Acta Cryst. (2006). E62, m3191-m3193  [ doi:10.1107/S1600536806043601 ]

Di--iodo-bis[pyridine(tri-p-tolylphosphine)silver(I)]

R. Meijboom and A. Muller

Abstract: The title compound, [Ag₂I₂(C₅H₅N)₂(C₂₁H₂₁P)₂], has C_i molecular symmetry. Each Ag atom is surrounded by a phosphine ligand, a pyridine ligand and two iodide anions in a distorted tetrahedral coordination. The AgAg separation in the binuclear species is 3.1130 (18) Å. The Ag-P distance is 2.4489 (12) Å, the Ag-N distance is 2.392 (3) Å, and the Ag-I distances are 2.8402 (14) and 2.8644 (8) Å.

Online 3 November 2006

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