12)0.13225 (4)0.0541 (4)
P20.80976 (16)0.65393 (11)0.05339 (4)0.0515 (4)
P30.80649 (17)0.15344 (11)0.05505 (4)0.0537 (4)
P41.16590 (17)0.08149 (13)0.13615 (4)0.0591 (4)
O10.7195 (4)0.4763 (2)0.10473 (10)0.0532 (9)
O20.7479 (4)0.6745 (2)0.13871 (9)0.0434 (8)
O30.8664 (5)0.7830 (3)0.19313 (11)0.0779 (13)
O40.8893 (4)0.0210 (2)0.10712 (10)0.0516 (9)
O50.8626 (4)0.1773 (2)0.14083 (9)0.0424 (8)
O60.7432 (4)0.2861 (3)0.19589 (10)0.0636 (11)
C10.8111 (6)0.4546 (4)0.12965 (15)0.0507 (14)
H10.83930.38580.13080.061*
C20.8786 (6)0.5208 (4)0.15676 (14)0.0446 (13)
C30.9858 (6)0.4784 (5)0.18140 (17)0.0613 (16)
H31.01060.40920.17870.074*
C41.0530 (6)0.5341 (5)0.20849 (17)0.0674 (18)
H41.12440.50440.22400.081*
C51.0138 (7)0.6380 (5)0.21309 (14)0.0628 (16)
H51.05840.67660.23220.075*
C60.9124 (6)0.6831 (4)0.19027 (14)0.0494 (14)
C70.8393 (5)0.6274 (4)0.15997 (12)0.0392 (11)
C80.9169 (10)0.8406 (6)0.22488 (19)0.122 (3)
H8A0.87860.81110.24790.182*
H8B0.88380.91060.22260.182*
H8C1.02240.83920.22560.182*
C90.4137 (8)0.4456 (5)0.1423 (2)0.108 (3)
H9A0.32660.43790.15760.161*
H9B0.49660.41840.15600.161*
H9C0.40180.40870.11880.161*
C100.4560 (8)0.6380 (7)0.17929 (17)0.111 (3)
H10A0.43600.71050.17770.167*
H10B0.55310.62750.18930.167*
H10C0.38530.60580.19580.167*
C110.2641 (7)0.6212 (7)0.1168 (2)0.102 (3)
H11A0.19090.58950.13270.153*
H11B0.24930.60040.09080.153*
H11C0.25600.69470.11860.153*
C120.7569 (9)0.7117 (7)0.00796 (17)0.101 (3)
H12A0.70870.77640.01250.152*
H12B0.69100.66630.00530.152*
H12C0.84310.72300.00730.152*
C130.9205 (9)0.5455 (5)0.0376 (2)0.106 (3)
H13A0.86010.49850.02340.159*
H13B0.96070.51070.05940.159*
H13C0.99900.56990.02170.159*
C140.9480 (7)0.7433 (4)0.07077 (17)0.0683 (17)
H14A1.02740.74710.05280.102*
H14B0.98490.71970.09490.102*
H14C0.90490.81030.07380.102*
C150.5200 (7)0.5519 (5)0.05193 (14)0.0649 (17)
H15A0.58720.52130.03410.097*
H15B0.46310.60400.03930.097*
H15C0.45560.49990.06190.097*
C160.5488 (6)0.7553 (4)0.08641 (14)0.0554 (15)
H16A0.52400.78550.11060.083*
H16B0.46190.74990.07100.083*
H16C0.61980.79790.07370.083*
C170.7984 (6)0.0426 (4)0.13190 (16)0.0536 (15)
H170.76850.11110.13270.064*
C180.7336 (6)0.0233 (4)0.15926 (14)0.0448 (13)
C190.6287 (7)0.0212 (5)0.18478 (17)0.0655 (17)
H190.60390.09040.18210.079*
C200.5649 (7)0.0346 (5)0.21251 (18)0.0743 (19)
H200.49710.00410.22880.089*
C210.6008 (6)0.1391 (5)0.21685 (15)0.0616 (16)
