Acta Cryst. (2006). E62, m3437-m3438  [ doi:10.1107/S1600536806048525 ]

Bis[-8-(pyrimidin-2-ylsulfanylmethyl)quinoline-²N,S]bis[(acetonitrile)silver(I)] bis(trifluoromethanesulfonate)

R.-F. Song, Y.-H. Wang and J.-R. Li

Abstract: In the twofold-symmetric dinuclear title compound, [Ag₂(C₁₄H₁₁N₃S)₂(CH₃CN)₂](CF₃SO₃)₂, each Ag^I atom is coordinated by one N atom and one S atom from one 8-(pyrimidin-2-ylsulfanylmethyl)quinoline ligand, one N atom from a second 8-(pyrimidin-2-ylsulfanylmethyl)quinoline ligand, and one N atom of CH₃CN, in a distorted trigonal pyramidal geometry. The cis bond angles around the Ag^I atom range from 90.8 (2) to 143.48 (11)°.

Online 24 November 2006

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