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In the title compound, [Ru(C18H21O3)Cl(C10H14)], the RuII atom displays tetra­hedral coordination, being linked to the two O atoms of the camphor-derived ligand and the p-cymene and Cl ligands.

Supporting information

cif

Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536806044655/ng2131sup1.cif
Contains datablocks global, I

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S1600536806044655/ng2131Isup2.hkl
Contains datablock I

CCDC reference: 630178

Key indicators

  • Single-crystal X-ray study
  • T = 293 K
  • Mean [sigma](C-C) = 0.007 Å
  • R factor = 0.036
  • wR factor = 0.088
  • Data-to-parameter ratio = 14.9

checkCIF/PLATON results

No syntax errors found



Alert level B PLAT027_ALERT_3_B _diffrn_reflns_theta_full (too) Low ............ 24.99 Deg.
Alert level C PLAT094_ALERT_2_C Ratio of Maximum / Minimum Residual Density .... 2.75 PLAT220_ALERT_2_C Large Non-Solvent C Ueq(max)/Ueq(min) ... 2.80 Ratio PLAT222_ALERT_3_C Large Non-Solvent H Ueq(max)/Ueq(min) ... 3.09 Ratio
Alert level G REFLT03_ALERT_4_G Please check that the estimate of the number of Friedel pairs is correct. If it is not, please give the correct count in the _publ_section_exptl_refinement section of the submitted CIF. From the CIF: _diffrn_reflns_theta_max 24.99 From the CIF: _reflns_number_total 4540 Count of symmetry unique reflns 2614 Completeness (_total/calc) 173.68% TEST3: Check Friedels for noncentro structure Estimate of Friedel pairs measured 1926 Fraction of Friedel pairs measured 0.737 Are heavy atom types Z>Si present yes PLAT199_ALERT_1_G Check the Reported _cell_measurement_temperature 293 K PLAT200_ALERT_1_G Check the Reported _diffrn_ambient_temperature . 293 K PLAT791_ALERT_1_G Confirm the Absolute Configuration of C12 = . R PLAT791_ALERT_1_G Confirm the Absolute Configuration of C16 = . S
0 ALERT level A = In general: serious problem 1 ALERT level B = Potentially serious problem 3 ALERT level C = Check and explain 5 ALERT level G = General alerts; check 4 ALERT type 1 CIF construction/syntax error, inconsistent or missing data 2 ALERT type 2 Indicator that the structure model may be wrong or deficient 2 ALERT type 3 Indicator that the structure quality may be low 1 ALERT type 4 Improvement, methodology, query or suggestion 0 ALERT type 5 Informative message, check

Computing details top

Data collection: SMART (Bruker, 1998); cell refinement: SAINT-Plus (Bruker, 1998); data reduction: SAINT-Plus; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997a); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997a); molecular graphics: DIAMOND (Brandenburg, 2001); software used to prepare material for publication: SHELXL97.

