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Acta Cryst. (2007). E63, m184-m186  [ doi:10.1107/S1600536806052688 ]

catena-Poly[[[aqua(2-amino-4,6-dimethylpyrimidine-[kappa]N1)copper(II)]-[mu]-benzene-1,3-dicarboxylato-[kappa]2O1:O3] 2-amino-4,6-dimethylpyrimidine solvate]

N. Li and Q. Wei

Abstract: In the title polymer, {[Cu(C8H4O4)(C6H9N3)(H2O)]·C6H9N3}n, the CuII ion approximates a distorted square-pyramidal geometry defined by an NO4 donor set. Adjacent CuII ions are bridged by isophthalate dianions to form a one-dimensional chain. Chains interact through [pi]-[pi] stacking interactions of 2-amino-4,6-dimethylpyrimidine rings and hydrogen bonds, to build a three-dimensional crystal structure.

Online 13 December 2006


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