Acta Cryst. (2006). E62, m3453-m3455  [ doi:10.1107/S160053680604760X ]

Tetrakis(tri-p-tolylphosphine-P)silver(I) hexafluorophosphate

G. J. S. Venter, R. Meijboom and A. Roodt

Abstract: The title compound, [Ag(P(p-tol)₃}₄]PF₆ or [Ag(C₂₁H₂₁P)₄]PF₆, crystallizes with parts of two independent formula units in the asymmetric unit. The Ag-P distances range between 2.5665 (13) and 2.6142 (7) Å, and the P-Ag-P angles between 109.310 (18) and 109.632 (18)°, indicating a distorted tetrahedral geometry. Both Ag atoms and both PF₆^- anions lie on threefold rotation axes.

Online 24 November 2006

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