Chloro(η6-p-cymene)[(1R)-(+)-3-(4-methoxybenzoyl)camphor(1-)- κ2O,O']ruthenium(II) top
Crystal data top
[Ru(C18H21O3)Cl(C10H14)]F(000) = 1152
Mr = 556.08Dx = 1.423 Mg m3
Orthorhombic, P212121Mo Kα radiation, λ = 0.71073 Å
Hall symbol: P 2ac 2abCell parameters from 2706 reflections
a = 8.2635 (11) Åθ = 3.2–19.8°
b = 12.5518 (16) ŵ = 0.73 mm1
c = 25.020 (3) ÅT = 293 K
V = 2595.1 (6) Å3Crystal face indices and distances (mm) from refrence point
0 0 1 0.075 0 0 -1 0.075
0 1 0 0.150 0 -1 0 0.170
1 0 0 0.060 -1 0 0 0.060
-1 0 2 0.075 1 0 -2 0.080
-1 2 1 0.113 0 2 1 0.130, orange
Z = 40.32 × 0.15 × 0.12 mm
Data collection top
Bruker SMART 1K CCD
diffractometer
4540 independent reflections
Radiation source: fine-focus sealed tube3969 reflections with I > 2σ(I)
Graphite monochromatorRint = 0.051
ω scansθmax = 25.0°, θmin = 2.9°
Absorption correction: gaussian
(XPREP in SHELXTL; Sheldrick, 1997b)
h = 99
Tmin = 0.889, Tmax = 0.925k = 1414
17420 measured reflectionsl = 2929
Refinement top
Refinement on F2Secondary atom site location: difference Fourier map
Least-squares matrix: fullHydrogen site location: inferred from neighbouring sites
R[F2 > 2σ(F2)] = 0.036H-atom parameters constrained
wR(F2) = 0.088 w = 1/[σ2(Fo2) + (0.052P)2]
where P = (Fo2 + 2Fc2)/3
S = 1.02(Δ/σ)max < 0.001
4540 reflectionsΔρmax = 0.98 e Å3
305 parametersΔρmin = 0.36 e Å3
0 restraintsAbsolute structure: Flack (1983), 1941 Friedel pairs
Primary atom site location: structure-invariant direct methodsAbsolute structure parameter: 0.07 (4)
Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. The Hydrogen atoms have been constrained to their ideal positions.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
Ru10.13342 (4)0.92366 (2)0.046650 (13)0.03102 (11)
Cl20.42440 (13)0.92394 (11)0.05058 (5)0.0503 (3)
O20.1547 (4)0.9672 (2)0.12646 (10)0.0362 (7)
O10.1514 (4)0.7661 (2)0.06983 (10)0.0404 (7)
O30.2351 (5)0.2806 (3)0.09284 (16)0.0588 (10)
C10.1650 (7)0.8336 (4)0.07919 (19)0.0594 (15)
H1A0.12180.76310.07530.089*
H1B0.27960.83220.07300.089*
H1C0.14420.85900.11470.089*
C20.0861 (6)0.9064 (4)0.03959 (17)0.0430 (11)
C30.1466 (7)1.0088 (3)0.02750 (16)0.0424 (11)
H30.23791.03240.04570.051*
