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Acta Cryst. (2006). E62, m3554-m3556  [ doi:10.1107/S1600536806050033 ]

[Delta]L-(L-Cysteinato-[kappa]2N,S)bis(ethylenediamine-[kappa]2N,N')cobalt(III) bis(perchlorate) monohydrate

T. Aridomi and T. Konno

Abstract: In the title compound, [Co(C3H6NO2S)(C2H8N2)2](ClO4)2·H2O, the central CoIII atom is coordinated by one N,S-bidentate L-cysteine (L-H2cys) and two N,N'-bidentate ethylenediamine (en) ligands in a slightly distorted octahedral geometry with a [Delta] configuration. The L-Hcys chelate ring adopts a [lambda] conformation, while the two en chelate rings have a [delta] conformation.

Online 30 November 2006


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