Acta Cryst. (2006). E62, m3404-m3406  [ doi:10.1107/S1600536806047660 ]

trans-Bis[(E)-acetone O-propanimidoyloxime-N']tetrachloroplatinum(IV)

A. V. Khripun, M. Haukka and V. Yu. Kukushkin

Abstract: The title complex, [PtCl₄(C₁₂H₂₄N₄O₂)] or trans-[PtCl₄{NH= C(Et)ON=CMe₂}₂], possesses a crystallographically imposed centre of symmetry. The coordination polyhedron of the complex is a slightly distorted octahedron. The two imino ligands are mutually trans. This configuration is stabilized by intramolecular N-HN hydrogen bonding between the imine H atom and the oxime N atom.

Online 22 November 2006

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