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Acta Cryst. (2006). E62, m3220-m3221  [ doi:10.1107/S1600536806038451 ]

Nonacarbonyl([mu]2-methanethiolato)([mu]3-trimethylsilylacetylene)triruthenium

O. F. Koentjoro, H. A. Sparkes and P. R. Raithby

Abstract: The structure of the title compound, [Ru3([mu]2CH3S){[mu]3-C2Si(CH3)3}(CO)9], contains an open triangle of Ru atoms. The open edge is bridged on one side by a [mu]2-S(CH3) unit, and the other side of the triangle is capped by a [C[triple bond]CSi(CH3)3] group, with the acetylenic bond perpendicular to the open Ru...Ru edge.

Online 8 November 2006


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