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Acta Cryst. (2006). E62, m3338-m3340  [ doi:10.1107/S160053680604726X ]

(2-Benzoylbenzoato-[kappa]O)triphenyl(triphenylphosphine oxide-[kappa]O)tin(IV)

C. A. K. Diop, A. Touré, L. Diop and R. Welter

Abstract: The structure of the title compound, [Sn(C6H5)3(C14H9O3)(C18H15OP)], consists of discrete molecules, in which the monodentate C6H5COC6H4COO- anion and OPPh3 are coordinated to an SnPh3 group, and the tin center is in a trigonal-bipyramidal environment. The axial and equatorial positions of the trigonal bipyramid are occupied by the two O atoms of OPPh3 and RCOO- and three ipso C atoms of the three phenyl rings, respectively.

Online 17 November 2006


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