Acta Cryst. (2006). E62, m3395-m3397  [ doi:10.1107/S1600536806048707 ]

Poly[[[aqua(1,10-phenanthroline-²N,N')nickel(II)]-₃-4,4'-(ethene-1,2-diyl)dibenzoato-₂-4,4'-(ethene-1,2-diyl)dibenzoato] monohydrate]

H.-Y. Wang, S. Gao, L.-H. Huo and J.-G. Zhao

Abstract: In the title complex, {[Ni(C₁₆H₁₀O₄)(C₁₂H₈N₂)(H₂O)]·H₂O}_n, the Ni^II ion is in a distorted octahedral geometry and coordinated by two N atoms of a 1,10-phenanthroline (phen) ligand, three carboxylate O atoms of two different bpea^2- ligands and one water molecule. The [Ni(phen)H₂O] units are connected by two different 4,4'-(ethene-1,2-diyl)dibenzoate (bpea^2-) bridges, forming a one-dimensional zigzag chain structure. One bpea^2- ligand coordinates to Ni in a bis-monodentate fashion, while the other acts as a bis-bidentate chelate.

Online 22 November 2006

Copyright © International Union of Crystallography
IUCr Webmaster