C40.0768 (5)1.0766 (4)0.01043 (17)0.0394 (10)
H40.11931.14430.01620.047*
C50.0604 (5)1.0410 (3)0.04015 (19)0.0361 (10)
C60.1262 (6)0.9384 (3)0.02914 (18)0.0411 (10)
H60.21780.91500.04720.049*
C70.0510 (6)0.8721 (4)0.00968 (19)0.0425 (11)
H70.09270.80430.01570.051*
C80.1260 (7)1.1132 (3)0.08327 (17)0.0420 (10)
H80.03341.14450.10200.050*
C90.2302 (7)1.0581 (4)0.1245 (2)0.0594 (15)
H9A0.17051.00060.14030.089*
H9B0.32581.03060.10760.089*
H9C0.26041.10820.15170.089*
C100.2181 (7)1.2047 (4)0.0554 (2)0.0617 (15)
H10A0.15181.23420.02760.093*
H10B0.24301.25910.08110.093*
H10C0.31661.17770.04030.093*
C110.1816 (5)0.8997 (4)0.16299 (17)0.0393 (11)
C120.2036 (7)0.9352 (4)0.22098 (18)0.0531 (13)
C130.1466 (10)1.0461 (3)0.2337 (2)0.0697 (17)
H13A0.20661.09650.21270.105*
H13B0.16321.06040.27100.105*
H13C0.03351.05210.22540.105*
C140.3846 (8)0.9129 (4)0.2320 (2)0.0726 (17)
H14A0.41800.94420.26570.087*
H14B0.45180.94120.20360.087*
C150.3959 (8)0.7888 (4)0.2342 (2)0.0667 (17)
H15A0.47300.76170.20830.080*
H15B0.42570.76410.26960.080*
C160.2219 (7)0.7562 (4)0.21983 (18)0.0542 (14)
H160.19450.68200.22780.065*
C170.1977 (6)0.7890 (3)0.16180 (16)0.0365 (10)
C180.1187 (9)0.8400 (4)0.24953 (18)0.0589 (15)
C190.1407 (12)0.8413 (5)0.31097 (19)0.096 (3)
H19A0.08600.78110.32630.145*
H19B0.09590.90580.32530.145*
H19C0.25390.83770.31950.145*
C200.0622 (8)0.8327 (5)0.2369 (3)0.081 (2)
H20A0.07700.82700.19890.122*
H20B0.11590.89560.24970.122*
H20C0.10710.77110.25410.122*
C210.1822 (5)0.7276 (3)0.11597 (16)0.0348 (10)
C220.1950 (5)0.6084 (3)0.11518 (16)0.0342 (10)
C230.3005 (6)0.5504 (3)0.14719 (19)0.0419 (11)
H230.36000.58540.17340.050*
C240.3188 (6)0.4410 (3)0.14077 (19)0.0434 (12)
H240.39140.40370.16220.052*
C250.2296 (6)0.3879 (4)0.1028 (2)0.0422 (11)
C260.1232 (7)0.4442 (3)0.07113 (18)0.0463 (11)
H260.06070.40870.04580.056*
C270.1092 (6)0.5536 (3)0.07696 (18)0.0412 (11)
H270.04000.59100.05440.049*
C280.3526 (8)0.2206 (4)0.1206 (2)0.0707 (16)
H28A0.34350.14690.11060.106*
H28B0.33550.22770.15840.106*
H28C0.45860.24620.11160.106*
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Ru10.03466 (17)0.02751 (16)0.03087 (17)0.00190 (16)0.00210 (16)0.00134 (15)
