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The new iodo­bismuthate compound (C13H11N2O)4[Bi6I22] has been synthesized solvothermally by reacting BiI3, Zn(NO3)2·6H2O and 4,5-diaza­fluoren-9-one in a water/ethanol solvent mixture. The asymmetric unit of the compound contains two independent [N-ethyl-4,5-dafo]+ cations and one-half of a centrosymmetric [Bi6I22]4− anion. The average terminal Bi—I, Bi—μ2-I and Bi—μ3-I bond lengths in the anion are 2.8923 (2), 3.1403 (2) and 3.3022 (2) Å, respectively.

Supporting information

cif

Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536806043960/om2062sup1.cif
Contains datablocks global, I

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S1600536806043960/om2062Isup2.hkl
Contains datablock I

CCDC reference: 630207

Key indicators

  • Single-crystal X-ray study
  • T = 150 K
  • Mean [sigma](C-C) = 0.013 Å
  • R factor = 0.035
  • wR factor = 0.076
  • Data-to-parameter ratio = 23.0

checkCIF/PLATON results

No syntax errors found



Alert level B PLAT411_ALERT_2_B Short Inter H...H Contact H12A .. H12A .. 2.05 Ang.
Alert level C PLAT042_ALERT_1_C Calc. and Rep. MoietyFormula Strings Differ .... ? PLAT066_ALERT_1_C Predicted and Reported Transmissions Identical . ? PLAT232_ALERT_2_C Hirshfeld Test Diff (M-X) Bi1 - I2 .. 7.27 su PLAT232_ALERT_2_C Hirshfeld Test Diff (M-X) Bi1 - I5 .. 6.85 su PLAT232_ALERT_2_C Hirshfeld Test Diff (M-X) Bi2 - I10 .. 8.08 su PLAT232_ALERT_2_C Hirshfeld Test Diff (M-X) Bi2 - I10_a .. 8.89 su PLAT232_ALERT_2_C Hirshfeld Test Diff (M-X) Bi3 - I6 .. 8.42 su PLAT342_ALERT_3_C Low Bond Precision on C-C bonds (x 1000) Ang ... 13
0 ALERT level A = In general: serious problem 1 ALERT level B = Potentially serious problem 8 ALERT level C = Check and explain 0 ALERT level G = General alerts; check 2 ALERT type 1 CIF construction/syntax error, inconsistent or missing data 6 ALERT type 2 Indicator that the structure model may be wrong or deficient 1 ALERT type 3 Indicator that the structure quality may be low 0 ALERT type 4 Improvement, methodology, query or suggestion 0 ALERT type 5 Informative message, check

Computing details top

Data collection: SMART-NT (Bruker, 1998); cell refinement: SAINT-Plus (Bruker, 2001); data reduction: SAINT-Plus; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: SHELXTL (Bruker, 2000); software used to prepare material for publication: SHELXTL.

Tetrakis(N-ethyl-9-oxo-4-azonia-5-aza-9H-fluorene) tetra-µ3-iodo-hexa-µ2-iodo-dodecaiodohexabismuthate top
Crystal data top
(C13H11N2O)4[Bi6I22]F(000) = 8432
Mr = 4890.63Dx = 3.492 Mg m3
Monoclinic, C2/cMo Kα radiation, λ = 0.71073 Å
Hall symbol: -C 2ycCell parameters from 5414 reflections
a = 13.3944 (10) Åθ = 2.2–26.4°
b = 17.0764 (12) ŵ = 18.65 mm1
c = 40.710 (3) ÅT = 150 K
β = 92.589 (1)°Plate, orange
V = 9302.1 (12) Å30.14 × 0.08 × 0.04 mm
Z = 4
Data collection top
Bruker SMART APEX CCD
diffractometer
9574 independent reflections
Radiation source: fine-focus sealed tube8178 reflections with I > 2σ(I)
Graphite monochromatorRint = 0.046
ω scansθmax = 26.5°, θmin = 1.9°
Absorption correction: multi-scan
(SADABS; Bruker, 2001)
h = 1616
Tmin = 0.180, Tmax = 0.474k = 2120
48604 measured reflectionsl = 5050
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.035Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.076H-atom parameters constrained
S = 1.08 w = 1/[σ2(Fo2) + (0.0257P)2 + 84.5173P]
where P = (Fo2 + 2Fc2)/3
9574 reflections(Δ/σ)max = 0.002
417 parametersΔρmax = 1.13 e Å3
0 restraintsΔρmin = 0.92 e Å3
Special details top

