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Acta Cryst. (2007). E63, m70-m72  [ doi:10.1107/S1600536806051609 ]

catena-Poly[[bis(N,N-dimethylformamide)manganese(II)]-di-[mu]2-oxalato]

Y.-N. Chan, H.-K. Zhao, X.-G. Wang and X.-J. Zhao

Abstract: The title complex, [Mn(C2O4)(C3H7NO)2]n, forms extended one-dimensional chains with oxalate dianions bridging MnII atoms in a bis-bidentate mode. The unique MnII atom lies on a crystallographic twofold axis and is in a distorted octahedral coordination environment. There is a single weak intramolecular C-H...O hydrogen-bond interaction [H...O = 2.38 Å].

Online 6 December 2006


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