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Acta Cryst. (2006). E62, m3242-m3244  [ doi:10.1107/S1600536806045715 ]

Poly[[aquasamarium(III)]-[mu]4-citrato-[kappa]4O:O':O'':O''']

T.-M. Shang and J.-H. Sun

Abstract: The title compound, [Sm(C6H5O7)(H2O)]n, was synthesized hydrothermally. Each SmIII atom is coordinated by eight O atoms from four citrate trianions and one aqua O atom. Each citrate trianion functions as a [mu]4-bridging ligand, forming a layer structure. Neighbouring layers are held together by O-H...O hydrogen-bonding interactions, which generate a three-dimensional framework.

Online 8 November 2006


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