Experimental. Crystal red at 294 K, becomes lighter red / orange at lower T

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
Bi10.58269 (2)0.559959 (19)0.357488 (7)0.02597 (8)
Bi20.63654 (2)0.555310 (18)0.470898 (7)0.02425 (8)
Bi30.31254 (2)0.457963 (18)0.417111 (7)0.02355 (8)
I10.79551 (4)0.53826 (4)0.354655 (15)0.03777 (15)
I20.56134 (5)0.69102 (4)0.310694 (15)0.03752 (14)
I30.54283 (4)0.43512 (4)0.309781 (14)0.03658 (14)
I40.84414 (4)0.52351 (4)0.463371 (15)0.03879 (15)
I50.62568 (4)0.68141 (3)0.420556 (13)0.03232 (13)
I60.56516 (4)0.43168 (3)0.416030 (12)0.02507 (11)
I70.33888 (4)0.58307 (3)0.366416 (14)0.02981 (13)
I80.27153 (5)0.33928 (3)0.368140 (14)0.03507 (14)
I90.67730 (4)0.67088 (3)0.526158 (13)0.03045 (13)
I100.61359 (4)0.41704 (3)0.523267 (13)0.02576 (12)
I110.10666 (4)0.49779 (4)0.424419 (16)0.03953 (15)
C10.8461 (7)0.4302 (6)0.2707 (2)0.043 (2)
C20.7875 (7)0.4980 (5)0.2574 (2)0.036 (2)
C30.6959 (7)0.5018 (7)0.2401 (2)0.044 (2)
H30.65820.45580.23530.052*
C40.6616 (7)0.5742 (6)0.2300 (2)0.046 (2)
H40.59930.57840.21800.055*
C50.7159 (7)0.6397 (6)0.2371 (2)0.042 (2)
H50.69030.68910.23010.051*
C60.8410 (7)0.5666 (5)0.2644 (2)0.033 (2)
C70.9363 (7)0.5467 (5)0.2836 (2)0.033 (2)
C81.0801 (7)0.5628 (6)0.3123 (2)0.041 (2)
H81.13090.59630.32140.050*
C91.0906 (7)0.4834 (6)0.3174 (2)0.039 (2)
H91.14640.46390.33020.047*
C101.0194 (7)0.4318 (6)0.3040 (2)0.044 (2)
H101.02570.37670.30640.052*
C110.9381 (7)0.4662 (5)0.2867 (2)0.035 (2)
C120.8627 (7)0.7127 (6)0.2598 (2)0.045 (2)
H12A0.93510.70130.26250.054*
H12B0.85210.74730.24040.054*
C130.8292 (8)0.7527 (7)0.2892 (2)0.053 (3)
H13A0.75970.76960.28550.080*
H13B0.87160.79860.29380.080*
H13C0.83410.71680.30800.080*
C140.6761 (7)0.2519 (5)0.3492 (2)0.035 (2)
C150.6038 (7)0.2304 (5)0.3745 (2)0.032 (2)
C160.5075 (7)0.2048 (5)0.3709 (2)0.036 (2)
H160.47590.19780.34970.044*
C170.4572 (7)0.1893 (5)0.3994 (2)0.039 (2)
H170.38930.17300.39780.047*
C180.5056 (7)0.1974 (5)0.4298 (2)0.035 (2)
H180.47100.18460.44890.042*
C190.6500 (6)0.2412 (4)0.40585 (19)0.0266 (18)
C200.7498 (6)0.2749 (5)0.4021 (2)0.0307 (19)
C210.9030 (7)0.3239 (6)0.4158 (2)0.043 (2)
H210.95230.33970.43190.052*
