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Acta Cryst. (2007). E63, m108-m110  [ doi:10.1107/S1600536806052007 ]

[mu]-1,4-Diazabicyclo[2.2.2]octane-[kappa]2N:N'-bis[bis(O,O'-diisopropyl dithiophosphato-[kappa]2S,S')zinc(II)]

C. A. Ellis, S. W. Ng and E. R. T. Tiekink

Abstract: The dinuclear title molecule, [Zn2(C6H14O2PS2)4(C6H12N2)], is disposed about a centre of inversion and features a heavily distorted coordination geometry, owing to the presence of asymmetrically coordinating dithiophosphate ligands. In the crystal structure, molecules are stacked into layers, with connections between layers provided by C-H...O interactions.

Online 8 December 2006


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