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Acta Cryst. (2006). E62, m3541-m3543  [ doi:10.1107/S1600536806049592 ]

catena-Poly[[[2-(2-furyl)-1H-imidazo[4,5-f][1,10]phenanthroline]zinc(II)]-[mu]-benzene-1,2-dicarboxylato]

C.-B. Li, Y.-W. Li, W. Fang, B. Liu and D.-Q. Li

Abstract: In the title compound, [Zn(C8H4O4)(C17H10N4O)]n, the ZnII atom is five-coordinated by two N atoms from the phenanthroline-derived ligand and three O atoms from one bidentate and one monodentate benzene-1,2-dicarboxylate (1,2-BDC) dianions in a distorted trigonal-bipyramidal geometry. The ZnII atoms are bridged by the 1,2-BDC ligands to form a single-chain structure. Neighboring chains interact through [pi]-[pi] interactions, leading to a two-dimensional network.

Online 30 November 2006


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