C220.9241 (7)0.3336 (5)0.3827 (2)0.042 (2)
H220.98620.35530.37690.050*
C230.8536 (7)0.3113 (5)0.3584 (2)0.041 (2)
H230.86660.31560.33570.050*
C240.7636 (7)0.2827 (5)0.3687 (2)0.0291 (19)
C250.6501 (8)0.2301 (6)0.4660 (2)0.043 (2)
H25A0.66000.28640.47090.051*
H25B0.71710.20570.46550.051*
C260.5954 (8)0.1937 (7)0.4938 (2)0.053 (3)
H26A0.53100.22010.49590.080*
H26B0.63560.19930.51440.080*
H26C0.58400.13790.48930.080*
N10.8055 (5)0.6368 (4)0.25404 (17)0.0353 (17)
N21.0033 (5)0.5959 (5)0.29533 (18)0.0373 (18)
N30.6012 (5)0.2231 (4)0.43306 (16)0.0298 (16)
N40.8167 (5)0.2935 (4)0.42615 (19)0.0364 (18)
O10.8248 (5)0.3621 (4)0.26904 (18)0.0543 (19)
O20.6672 (5)0.2446 (4)0.31998 (14)0.0433 (16)
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Bi10.02548 (16)0.02896 (18)0.02360 (15)0.00162 (12)0.00239 (12)0.00028 (13)
Bi20.02329 (16)0.02715 (17)0.02249 (15)0.00182 (12)0.00305 (12)0.00045 (12)
Bi30.02263 (16)0.02452 (16)0.02355 (15)0.00060 (12)0.00148 (12)0.00050 (12)
I10.0253 (3)0.0540 (4)0.0344 (3)0.0003 (3)0.0057 (2)0.0060 (3)
I20.0447 (3)0.0323 (3)0.0359 (3)0.0038 (3)0.0052 (3)0.0058 (3)
I30.0393 (3)0.0337 (3)0.0363 (3)0.0004 (2)0.0034 (3)0.0071 (3)
I40.0251 (3)0.0498 (4)0.0420 (3)0.0033 (3)0.0079 (2)0.0026 (3)
I50.0437 (3)0.0276 (3)0.0256 (3)0.0050 (2)0.0011 (2)0.0023 (2)
I60.0260 (3)0.0235 (3)0.0258 (3)0.0023 (2)0.0015 (2)0.0010 (2)
I70.0265 (3)0.0286 (3)0.0344 (3)0.0019 (2)0.0028 (2)0.0086 (2)
I80.0480 (4)0.0272 (3)0.0296 (3)0.0008 (2)0.0023 (3)0.0035 (2)
I90.0429 (3)0.0246 (3)0.0239 (3)0.0056 (2)0.0021 (2)0.0007 (2)
I100.0265 (3)0.0233 (3)0.0275 (3)0.0002 (2)0.0024 (2)0.0013 (2)
I110.0238 (3)0.0431 (4)0.0521 (4)0.0022 (2)0.0061 (3)0.0049 (3)
C10.041 (6)0.044 (6)0.043 (6)0.000 (5)0.012 (4)0.002 (5)
C20.035 (5)0.036 (5)0.036 (5)0.001 (4)0.014 (4)0.008 (4)
C30.047 (6)0.062 (7)0.022 (4)0.008 (5)0.002 (4)0.009 (5)
C40.035 (5)0.062 (7)0.041 (6)0.001 (5)0.000 (4)0.004 (5)
C50.029 (5)0.054 (6)0.044 (6)0.011 (4)0.003 (4)0.006 (5)
C60.037 (5)0.042 (5)0.021 (4)0.003 (4)0.003 (4)0.000 (4)
C70.040 (5)0.036 (5)0.022 (4)0.001 (4)0.006 (4)0.002 (4)
C80.032 (5)0.060 (7)0.033 (5)0.001 (5)0.003 (4)0.012 (5)
C90.026 (5)0.053 (6)0.039 (5)0.005 (4)0.000 (4)0.001 (5)