H210.55600.17740.23600.074*
C220.7008 (6)0.1854 (4)0.19332 (13)0.0489 (13)
C230.7718 (5)0.1302 (4)0.16240 (13)0.0406 (12)
C240.6816 (8)0.3461 (5)0.22544 (17)0.085 (2)
H24A0.57700.34990.22210.127*
H24B0.72260.41420.22470.127*
H24C0.70350.31490.24960.127*
C250.7033 (9)0.0428 (5)0.0372 (2)0.109 (3)
H25A0.63600.06510.01780.164*
H25B0.64940.01200.05780.164*
H25C0.77020.00680.02670.164*
C260.6607 (7)0.2375 (5)0.07166 (17)0.0732 (18)
H26A0.58220.23800.05340.110*
H26B0.69830.30610.07470.110*
H26C0.62440.21280.09570.110*
C270.8633 (9)0.2142 (7)0.01057 (17)0.105 (3)
H27A0.93910.17360.00120.158*
H27B0.90030.28200.01580.158*
H27C0.78060.21890.00630.158*
C281.1961 (9)0.0543 (6)0.1450 (3)0.118 (3)
H28A1.27290.06240.16360.177*
H28B1.22420.08780.12170.177*
H28C1.10720.08480.15450.177*
C291.1494 (8)0.1345 (7)0.18371 (17)0.117 (3)
H29A1.07840.09550.19790.175*
H29B1.11810.20500.18210.175*
H29C1.24300.13100.19630.175*
C301.3477 (7)0.1233 (7)0.1226 (2)0.113 (3)
H30A1.41830.09690.14040.169*
H30B1.35150.19720.12260.169*
H30C1.37010.09810.09750.169*
C311.0959 (7)0.0523 (5)0.05546 (15)0.0710 (18)
H31A1.16880.00720.06610.107*
H31B1.14330.10510.04080.107*
H31C1.03120.01340.03930.107*
C321.0677 (6)0.2556 (4)0.08887 (15)0.0594 (15)
H32A0.99960.29770.07490.089*
H32B1.15710.24870.07460.089*
H32C1.08860.28730.11300.089*
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Co10.0486 (4)0.0379 (3)0.0345 (3)0.0006 (3)0.0030 (3)0.0045 (3)
Co20.0485 (4)0.0384 (4)0.0416 (3)0.0017 (3)0.0077 (3)0.0056 (4)
P10.0515 (9)0.0613 (10)0.0494 (8)0.0030 (8)0.0009 (7)0.0001 (7)
P20.0648 (10)0.0475 (8)0.0421 (8)0.0031 (7)0.0085 (7)0.0042 (6)
P30.0701 (11)0.0459 (8)0.0452 (8)0.0033 (7)0.0051 (7)0.0054 (6)
P40.0504 (9)0.0630 (10)0.0638 (9)0.0080 (8)0.0002 (8)0.0012 (8)
O10.066 (3)0.0373 (19)0.056 (2)0.0014 (17)0.007 (2)0.0098 (17)
O20.051 (2)0.040 (2)0.0390 (18)0.0048 (17)0.0110 (18)0.0013 (15)
O30.113 (4)0.061 (3)0.059 (2)0.008 (3)0.041 (3)0.018 (2)
O40.063 (3)0.0377 (19)0.054 (2)0.0001 (18)0.0046 (19)0.0051 (16)
O50.049 (2)0.0346 (19)0.0438 (18)0.0014 (16)0.0115 (18)0.0026 (15)
O60.082 (3)0.051 (2)0.058 (2)0.002 (2)0.028 (2)0.0091 (19)
C10.058 (4)0.040 (3)0.054 (3)0.000 (3)0.014 (3)0.003 (3)
C20.049 (3)0.036 (3)0.049 (3)0.004 (3)0.002 (3)0.009 (2)
C30.051 (4)0.056 (4)0.077 (4)0.010 (3)0.007 (3)0.020 (3)
C40.052 (4)0.085 (5)0.066 (4)0.003 (3)0.019 (3)0.033 (4)