Cl20.0341 (5)0.0658 (7)0.0510 (7)0.0012 (5)0.0007 (5)0.0003 (8)
O20.051 (2)0.0296 (14)0.0283 (15)0.0027 (15)0.0018 (15)0.0003 (11)
O10.059 (2)0.0301 (15)0.0324 (15)0.0017 (17)0.0046 (16)0.0007 (12)
O30.069 (2)0.0280 (18)0.079 (3)0.0072 (17)0.014 (2)0.0016 (17)
C10.069 (4)0.067 (4)0.042 (3)0.011 (3)0.004 (3)0.011 (2)
C20.054 (3)0.039 (3)0.036 (2)0.004 (2)0.006 (2)0.000 (2)
C30.053 (3)0.041 (3)0.033 (2)0.002 (3)0.006 (2)0.0093 (19)
C40.050 (3)0.027 (2)0.041 (2)0.001 (2)0.0059 (19)0.003 (2)
C50.034 (2)0.032 (2)0.043 (3)0.0047 (18)0.010 (2)0.0039 (19)
C60.033 (2)0.038 (2)0.053 (3)0.005 (2)0.020 (2)0.0030 (19)
C70.041 (3)0.039 (3)0.047 (3)0.003 (2)0.010 (2)0.005 (2)
C80.042 (3)0.037 (2)0.047 (3)0.004 (2)0.008 (2)0.0023 (19)
C90.054 (3)0.054 (4)0.070 (4)0.001 (3)0.008 (3)0.018 (3)
C100.072 (4)0.051 (3)0.062 (4)0.023 (3)0.005 (3)0.005 (3)
C110.040 (3)0.044 (3)0.034 (2)0.001 (2)0.0039 (19)0.001 (2)
C120.079 (4)0.046 (3)0.035 (3)0.001 (3)0.005 (2)0.003 (2)
C130.126 (5)0.042 (3)0.042 (3)0.006 (3)0.011 (4)0.009 (2)
C140.094 (4)0.068 (4)0.056 (3)0.001 (4)0.039 (3)0.011 (3)
C150.091 (5)0.061 (3)0.048 (3)0.017 (3)0.024 (3)0.006 (3)
C160.086 (4)0.045 (3)0.031 (3)0.011 (3)0.001 (3)0.005 (2)
C170.046 (3)0.032 (2)0.031 (2)0.001 (2)0.004 (2)0.0060 (19)
C180.098 (4)0.047 (3)0.032 (2)0.020 (3)0.010 (3)0.005 (2)
C190.191 (8)0.068 (4)0.030 (3)0.024 (6)0.011 (5)0.007 (3)
C200.105 (6)0.046 (3)0.093 (5)0.013 (4)0.047 (4)0.007 (3)
C210.035 (3)0.034 (2)0.035 (2)0.0034 (19)0.0023 (18)0.0058 (19)
C220.043 (3)0.031 (2)0.029 (2)0.0011 (19)0.0055 (19)0.0034 (17)
C230.054 (3)0.035 (3)0.037 (3)0.001 (2)0.007 (2)0.0032 (19)
C240.053 (3)0.035 (3)0.041 (3)0.008 (2)0.007 (2)0.002 (2)
C250.046 (3)0.034 (2)0.047 (3)0.005 (2)0.003 (2)0.003 (2)
C260.052 (3)0.044 (3)0.043 (2)0.001 (3)0.005 (2)0.006 (2)
C270.045 (3)0.034 (3)0.045 (3)0.003 (2)0.004 (2)0.0020 (19)
C280.074 (4)0.031 (3)0.107 (5)0.012 (3)0.005 (4)0.003 (3)
Geometric parameters (Å, º) top
Ru1—O12.067 (3)C12—C131.503 (6)
Ru1—O22.078 (3)C12—C141.546 (8)
Ru1—C32.144 (4)C12—C181.559 (7)
Ru1—C42.174 (5)C13—H13A0.9600
Ru1—C72.174 (5)C13—H13B0.9600
Ru1—C52.182 (4)C13—H13C0.9600
Ru1—C62.197 (5)C14—C151.561 (7)
Ru1—C22.203 (4)C14—H14A0.9700