C100.048 (6)0.049 (6)0.034 (5)0.005 (5)0.007 (4)0.010 (5)
C110.034 (5)0.043 (6)0.029 (5)0.002 (4)0.001 (4)0.010 (4)
C120.039 (6)0.044 (6)0.051 (6)0.002 (4)0.002 (5)0.001 (5)
C130.054 (7)0.061 (7)0.046 (6)0.015 (5)0.005 (5)0.007 (5)
C140.048 (6)0.028 (5)0.028 (5)0.010 (4)0.008 (4)0.003 (4)
C150.039 (5)0.028 (5)0.028 (4)0.013 (4)0.002 (4)0.001 (4)
C160.041 (5)0.033 (5)0.034 (5)0.012 (4)0.009 (4)0.002 (4)
C170.032 (5)0.033 (5)0.052 (6)0.004 (4)0.002 (4)0.005 (4)
C180.038 (5)0.033 (5)0.034 (5)0.010 (4)0.004 (4)0.007 (4)
C190.043 (5)0.016 (4)0.021 (4)0.011 (3)0.002 (4)0.005 (3)
C200.032 (5)0.031 (5)0.029 (4)0.006 (4)0.000 (4)0.010 (4)
C210.038 (5)0.053 (6)0.038 (5)0.005 (5)0.003 (4)0.004 (5)
C220.042 (6)0.035 (5)0.049 (6)0.000 (4)0.009 (5)0.002 (4)
C230.043 (6)0.038 (6)0.043 (6)0.005 (4)0.002 (4)0.005 (4)
C240.044 (5)0.019 (4)0.025 (4)0.000 (4)0.003 (4)0.004 (3)
C250.061 (7)0.032 (5)0.034 (5)0.007 (5)0.004 (5)0.000 (4)
C260.049 (6)0.064 (7)0.046 (6)0.018 (5)0.000 (5)0.001 (5)
N10.038 (4)0.035 (4)0.032 (4)0.000 (3)0.001 (3)0.001 (3)
N20.030 (4)0.051 (5)0.031 (4)0.002 (3)0.003 (3)0.011 (4)
N30.032 (4)0.030 (4)0.028 (4)0.010 (3)0.001 (3)0.001 (3)
N40.031 (4)0.033 (4)0.045 (5)0.004 (3)0.004 (3)0.005 (4)
O10.057 (5)0.040 (4)0.065 (5)0.004 (3)0.005 (4)0.006 (4)
O20.057 (4)0.045 (4)0.028 (3)0.003 (3)0.004 (3)0.004 (3)
Geometric parameters (Å, º) top
Bi1—I12.8820 (7)C9—H90.9500
Bi1—I32.9169 (7)C10—C111.399 (12)
Bi1—I22.9445 (7)C10—H100.9500
Bi1—I63.2533 (6)C12—C131.467 (13)
Bi1—I73.3257 (7)C12—N11.518 (12)
Bi1—I53.3304 (6)C12—H12A0.9900
Bi2—I42.8632 (7)C12—H12B0.9900
Bi2—I52.9718 (6)C13—H13A0.9800
Bi2—I93.0237 (6)C13—H13B0.9800
Bi2—I63.1887 (6)C13—H13C0.9800
Bi2—I103.2053 (6)C14—O21.198 (10)
Bi2—I10i3.4025 (6)C14—C241.482 (12)
Bi3—I112.8687 (7)C14—C151.490 (13)
Bi3—I82.8783 (6)C15—C161.364 (12)
Bi3—I73.0022 (6)C15—C191.404 (11)
Bi3—I9i3.1881 (6)C16—C171.392 (13)
Bi3—I10i3.3479 (6)C16—H160.9500
Bi3—I63.4156 (6)C17—C181.378 (12)
I9—Bi3i3.1881 (6)C17—H170.9500
I10—Bi3i3.3479 (6)C18—N31.355 (11)
I10—Bi2i3.4024 (6)C18—H180.9500
C1—O11.200 (11)C19—N31.347 (10)
C1—C21.487 (13)C19—C201.470 (12)
C1—C111.498 (13)C20—N41.336 (10)
C2—C31.388 (12)C20—C241.385 (11)
