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Acta Cryst. (2007). E63, o179-o181 [ doi:10.1107/S1600536806051749 ]
Abstract: Ions of the title compound, tryptaminium dihydrogenphosphate, C10H13N2+·H2PO4-, are connected by intermolecular N-H
O=P [N
O = 3.028 (3) Å], NH3
O=P [N
O = 2.720 (3) and 2.950 (3) Å], NH3
OH-P [N
O = 2.993 (2) Å] and P-OH
O=P [O
O = 2.562 (2) and 2.619 (2) Å] hydrogen bonds between the indole -NH and ammonium -NH3 groups of the cation and the dihydrogenphosphate anions into an infinite three-dimensional network.
Online 8 December 2006
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