Ru1—Cl22.4065 (11)C14—H14B0.9700
O2—C111.266 (5)C15—C161.537 (8)
O1—C211.277 (5)C15—H15A0.9700
O3—C251.371 (5)C15—H15B0.9700
O3—C281.411 (6)C16—C171.522 (6)
C1—C21.497 (6)C16—C181.545 (7)
C1—H1A0.9600C16—H160.9800
C1—H1B0.9600C17—C211.388 (6)
C1—H1C0.9600C18—C201.531 (10)
C2—C31.412 (6)C18—C191.548 (7)
C2—C71.424 (7)C19—H19A0.9600
C3—C41.400 (6)C19—H19B0.9600
C3—H30.9300C19—H19C0.9600
C4—C51.427 (6)C20—H20A0.9600
C4—H40.9300C20—H20B0.9600
C5—C61.425 (6)C20—H20C0.9600
C5—C81.510 (6)C21—C221.500 (6)
C6—C71.422 (6)C22—C271.375 (6)
C6—H60.9300C22—C231.389 (6)
C7—H70.9300C23—C241.391 (6)
C8—C91.511 (7)C23—H230.9300
C8—C101.543 (6)C24—C251.374 (7)
C8—H80.9800C24—H240.9300
C9—H9A0.9600C25—C261.378 (7)
C9—H9B0.9600C26—C271.386 (5)
C9—H9C0.9600C26—H260.9300
C10—H10A0.9600C27—H270.9300
C10—H10B0.9600C28—H28A0.9600
C10—H10C0.9600C28—H28B0.9600
C11—C171.396 (6)C28—H28C0.9600
C11—C121.529 (6)
O1—Ru1—O288.64 (10)C8—C9—H9C109.5
O1—Ru1—C3135.74 (14)H9A—C9—H9C109.5
O2—Ru1—C3134.13 (15)H9B—C9—H9C109.5
O1—Ru1—C4167.88 (15)C8—C10—H10A109.5
O2—Ru1—C4100.74 (13)C8—C10—H10B109.5
C3—Ru1—C437.82 (17)H10A—C10—H10B109.5
O1—Ru1—C786.98 (15)C8—C10—H10C109.5
O2—Ru1—C7139.51 (17)H10A—C10—H10C109.5
C3—Ru1—C767.86 (19)H10B—C10—H10C109.5
C4—Ru1—C780.90 (17)O2—C11—C17131.9 (4)
O1—Ru1—C5136.04 (15)O2—C11—C12120.7 (4)
O2—Ru1—C587.48 (15)C17—C11—C12107.4 (4)
C3—Ru1—C568.68 (19)C13—C12—C11115.7 (4)
C4—Ru1—C538.26 (17)C13—C12—C14115.7 (5)
C7—Ru1—C568.78 (17)C11—C12—C14103.4 (4)
O1—Ru1—C6101.93 (15)C13—C12—C18118.2 (5)
O2—Ru1—C6104.60 (15)C11—C12—C1899.1 (4)
C3—Ru1—C680.5 (2)C14—C12—C18102.4 (5)
C4—Ru1—C668.43 (17)C12—C13—H13A109.5
C7—Ru1—C637.96 (17)C12—C13—H13B109.5
C5—Ru1—C637.97 (15)H13A—C13—H13B109.5
O1—Ru1—C2101.14 (14)C12—C13—H13C109.5
O2—Ru1—C2169.09 (13)H13A—C13—H13C109.5
C3—Ru1—C237.87 (17)H13B—C13—H13C109.5
C4—Ru1—C268.93 (16)C12—C14—C15104.2 (5)
C7—Ru1—C237.97 (18)C12—C14—H14A110.9
C5—Ru1—C282.13 (17)C15—C14—H14A110.9
C6—Ru1—C268.88 (17)C12—C14—H14B110.9
O1—Ru1—Cl285.31 (11)C15—C14—H14B110.9
O2—Ru1—Cl282.86 (10)H14A—C14—H14B108.9
C3—Ru1—Cl289.07 (16)C16—C15—C14101.6 (4)
C4—Ru1—Cl2103.34 (13)C16—C15—H15A111.4
C7—Ru1—Cl2136.66 (14)C14—C15—H15A111.4
C5—Ru1—Cl2137.34 (12)C16—C15—H15B111.4