C2—C61.397 (12)C21—N41.352 (12)
C3—C41.374 (14)C21—C221.397 (13)
C3—H30.9500C21—H210.9500
C4—C51.359 (14)C22—C231.390 (13)
C4—H40.9500C22—H220.9500
C5—N11.357 (11)C23—C241.384 (13)
C5—H50.9500C23—H230.9500
C6—N11.350 (11)C25—N31.470 (11)
C6—C71.506 (12)C25—C261.512 (13)
C7—N21.304 (11)C25—H25A0.9900
C7—C111.381 (12)C25—H25B0.9900
C8—N21.339 (12)C26—H26A0.9800
C8—C91.379 (13)C26—H26B0.9800
C8—H80.9500C26—H26C0.9800
C9—C101.392 (13)
I1—Bi1—I391.780 (19)N2—C8—H8117.8
I1—Bi1—I298.00 (2)C9—C8—H8117.8
I3—Bi1—I296.62 (2)C8—C9—C10120.0 (9)
I1—Bi1—I692.696 (18)C8—C9—H9120.0
I3—Bi1—I688.772 (18)C10—C9—H9120.0
I2—Bi1—I6167.845 (19)C9—C10—C11115.8 (10)
I1—Bi1—I7175.988 (19)C9—C10—H10122.1
I3—Bi1—I790.477 (17)C11—C10—H10122.1
I2—Bi1—I785.029 (17)C7—C11—C10118.3 (9)
I6—Bi1—I784.035 (15)C7—C11—C1111.0 (8)
I1—Bi1—I588.513 (18)C10—C11—C1130.7 (9)
I3—Bi1—I5171.314 (19)C13—C12—N1110.7 (8)
I2—Bi1—I591.938 (18)C13—C12—H12A109.5
I6—Bi1—I582.544 (16)N1—C12—H12A109.5
I7—Bi1—I588.756 (16)C13—C12—H12B109.5
I4—Bi2—I594.654 (19)N1—C12—H12B109.5
I4—Bi2—I993.431 (19)H12A—C12—H12B108.1
I5—Bi2—I992.391 (18)C12—C13—H13A109.5
I4—Bi2—I693.520 (18)C12—C13—H13B109.5
I5—Bi2—I689.590 (17)H13A—C13—H13B109.5
I9—Bi2—I6172.594 (18)C12—C13—H13C109.5
I4—Bi2—I1093.111 (18)H13A—C13—H13C109.5
I5—Bi2—I10171.609 (18)H13B—C13—H13C109.5
I9—Bi2—I1090.312 (16)O2—C14—C24127.6 (9)
I6—Bi2—I1086.761 (16)O2—C14—C15128.5 (9)
I4—Bi2—I10i176.323 (19)C24—C14—C15103.9 (7)
I5—Bi2—I10i85.977 (16)C16—C15—C19121.0 (8)
I9—Bi2—I10i90.160 (16)C16—C15—C14130.2 (8)
I6—Bi2—I10i82.858 (14)C19—C15—C14108.8 (8)
I10—Bi2—I10i86.073 (15)C15—C16—C17117.6 (8)
I11—Bi3—I894.85 (2)C15—C16—H16121.2
I11—Bi3—I792.633 (19)C17—C16—H16121.2
I8—Bi3—I792.841 (19)C18—C17—C16120.2 (9)
I11—Bi3—I9i95.641 (19)C18—C17—H17119.9
I8—Bi3—I9i90.936 (18)C16—C17—H17119.9
I7—Bi3—I9i170.583 (18)N3—C18—C17121.7 (8)
I11—Bi3—I10i91.583 (18)N3—C18—H18119.1
I8—Bi3—I10i172.718 (18)C17—C18—H18119.1
I7—Bi3—I10i90.264 (17)N3—C19—C15120.5 (8)
I9i—Bi3—I10i85.030 (16)N3—C19—C20130.7 (7)
I11—Bi3—I6171.880 (19)C15—C19—C20108.8 (7)
I8—Bi3—I693.251 (17)N4—C20—C24125.5 (8)
I7—Bi3—I686.410 (15)N4—C20—C19126.9 (8)
I9i—Bi3—I684.764 (15)C24—C20—C19107.6 (7)
