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Acta Cryst. (2006). E62, m3578-m3579 [ doi:10.1107/S1600536806049415 ]
2O,O')diaquacopper(II)Abstract: A new monomeric copper acetate complex, [Cu(C2H3O2)2(H2O)2], was obtained unexpectedly by the reaction of Cu2(CO3)2(OH)2·xH2O, acetonitrile, ammonia and water under hydrothermal conditions. The structure contains a discrete centrosymmetric diacetatodiaquacopper(II) complex and the CuII atom is coordinated by four O atoms from two acetate anions and two water molecules, giving a distorted octahedral geometry.
Online 30 November 2006
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