C6—Ru1—Cl2169.57 (13)C14—C15—H15B111.4
C2—Ru1—Cl2102.56 (13)H15A—C15—H15B109.3
C11—O2—Ru1122.2 (3)C17—C16—C15105.9 (4)
C21—O1—Ru1129.0 (3)C17—C16—C18101.7 (4)
C25—O3—C28117.3 (4)C15—C16—C18102.9 (4)
C2—C1—H1A109.5C17—C16—H16114.9
C2—C1—H1B109.5C15—C16—H16114.9
H1A—C1—H1B109.5C18—C16—H16114.9
C2—C1—H1C109.5C21—C17—C11124.2 (4)
H1A—C1—H1C109.5C21—C17—C16130.5 (4)
H1B—C1—H1C109.5C11—C17—C16105.1 (4)
C3—C2—C7116.4 (4)C20—C18—C16113.5 (5)
C3—C2—C1122.9 (5)C20—C18—C19108.7 (6)
C7—C2—C1120.7 (4)C16—C18—C19114.8 (5)
C3—C2—Ru168.8 (2)C20—C18—C12113.0 (4)
C7—C2—Ru169.9 (3)C16—C18—C1293.1 (4)
C1—C2—Ru1129.1 (3)C19—C18—C12113.2 (5)
C4—C3—C2123.6 (5)C18—C19—H19A109.5
C4—C3—Ru172.3 (3)C18—C19—H19B109.5
C2—C3—Ru173.4 (2)H19A—C19—H19B109.5
C4—C3—H3118.2C18—C19—H19C109.5
C2—C3—H3118.2H19A—C19—H19C109.5
Ru1—C3—H3128.7H19B—C19—H19C109.5
C3—C4—C5119.3 (4)C18—C20—H20A109.5
C3—C4—Ru169.9 (3)C18—C20—H20B109.5
C5—C4—Ru171.1 (2)H20A—C20—H20B109.5
C3—C4—H4120.3C18—C20—H20C109.5
C5—C4—H4120.3H20A—C20—H20C109.5
Ru1—C4—H4131.3H20B—C20—H20C109.5
C6—C5—C4119.1 (4)O1—C21—C17123.7 (4)
C6—C5—C8122.9 (4)O1—C21—C22112.3 (4)
C4—C5—C8118.0 (4)C17—C21—C22124.0 (4)
C6—C5—Ru171.6 (2)C27—C22—C23117.5 (4)
C4—C5—Ru170.6 (2)C27—C22—C21118.1 (4)
C8—C5—Ru1128.0 (3)C23—C22—C21124.0 (4)
C7—C6—C5119.6 (5)C22—C23—C24121.3 (4)
C7—C6—Ru170.2 (3)C22—C23—H23119.4
C5—C6—Ru170.4 (3)C24—C23—H23119.4
C7—C6—H6120.2C25—C24—C23120.0 (4)
C5—C6—H6120.2C25—C24—H24120.0
Ru1—C6—H6132.1C23—C24—H24120.0
C6—C7—C2122.0 (4)O3—C25—C24125.7 (4)
C6—C7—Ru171.9 (3)O3—C25—C26114.9 (4)
C2—C7—Ru172.1 (3)C24—C25—C26119.4 (4)
C6—C7—H7119.0C25—C26—C27120.0 (5)
C2—C7—H7119.0C25—C26—H26120.0
Ru1—C7—H7129.6C27—C26—H26120.0
C5—C8—C9114.7 (4)C22—C27—C26121.7 (4)
C5—C8—C10107.5 (4)C22—C27—H27119.1
C9—C8—C10111.6 (5)C26—C27—H27119.1
C5—C8—H8107.6O3—C28—H28A109.5
C9—C8—H8107.6O3—C28—H28B109.5
C10—C8—H8107.6H28A—C28—H28B109.5
C8—C9—H9A109.5O3—C28—H28C109.5
C8—C9—H9B109.5H28A—C28—H28C109.5
H9A—C9—H9B109.5H28B—C28—H28C109.5
O1—Ru1—O2—C114.9 (4)C4—C5—C6—Ru154.2 (3)
C3—Ru1—O2—C11162.3 (4)C8—C5—C6—Ru1123.9 (4)
C4—Ru1—O2—C11177.2 (4)O1—Ru1—C6—C769.0 (3)
C7—Ru1—O2—C1188.6 (4)O2—Ru1—C6—C7160.7 (3)
C5—Ru1—O2—C11141.1 (4)C3—Ru1—C6—C766.0 (3)