I10i—Bi3—I680.364 (14)N4—C21—C22124.0 (9)
Bi2—I5—Bi194.692 (18)N4—C21—H21118.0
Bi2—I6—Bi192.183 (16)C22—C21—H21118.0
Bi2—I6—Bi399.780 (15)C23—C22—C21119.5 (9)
Bi1—I6—Bi391.450 (14)C23—C22—H22120.2
Bi3—I7—Bi197.885 (16)C21—C22—H22120.2
Bi2—I9—Bi3i95.097 (17)C24—C23—C22116.9 (9)
Bi2—I10—Bi3i88.764 (15)C24—C23—H23121.5
Bi2—I10—Bi2i93.927 (15)C22—C23—H23121.5
Bi3i—I10—Bi2i96.932 (15)C23—C24—C20119.3 (8)
O1—C1—C2127.8 (9)C23—C24—C14129.9 (8)
O1—C1—C11127.7 (9)C20—C24—C14110.7 (8)
C2—C1—C11104.5 (8)N3—C25—C26116.0 (8)
C3—C2—C6119.8 (9)N3—C25—H25A108.3
C3—C2—C1131.5 (9)C26—C25—H25A108.3
C6—C2—C1108.7 (8)N3—C25—H25B108.3
C4—C3—C2118.0 (9)C26—C25—H25B108.3
C4—C3—H3121.0H25A—C25—H25B107.4
C2—C3—H3121.0C25—C26—H26A109.5
C5—C4—C3120.5 (9)C25—C26—H26B109.5
C5—C4—H4119.7H26A—C26—H26B109.5
C3—C4—H4119.7C25—C26—H26C109.5
N1—C5—C4122.0 (9)H26A—C26—H26C109.5
N1—C5—H5119.0H26B—C26—H26C109.5
C4—C5—H5119.0C6—N1—C5118.8 (8)
N1—C6—C2120.8 (8)C6—N1—C12122.8 (7)
N1—C6—C7129.9 (8)C5—N1—C12118.4 (8)
C2—C6—C7109.4 (8)C7—N2—C8114.6 (8)
N2—C7—C11126.9 (9)C19—N3—C18119.0 (7)
N2—C7—C6126.7 (8)C19—N3—C25121.2 (8)
C11—C7—C6106.4 (8)C18—N3—C25119.8 (8)
N2—C8—C9124.4 (9)C20—N4—C21114.6 (8)
I4—Bi2—I5—Bi185.824 (19)N1—C6—C7—N23.0 (15)
I9—Bi2—I5—Bi1179.464 (17)C2—C6—C7—N2177.6 (8)
I6—Bi2—I5—Bi17.674 (16)N1—C6—C7—C11177.8 (9)
I10i—Bi2—I5—Bi190.543 (16)C2—C6—C7—C111.6 (10)
I1—Bi1—I5—Bi285.329 (19)N2—C8—C9—C101.5 (15)
I2—Bi1—I5—Bi2176.714 (18)C8—C9—C10—C112.4 (13)
I6—Bi1—I5—Bi27.585 (16)N2—C7—C11—C100.3 (14)
I7—Bi1—I5—Bi291.732 (17)C6—C7—C11—C10179.5 (8)
I4—Bi2—I6—Bi186.801 (18)N2—C7—C11—C1178.2 (8)
I5—Bi2—I6—Bi17.837 (17)C6—C7—C11—C11.0 (10)
I10—Bi2—I6—Bi1179.723 (15)C9—C10—C11—C71.8 (13)
I10i—Bi2—I6—Bi193.833 (15)C9—C10—C11—C1176.4 (9)
I4—Bi2—I6—Bi3178.651 (18)O1—C1—C11—C7179.9 (10)
I5—Bi2—I6—Bi384.013 (17)C2—C1—C11—C70.1 (10)
I10—Bi2—I6—Bi388.427 (16)O1—C1—C11—C101.8 (17)
I10i—Bi2—I6—Bi31.984 (14)C2—C1—C11—C10178.3 (9)
I1—Bi1—I6—Bi281.097 (18)O2—C14—C15—C167.2 (16)
I3—Bi1—I6—Bi2172.821 (17)C24—C14—C15—C16174.4 (9)
I2—Bi1—I6—Bi270.58 (9)O2—C14—C15—C19173.4 (9)
I7—Bi1—I6—Bi296.570 (16)C24—C14—C15—C195.0 (9)
I5—Bi1—I6—Bi27.048 (15)C19—C15—C16—C170.5 (12)
