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Acta Cryst. (2007). E63, m17-m19  [ doi:10.1107/S1600536806050914 ]

Tetraaqua(2,2'-bipyridine-5,5'-dicarboxylato)iron(II) dihydrate

O. K. Kwak, K. S. Min and B. G. Kim

Abstract: In the title compound, [Fe(C12H6N2O4)(H2O)4]·2H2O, the FeII ion (site symmetry 2) is bonded to one N,N'-bidentate 2,2'-bipyridine-5,5'-dicarboxylate ligand and four water molecules, resulting in a distorted cis-FeN2O4 coordination geometry. A network of [pi]-[pi] interactions and O-H...O hydrogen bonds gives rise to a robust supramolecular network in the crystal structure.

Online 6 December 2006


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