Acta Cryst. (2006). E62, m3351-m3353  [ doi:10.1107/S1600536806047477 ]

[1,4,12,15,18,26,31,39,42,43,44-Undecaazapentacyclo[13.13.13.1^6,10.1^20,24.1^33,37]tetratetraconta-4,6,8,10(44),11,18,20,22,24(43),25,31,33,35,37(42),38-pentadecaene-⁹N⁴,N¹¹,N¹⁸,N²⁶,N³¹,N³⁹,N⁴²,N⁴³,N⁴⁴]gadolinium(III) trichloride trihydrate

X.-L. Hu, L. Qiu, W.-B. Sun and S. W. Ng

Abstract: The Gd atom in the title compound, [Gd(C₃₃H₃₉N₁₁)]Cl₃·3H₂O, lies on a position of 32 point symmetry and exhibits a tricapped trigonal prismatic coordination geometry. A twofold rotation axis passes through the coordinated N atom and the opposite C atom of the pyridyl ring of the ligand, while a threefold rotation axis passes through the aliphatic N atom. The Cl atom and O atom of the uncoordinated water molecule both lie on twofold rotation axes.

Online 17 November 2006

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