C6—Ru1—O2—C11106.9 (4)C4—Ru1—C6—C7103.3 (3)
C2—Ru1—O2—C11158.8 (8)C5—Ru1—C6—C7133.3 (4)
Cl2—Ru1—O2—C1180.6 (3)C2—Ru1—C6—C728.5 (3)
O2—Ru1—O1—C216.7 (4)Cl2—Ru1—C6—C764.4 (7)
C3—Ru1—O1—C21160.1 (4)O1—Ru1—C6—C5157.7 (3)
C4—Ru1—O1—C21147.7 (7)O2—Ru1—C6—C566.0 (3)
C7—Ru1—O1—C21146.4 (4)C3—Ru1—C6—C567.4 (3)
C5—Ru1—O1—C2191.7 (4)C4—Ru1—C6—C530.0 (3)
C6—Ru1—O1—C21111.3 (4)C7—Ru1—C6—C5133.3 (4)
C2—Ru1—O1—C21178.2 (4)C2—Ru1—C6—C5104.9 (3)
Cl2—Ru1—O1—C2176.2 (4)Cl2—Ru1—C6—C569.0 (7)
O1—Ru1—C2—C3159.3 (3)C5—C6—C7—C22.2 (7)
O2—Ru1—C2—C347.2 (10)Ru1—C6—C7—C254.2 (4)
C4—Ru1—C2—C327.9 (3)C5—C6—C7—Ru152.0 (4)
C7—Ru1—C2—C3130.5 (4)C3—C2—C7—C61.8 (7)
C5—Ru1—C2—C365.1 (3)C1—C2—C7—C6178.4 (4)
C6—Ru1—C2—C3102.0 (3)Ru1—C2—C7—C654.1 (4)
Cl2—Ru1—C2—C371.7 (3)C3—C2—C7—Ru152.3 (4)
O1—Ru1—C2—C770.1 (3)C1—C2—C7—Ru1124.3 (4)
O2—Ru1—C2—C783.3 (9)O1—Ru1—C7—C6113.8 (3)
C3—Ru1—C2—C7130.5 (4)O2—Ru1—C7—C629.5 (4)
C4—Ru1—C2—C7102.6 (3)C3—Ru1—C7—C6103.4 (3)
C5—Ru1—C2—C765.4 (3)C4—Ru1—C7—C666.4 (3)
C6—Ru1—C2—C728.5 (3)C5—Ru1—C7—C628.7 (3)
Cl2—Ru1—C2—C7157.8 (2)C2—Ru1—C7—C6133.7 (4)
O1—Ru1—C2—C143.6 (5)Cl2—Ru1—C7—C6166.2 (2)
O2—Ru1—C2—C1163.0 (7)O1—Ru1—C7—C2112.5 (3)
C3—Ru1—C2—C1115.7 (6)O2—Ru1—C7—C2163.2 (2)
C4—Ru1—C2—C1143.7 (5)C3—Ru1—C7—C230.3 (3)
C7—Ru1—C2—C1113.7 (5)C4—Ru1—C7—C267.3 (3)
C5—Ru1—C2—C1179.1 (5)C5—Ru1—C7—C2105.0 (3)
C6—Ru1—C2—C1142.2 (5)C6—Ru1—C7—C2133.7 (4)
Cl2—Ru1—C2—C144.0 (5)Cl2—Ru1—C7—C232.6 (3)
C7—C2—C3—C41.7 (7)C6—C5—C8—C917.8 (6)
C1—C2—C3—C4178.3 (5)C4—C5—C8—C9160.3 (4)
Ru1—C2—C3—C454.6 (4)Ru1—C5—C8—C973.8 (6)
C7—C2—C3—Ru152.8 (4)C6—C5—C8—C10107.0 (5)
C1—C2—C3—Ru1123.7 (4)C4—C5—C8—C1074.9 (5)
O1—Ru1—C3—C4164.3 (3)Ru1—C5—C8—C10161.4 (4)
O2—Ru1—C3—C434.3 (4)Ru1—O2—C11—C172.3 (7)
C7—Ru1—C3—C4104.2 (3)Ru1—O2—C11—C12177.4 (3)
C5—Ru1—C3—C429.3 (3)O2—C11—C12—C1316.3 (8)
C6—Ru1—C3—C466.9 (3)C17—C11—C12—C13163.9 (5)
C2—Ru1—C3—C4134.6 (5)O2—C11—C12—C14111.1 (5)
Cl2—Ru1—C3—C4113.4 (3)C17—C11—C12—C1468.7 (5)
O1—Ru1—C3—C229.7 (4)O2—C11—C12—C18143.7 (5)
O2—Ru1—C3—C2168.8 (2)C17—C11—C12—C1836.5 (5)
C4—Ru1—C3—C2134.6 (5)C13—C12—C14—C15161.5 (4)
C7—Ru1—C3—C230.3 (3)C11—C12—C14—C1571.0 (5)
C5—Ru1—C3—C2105.2 (3)C18—C12—C14—C1531.6 (5)
C6—Ru1—C3—C267.7 (3)C12—C14—C15—C164.1 (5)
