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Acta Cryst. (2006). E62, m3439-m3441 [ doi:10.1107/S1600536806048343 ]
![[mu]](/logos/entities/mu_rmgif.gif)
3-Oxo-hexa-2-pivalato-(pivalic acid-![[kappa]](/logos/entities/kappa_rmgif.gif)
O)bis(pyridine-N)trimanganese(III,III,II)Abstract: The asymmetric unit of the title compound, [Mn3(C5H9O2)6O(C5H5N)2(C5H10O2)], comprises two independent and similar [MnIII2MnIIO{(CH3)3CCO2}6(py)2(CH3)3CCOOH] (py = pyridine) molecules each with an Mn3(3-O) core. In each molecule, the Mn atoms have octahedral geometry with two coordinated pyridines bonded to two MnIII and a terminal pivalic acid coordinated to the MnII atom.
Online 24 November 2006
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