C50.072 (4)0.077 (5)0.040 (3)0.018 (3)0.018 (3)0.009 (3)
C60.060 (4)0.051 (3)0.037 (3)0.002 (3)0.009 (3)0.004 (2)
C70.040 (3)0.044 (3)0.033 (2)0.004 (3)0.003 (2)0.003 (2)
C80.194 (9)0.087 (5)0.084 (5)0.020 (6)0.063 (6)0.034 (4)
C90.096 (6)0.084 (5)0.142 (7)0.024 (5)0.038 (6)0.021 (5)
C100.080 (5)0.181 (9)0.071 (4)0.036 (6)0.036 (4)0.031 (5)
C110.047 (4)0.151 (7)0.108 (5)0.003 (5)0.005 (4)0.037 (6)
C120.109 (6)0.140 (7)0.055 (4)0.017 (6)0.000 (4)0.024 (4)
C130.132 (7)0.066 (5)0.119 (6)0.003 (4)0.067 (6)0.025 (4)
C140.063 (4)0.068 (4)0.074 (4)0.014 (3)0.016 (3)0.011 (3)
C150.081 (5)0.067 (4)0.047 (3)0.020 (3)0.015 (3)0.014 (3)
C160.058 (4)0.059 (3)0.050 (3)0.006 (3)0.008 (3)0.002 (3)
C170.065 (4)0.033 (3)0.063 (4)0.001 (3)0.006 (3)0.000 (3)
C180.045 (3)0.038 (3)0.052 (3)0.004 (3)0.003 (3)0.009 (2)
C190.071 (5)0.052 (4)0.074 (4)0.018 (3)0.004 (4)0.015 (3)
C200.074 (5)0.084 (5)0.065 (4)0.014 (4)0.019 (4)0.020 (4)
C210.058 (4)0.085 (5)0.042 (3)0.002 (3)0.010 (3)0.009 (3)
C220.057 (4)0.056 (3)0.034 (3)0.003 (3)0.004 (3)0.000 (2)
C230.041 (3)0.043 (3)0.037 (3)0.001 (2)0.002 (2)0.003 (2)
C240.106 (6)0.082 (5)0.067 (4)0.013 (4)0.032 (4)0.022 (4)
C250.135 (8)0.070 (5)0.123 (6)0.003 (5)0.072 (6)0.022 (4)
C260.069 (4)0.077 (4)0.073 (4)0.007 (4)0.010 (4)0.010 (3)
C270.123 (7)0.143 (7)0.050 (4)0.002 (6)0.004 (4)0.028 (4)
C280.115 (7)0.071 (5)0.169 (8)0.015 (5)0.033 (6)0.027 (5)
C290.100 (6)0.182 (9)0.069 (4)0.028 (6)0.027 (4)0.040 (5)
C300.062 (4)0.151 (8)0.126 (6)0.009 (5)0.004 (5)0.026 (6)
C310.082 (5)0.074 (4)0.057 (3)0.011 (4)0.015 (3)0.015 (3)
C320.069 (4)0.049 (3)0.061 (3)0.008 (3)0.015 (3)0.005 (3)
Geometric parameters (Å, º) top
Co1—C161.988 (5)C11—H11C0.9600
Co1—C151.999 (5)C12—H12A0.9600
Co1—O12.005 (4)C12—H12B0.9600
Co1—O22.013 (3)C12—H12C0.9600
Co1—P12.2104 (15)C13—H13A0.9600
Co1—P22.2208 (16)C13—H13B0.9600
Co2—C321.992 (5)C13—H13C0.9600
Co2—C311.996 (5)C14—H14A0.9600
Co2—O42.000 (4)C14—H14B0.9600
Co2—O52.016 (3)C14—H14C0.9600
Co2—P42.2151 (17)C15—H15A0.9600
Co2—P32.2208 (16)C15—H15B0.9600
P1—C111.799 (6)C15—H15C0.9600
P1—C101.808 (6)C16—H16A0.9600
P1—C91.821 (7)C16—H16B0.9600
P2—C141.816 (6)C16—H16C0.9600
P2—C131.817 (7)C17—C181.414 (7)
P2—C121.825 (6)C17—H170.9300
P3—C261.813 (6)C18—C191.430 (8)
P3—C271.822 (6)C18—C231.435 (7)
P3—C251.825 (7)C19—C201.344 (8)
P4—C301.804 (6)C19—H190.9300
