Acta Cryst. (2007). E63, m227-m229  [ doi:10.1107/S160053680605272X ]

Propane-1,3-diylbis(triphenylphosphonium) (oxalato)oxodiperoxomolybdate(VI) monohydrate

X.-Y. Shi, J.-F. Wei, X.-R. Zhang and J. Cao

Abstract: In the structure of the title compound, (C₃₉H₃₆P₂)[Mo(C₂O₄)O(O₂)₂]·H₂O, the Mo atom in the complex anion shows a distorted pentagonal-bipyramidal geometry and the six phenyl rings in the cation form a double propeller linked by a propane group. The cations, anions and water molecules are connected via hydrogen bonds and electrostatic interactions to form a three-dimensional extended network.

Online 15 December 2006

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