I1—Bi1—I6—Bi3179.056 (17)C14—C15—C16—C17179.8 (8)
I3—Bi1—I6—Bi387.332 (17)C15—C16—C17—C182.1 (13)
I2—Bi1—I6—Bi329.27 (9)C16—C17—C18—N32.4 (13)
I7—Bi1—I6—Bi33.277 (14)C16—C15—C19—N32.9 (12)
I5—Bi1—I6—Bi392.799 (15)C14—C15—C19—N3177.6 (7)
I8—Bi3—I6—Bi2178.504 (17)C16—C15—C19—C20175.5 (8)
I7—Bi3—I6—Bi288.849 (18)C14—C15—C19—C204.0 (9)
I9i—Bi3—I6—Bi287.861 (17)N3—C19—C20—N42.0 (14)
I10i—Bi3—I6—Bi22.029 (15)C15—C19—C20—N4179.9 (8)
I8—Bi3—I6—Bi189.029 (18)N3—C19—C20—C24179.3 (8)
I7—Bi3—I6—Bi13.617 (16)C15—C19—C20—C241.2 (9)
I9i—Bi3—I6—Bi1179.672 (15)N4—C21—C22—C230.1 (15)
I10i—Bi3—I6—Bi194.496 (16)C21—C22—C23—C242.1 (14)
I11—Bi3—I7—Bi1175.496 (18)C22—C23—C24—C202.4 (13)
I8—Bi3—I7—Bi189.511 (19)C22—C23—C24—C14177.6 (8)
I10i—Bi3—I7—Bi183.899 (16)N4—C20—C24—C230.5 (13)
I6—Bi3—I7—Bi13.571 (16)C19—C20—C24—C23178.2 (8)
I3—Bi1—I7—Bi384.95 (2)N4—C20—C24—C14176.6 (8)
I2—Bi1—I7—Bi3178.449 (19)C19—C20—C24—C142.2 (9)
I6—Bi1—I7—Bi33.763 (16)O2—C14—C24—C231.5 (16)
I5—Bi1—I7—Bi386.395 (18)C15—C14—C24—C23180.0 (9)
I4—Bi2—I9—Bi3i86.046 (19)O2—C14—C24—C20174.0 (9)
I5—Bi2—I9—Bi3i179.143 (17)C15—C14—C24—C204.4 (9)
I10—Bi2—I9—Bi3i7.089 (17)C2—C6—N1—C51.2 (12)
I10i—Bi2—I9—Bi3i93.164 (16)C7—C6—N1—C5179.4 (8)
I4—Bi2—I10—Bi3i86.729 (18)C2—C6—N1—C12177.4 (8)
I9—Bi2—I10—Bi3i6.724 (16)C7—C6—N1—C122.0 (14)
I6—Bi2—I10—Bi3i179.917 (14)C4—C5—N1—C60.8 (14)
I10i—Bi2—I10—Bi3i96.863 (15)C4—C5—N1—C12177.8 (9)
I4—Bi2—I10—Bi2i176.407 (19)C13—C12—N1—C696.0 (10)
I9—Bi2—I10—Bi2i90.140 (16)C13—C12—N1—C585.4 (10)
I6—Bi2—I10—Bi2i83.053 (14)C11—C7—N2—C80.7 (13)
I10i—Bi2—I10—Bi2i0.001 (2)C6—C7—N2—C8178.3 (8)
O1—C1—C2—C30.1 (17)C9—C8—N2—C70.1 (13)
C11—C1—C2—C3179.9 (9)C15—C19—N3—C182.6 (11)
O1—C1—C2—C6178.9 (10)C20—C19—N3—C18175.4 (8)
C11—C1—C2—C60.9 (10)C15—C19—N3—C25176.8 (8)
C6—C2—C3—C40.7 (13)C20—C19—N3—C255.2 (13)
C1—C2—C3—C4178.1 (9)C17—C18—N3—C190.0 (12)
C2—C3—C4—C50.4 (14)C17—C18—N3—C25179.4 (8)
C3—C4—C5—N10.4 (15)C26—C25—N3—C19168.6 (8)
C3—C2—C6—N11.1 (13)C26—C25—N3—C1810.8 (12)
C1—C2—C6—N1177.9 (8)C24—C20—N4—C211.7 (13)
C3—C2—C6—C7179.4 (7)C19—C20—N4—C21179.8 (8)
C1—C2—C6—C71.6 (10)C22—C21—N4—C202.0 (14)
Symmetry code: (i) x+1, y+1, z+1.
 

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