P4—C281.811 (7)C20—C211.403 (8)
P4—C291.811 (6)C20—H200.9300
O1—C11.239 (6)C21—C221.367 (7)
O2—C71.273 (5)C21—H210.9300
O3—C61.365 (6)C22—C231.451 (7)
O3—C81.418 (7)C24—H24A0.9600
O4—C171.232 (6)C24—H24B0.9600
O5—C231.276 (5)C24—H24C0.9600
O6—C221.365 (6)C25—H25A0.9600
O6—C241.412 (6)C25—H25B0.9600
C1—C21.421 (7)C25—H25C0.9600
C1—H10.9300C26—H26A0.9600
C2—C31.414 (7)C26—H26B0.9600
C2—C71.433 (7)C26—H26C0.9600
C3—C41.341 (8)C27—H27A0.9600
C3—H30.9300C27—H27B0.9600
C4—C51.404 (8)C27—H27C0.9600
C4—H40.9300C28—H28A0.9600
C5—C61.355 (7)C28—H28B0.9600
C5—H50.9300C28—H28C0.9600
C6—C71.447 (7)C29—H29A0.9600
C8—H8A0.9600C29—H29B0.9600
C8—H8B0.9600C29—H29C0.9600
C8—H8C0.9600C30—H30A0.9600
C9—H9A0.9600C30—H30B0.9600
C9—H9B0.9600C30—H30C0.9600
C9—H9C0.9600C31—H31A0.9600
C10—H10A0.9600C31—H31B0.9600
C10—H10B0.9600C31—H31C0.9600
C10—H10C0.9600C32—H32A0.9600
C11—H11A0.9600C32—H32B0.9600
C11—H11B0.9600C32—H32C0.9600
C16—Co1—C1594.0 (2)P2—C12—H12A109.5
C16—Co1—O1178.26 (18)P2—C12—H12B109.5
C15—Co1—O187.6 (2)H12A—C12—H12B109.5
C16—Co1—O288.14 (17)P2—C12—H12C109.5
C15—Co1—O2177.7 (2)H12A—C12—H12C109.5
O1—Co1—O290.22 (14)H12B—C12—H12C109.5
C16—Co1—P188.34 (16)P2—C13—H13A109.5
C15—Co1—P187.93 (18)P2—C13—H13B109.5
O1—Co1—P191.12 (12)H13A—C13—H13B109.5
O2—Co1—P191.36 (11)P2—C13—H13C109.5
C16—Co1—P288.85 (16)H13A—C13—H13C109.5
C15—Co1—P288.53 (18)H13B—C13—H13C109.5
O1—Co1—P291.80 (12)P2—C14—H14A109.5
O2—Co1—P292.29 (10)P2—C14—H14B109.5
P1—Co1—P2175.32 (6)H14A—C14—H14B109.5
C32—Co2—C3193.3 (2)P2—C14—H14C109.5
C32—Co2—O4178.68 (19)H14A—C14—H14C109.5
C31—Co2—O488.1 (2)H14B—C14—H14C109.5
C32—Co2—O588.57 (18)Co1—C15—H15A109.5
C31—Co2—O5178.0 (2)Co1—C15—H15B109.5
O4—Co2—O590.10 (13)H15A—C15—H15B109.5
C32—Co2—P488.58 (18)Co1—C15—H15C109.5
C31—Co2—P487.83 (19)H15A—C15—H15C109.5
O4—Co2—P491.47 (11)H15B—C15—H15C109.5
O5—Co2—P491.34 (10)Co1—C16—H16A109.5
C32—Co2—P389.42 (17)Co1—C16—H16B109.5
C31—Co2—P388.28 (19)H16A—C16—H16B109.5
O4—Co2—P390.62 (11)Co1—C16—H16C109.5
O5—Co2—P392.62 (10)H16A—C16—H16C109.5
P4—Co2—P3175.52 (6)H16B—C16—H16C109.5
C11—P1—C10102.4 (4)O4—C17—C18128.4 (5)
C11—P1—C9101.4 (4)O4—C17—H17115.8
C10—P1—C9103.0 (4)C18—C17—H17115.8
C11—P1—Co1118.0 (2)C17—C18—C19117.3 (5)
C10—P1—Co1114.5 (2)C17—C18—C23122.4 (5)
C9—P1—Co1115.4 (2)C19—C18—C23120.3 (5)
C14—P2—C13102.3 (3)C20—C19—C18121.5 (5)
C14—P2—C12102.3 (3)C20—C19—H19119.2