Cl2—Ru1—C3—C2112.0 (3)C14—C15—C16—C1767.1 (5)
C2—C3—C4—C51.9 (7)C14—C15—C16—C1839.1 (5)
Ru1—C3—C4—C553.1 (4)O2—C11—C17—C211.5 (8)
C2—C3—C4—Ru155.0 (4)C12—C11—C17—C21178.7 (4)
O1—Ru1—C4—C364.2 (8)O2—C11—C17—C16177.7 (5)
O2—Ru1—C4—C3155.7 (3)C12—C11—C17—C162.5 (5)
C7—Ru1—C4—C365.4 (3)C15—C16—C17—C21109.9 (6)
C5—Ru1—C4—C3132.5 (4)C18—C16—C17—C21142.9 (5)
C6—Ru1—C4—C3102.7 (3)C15—C16—C17—C1174.2 (5)
C2—Ru1—C4—C328.0 (3)C18—C16—C17—C1132.9 (5)
Cl2—Ru1—C4—C370.6 (3)C17—C16—C18—C2064.3 (5)
O1—Ru1—C4—C568.4 (8)C15—C16—C18—C20173.8 (4)
O2—Ru1—C4—C571.8 (3)C17—C16—C18—C19169.9 (6)
C3—Ru1—C4—C5132.5 (4)C15—C16—C18—C1960.3 (7)
C7—Ru1—C4—C567.1 (3)C17—C16—C18—C1252.5 (5)
C6—Ru1—C4—C529.8 (3)C15—C16—C18—C1257.0 (4)
C2—Ru1—C4—C5104.6 (3)C13—C12—C18—C2061.2 (6)
Cl2—Ru1—C4—C5156.9 (2)C11—C12—C18—C2064.5 (5)
C3—C4—C5—C62.1 (6)C14—C12—C18—C20170.5 (5)
Ru1—C4—C5—C654.7 (3)C13—C12—C18—C16178.3 (5)
C3—C4—C5—C8176.0 (4)C11—C12—C18—C1652.7 (5)
Ru1—C4—C5—C8123.5 (4)C14—C12—C18—C1653.3 (5)
C3—C4—C5—Ru152.5 (4)C13—C12—C18—C1962.9 (7)
O1—Ru1—C5—C632.4 (4)C11—C12—C18—C19171.4 (5)
O2—Ru1—C5—C6117.8 (3)C14—C12—C18—C1965.4 (6)
C3—Ru1—C5—C6102.3 (3)Ru1—O1—C21—C175.3 (6)
C4—Ru1—C5—C6131.3 (4)Ru1—O1—C21—C22176.3 (3)
C7—Ru1—C5—C628.7 (3)C11—C17—C21—O10.0 (7)
C2—Ru1—C5—C665.5 (3)C16—C17—C21—O1175.1 (5)
Cl2—Ru1—C5—C6165.6 (2)C11—C17—C21—C22178.2 (4)
O1—Ru1—C5—C4163.7 (2)C16—C17—C21—C223.1 (8)
O2—Ru1—C5—C4110.9 (2)O1—C21—C22—C2727.9 (6)
C3—Ru1—C5—C429.0 (3)C17—C21—C22—C27150.5 (5)
C7—Ru1—C5—C4102.6 (3)O1—C21—C22—C23145.5 (5)
C6—Ru1—C5—C4131.3 (4)C17—C21—C22—C2336.1 (7)
C2—Ru1—C5—C465.7 (3)C27—C22—C23—C240.1 (7)
Cl2—Ru1—C5—C434.3 (3)C21—C22—C23—C24173.3 (4)
O1—Ru1—C5—C885.4 (4)C22—C23—C24—C251.1 (7)
O2—Ru1—C5—C80.0 (4)C28—O3—C25—C245.9 (8)
C3—Ru1—C5—C8139.9 (4)C28—O3—C25—C26174.3 (5)
C4—Ru1—C5—C8110.9 (5)C23—C24—C25—O3179.4 (5)
C7—Ru1—C5—C8146.5 (4)C23—C24—C25—C260.4 (7)
C6—Ru1—C5—C8117.8 (5)O3—C25—C26—C27178.9 (5)
C2—Ru1—C5—C8176.6 (4)C24—C25—C26—C271.3 (7)
Cl2—Ru1—C5—C876.6 (4)C23—C22—C27—C261.7 (7)
C4—C5—C6—C72.3 (6)C21—C22—C27—C26175.4 (4)
C8—C5—C6—C7175.8 (4)C25—C26—C27—C222.4 (8)
Ru1—C5—C6—C751.9 (4)
 

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