Acta Cryst. (2006). E62, m3165-m3166  [ doi:10.1107/S1600536806044710 ]

Diaquaazido(3,5-diaminobenzoato-N)(1,10-phenanthroline-²N,N')zinc(II) monohydrate

M.-X. Li, H.-J. Zhao, M. Shao, Z.-X. Miao and S.-R. Zhou

Abstract: The reaction of 3,5-diaminobenzoic acid, 1,10-phenanthroline, NaN₃ and Zn^II in basic aqueous solution gave rise to the title compound, [Zn(C₇H₇N₂O₂)(N₃)(C₁₂H₈N₂)(H₂O)₂]·H₂O. The Zn^II atom is six-coordinate with a distorted octahedral geometry. The two aqua ligands are in cis positions and the 3,5-diaminobenzoate ligand binds to the central Zn atom through one of its amino groups.

Online 3 November 2006

Copyright © International Union of Crystallography
IUCr Webmaster