C13—P2—C12101.5 (4)C18—C19—H19119.2
C14—P2—Co1115.12 (19)C19—C20—C21119.9 (6)
C13—P2—Co1115.3 (2)C19—C20—H20120.0
C12—P2—Co1118.1 (3)C21—C20—H20120.0
C26—P3—C27102.8 (4)C22—C21—C20120.9 (6)
C26—P3—C25101.9 (3)C22—C21—H21119.5
C27—P3—C25101.1 (4)C20—C21—H21119.5
C26—P3—Co2115.7 (2)O6—C22—C21124.6 (5)
C27—P3—Co2117.7 (3)O6—C22—C23113.3 (4)
C25—P3—Co2115.3 (2)C21—C22—C23122.0 (5)
C30—P4—C28101.5 (4)O5—C23—C18125.1 (4)
C30—P4—C29101.8 (4)O5—C23—C22119.7 (4)
C28—P4—C29102.9 (4)C18—C23—C22115.2 (5)
C30—P4—Co2118.4 (3)O6—C24—H24A109.5
C28—P4—Co2115.0 (3)O6—C24—H24B109.5
C29—P4—Co2115.0 (2)H24A—C24—H24B109.5
C1—O1—Co1126.3 (3)O6—C24—H24C109.5
C7—O2—Co1127.3 (3)H24A—C24—H24C109.5
C6—O3—C8117.3 (5)H24B—C24—H24C109.5
C17—O4—Co2126.9 (3)P3—C25—H25A109.5
C23—O5—Co2127.1 (3)P3—C25—H25B109.5
C22—O6—C24117.7 (4)H25A—C25—H25B109.5
O1—C1—C2128.7 (5)P3—C25—H25C109.5
O1—C1—H1115.7H25A—C25—H25C109.5
C2—C1—H1115.7H25B—C25—H25C109.5
C3—C2—C1118.1 (5)P3—C26—H26A109.5
C3—C2—C7120.0 (5)P3—C26—H26B109.5
C1—C2—C7121.9 (5)H26A—C26—H26B109.5
C4—C3—C2122.5 (6)P3—C26—H26C109.5
C4—C3—H3118.8H26A—C26—H26C109.5
C2—C3—H3118.8H26B—C26—H26C109.5
C3—C4—C5118.9 (5)P3—C27—H27A109.5
C3—C4—H4120.5P3—C27—H27B109.5
C5—C4—H4120.5H27A—C27—H27B109.5
C6—C5—C4121.3 (5)P3—C27—H27C109.5
C6—C5—H5119.3H27A—C27—H27C109.5
C4—C5—H5119.3H27B—C27—H27C109.5
C5—C6—O3125.1 (5)P4—C28—H28A109.5
C5—C6—C7122.0 (5)P4—C28—H28B109.5
O3—C6—C7112.8 (4)H28A—C28—H28B109.5
O2—C7—C2125.5 (4)P4—C28—H28C109.5
O2—C7—C6119.3 (5)H28A—C28—H28C109.5
C2—C7—C6115.2 (5)H28B—C28—H28C109.5
O3—C8—H8A109.5P4—C29—H29A109.5
O3—C8—H8B109.5P4—C29—H29B109.5
H8A—C8—H8B109.5H29A—C29—H29B109.5
O3—C8—H8C109.5P4—C29—H29C109.5
H8A—C8—H8C109.5H29A—C29—H29C109.5
H8B—C8—H8C109.5H29B—C29—H29C109.5
P1—C9—H9A109.5P4—C30—H30A109.5
P1—C9—H9B109.5P4—C30—H30B109.5
H9A—C9—H9B109.5H30A—C30—H30B109.5
P1—C9—H9C109.5P4—C30—H30C109.5
H9A—C9—H9C109.5H30A—C30—H30C109.5
H9B—C9—H9C109.5H30B—C30—H30C109.5
P1—C10—H10A109.5Co2—C31—H31A109.5
P1—C10—H10B109.5Co2—C31—H31B109.5
H10A—C10—H10B109.5H31A—C31—H31B109.5
P1—C10—H10C109.5Co2—C31—H31C109.5
H10A—C10—H10C109.5H31A—C31—H31C109.5
H10B—C10—H10C109.5H31B—C31—H31C109.5
P1—C11—H11A109.5Co2—C32—H32A109.5
P1—C11—H11B109.5Co2—C32—H32B109.5
H11A—C11—H11B109.5H32A—C32—H32B109.5
P1—C11—H11C109.5Co2—C32—H32C109.5
H11A—C11—H11C109.5H32A—C32—H32C109.5
H11B—C11—H11C109.5H32B—C32—H32C109.5
C16—Co1—P1—C1143.3 (4)O1—Co1—O2—C72.4 (4)
C15—Co1—P1—C1150.7 (4)P1—Co1—O2—C793.5 (4)
O1—Co1—P1—C11138.3 (3)P2—Co1—O2—C789.5 (4)
O2—Co1—P1—C11131.4 (3)C31—Co2—O4—C17179.1 (5)
C16—Co1—P1—C1077.3 (3)O5—Co2—O4—C170.1 (4)
C15—Co1—P1—C10171.4 (4)P4—Co2—O4—C1791.3 (4)
O1—Co1—P1—C10101.0 (3)P3—Co2—O4—C1792.7 (4)
O2—Co1—P1—C1010.8 (3)C32—Co2—O5—C23179.8 (4)
C16—Co1—P1—C9163.4 (3)O4—Co2—O5—C230.2 (4)
C15—Co1—P1—C969.4 (4)P4—Co2—O5—C2391.2 (4)
O1—Co1—P1—C918.2 (3)P3—Co2—O5—C2390.9 (4)
O2—Co1—P1—C9108.5 (3)Co1—O1—C1—C20.7 (8)
C16—Co1—P2—C1473.5 (3)O1—C1—C2—C3177.2 (5)
C15—Co1—P2—C14167.5 (3)O1—C1—C2—C73.8 (8)
O1—Co1—P2—C14104.9 (3)C1—C2—C3—C4178.4 (5)
O2—Co1—P2—C1414.6 (3)C7—C2—C3—C40.7 (8)
C16—Co1—P2—C13167.7 (4)C2—C3—C4—C51.2 (9)
C15—Co1—P2—C1373.7 (4)C3—C4—C5—C61.5 (9)
O1—Co1—P2—C1313.9 (3)C4—C5—C6—O3179.0 (6)
O2—Co1—P2—C13104.2 (3)C4—C5—C6—C70.2 (8)
C16—Co1—P2—C1247.6 (3)C8—O3—C6—C57.1 (9)
C15—Co1—P2—C1246.4 (4)C8—O3—C6—C7172.1 (6)
O1—Co1—P2—C12134.0 (3)Co1—O2—C7—C20.3 (7)
O2—Co1—P2—C12135.7 (3)Co1—O2—C7—C6179.6 (3)
C32—Co2—P3—C2677.3 (3)C3—C2—C7—O2177.8 (5)
C31—Co2—P3—C26170.6 (3)C1—C2—C7—O23.2 (8)
O4—Co2—P3—C26101.4 (3)C3—C2—C7—C62.1 (7)
O5—Co2—P3—C2611.2 (3)C1—C2—C7—C6176.9 (4)
C32—Co2—P3—C2744.7 (4)C5—C6—C7—O2178.1 (5)
C31—Co2—P3—C2748.6 (4)O3—C6—C7—O22.7 (7)
O4—Co2—P3—C27136.6 (3)C5—C6—C7—C21.9 (7)
O5—Co2—P3—C27133.3 (3)O3—C6—C7—C2177.3 (4)
C32—Co2—P3—C25164.0 (4)Co2—O4—C17—C181.0 (8)
C31—Co2—P3—C2570.7 (4)O4—C17—C18—C19179.2 (5)
O4—Co2—P3—C2517.4 (4)O4—C17—C18—C232.0 (9)
O5—Co2—P3—C25107.5 (3)C17—C18—C19—C20177.8 (6)
C32—Co2—P4—C3040.7 (4)C23—C18—C19—C201.0 (9)
C31—Co2—P4—C3052.6 (4)C18—C19—C20—C210.1 (10)
O4—Co2—P4—C30140.6 (4)C19—C20—C21—C220.3 (10)
O5—Co2—P4—C30129.2 (3)C24—O6—C22—C211.4 (8)
C32—Co2—P4—C28160.9 (4)C24—O6—C22—C23179.2 (5)
C31—Co2—P4—C2867.5 (4)C20—C21—C22—O6179.2 (6)
O4—Co2—P4—C2820.5 (4)C20—C21—C22—C231.4 (8)
O5—Co2—P4—C28110.6 (3)Co2—O5—C23—C181.3 (7)
C32—Co2—P4—C2979.8 (4)Co2—O5—C23—C22177.6 (3)
C31—Co2—P4—C29173.2 (4)C17—C18—C23—O52.1 (8)
O4—Co2—P4—C2998.8 (3)C19—C18—C23—O5179.2 (5)
O5—Co2—P4—C298.7 (3)C17—C18—C23—C22176.8 (5)
C15—Co1—O1—C1178.9 (4)C19—C18—C23—C221.9 (7)
O2—Co1—O1—C11.9 (4)O6—C22—C23—O50.6 (7)
P1—Co1—O1—C193.2 (4)C21—C22—C23—O5178.8 (5)
P2—Co1—O1—C190.4 (4)O6—C22—C23—C18178.4 (4)
C16—Co1—O2—C7178.2 (4)C21—C22—C23—C182.1 (7)
 

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